scholarly journals Effect of polycarboxylate superplasticizer on fluidity and rheology of cement slurry containing silica fume

2021 ◽  
Vol 237 ◽  
pp. 03008
Author(s):  
Qingen Meng ◽  
Juan He ◽  
Congmi Cheng ◽  
Xiaofen Zhu
Keyword(s):  
Rheological Properties ◽  
Yield Stress ◽  
Silica Fume ◽  
Plastic Viscosity ◽  
Cement Slurry ◽  
Pseudoplastic Fluid ◽  
Plasticizer Content ◽  
Polycarboxylate Superplasticizer ◽  
Dispersion Degree ◽  
Fluid Characteristic

The effect of polycarboxylate superplasticizer on the fluidity and rheology of cement - silica fume - water paste was investigated. The changes of dispersion degree, yield stress and plastic viscosity of paste with different superplasticizer content were analyzed. The results show that the rheological properties of paste with different superplasticizer content conform to Herschel-Bulkley model. The shear thinning of the slurry is manifested as a typical yielding pseudoplastic fluid characteristic. When the content of superplasticizer is less than 1.0%, the plastic viscosity and yield stress decrease and the fluidity increase with the increase of plasticizer content. When the content of superplasticizer is more than 1.0%, the yield stress decreases slightly and the plastic viscosity increases with the increase of plasticizer content. The fluidity decreases with the increase of yield stress, and there is a good correlation between them.

scholarly journals Effect of Silica Fume on the Rheological Properties of Cement Paste with Ultra-Low Water Binder Ratio

Materials ◽  
2022 ◽  
Vol 15 (2) ◽  
pp. 554
Author(s):  
Juan He ◽  
Congmi Cheng ◽  
Xiaofen Zhu ◽  
Xiaosen Li
Keyword(s):  
Hysteresis Loop ◽  
Rheological Properties ◽  
Yield Stress ◽  
Silica Fume ◽  
Plastic Viscosity ◽  
Rheological Parameters ◽  
Loop Area ◽  
Binder Ratio ◽  
Hysteresis Loop Area ◽  
Water Binder Ratio

The effect of silica fume on the rheological properties of a cement–silica fume–high range water reducer–water mixture with ultra-low water binder ratio (CSHWM) was studied. The results indicate that the W/B ratio and silica fume content have different effects on the rheological parameters, including the yield stress, plastic viscosity, and hysteresis loop area. The shear-thickening influence of CSHWM decreased with the increased silica fume content. When the silica fume content increased from 0% to 35%, the mixture with W/B ratio of 0.19 and 0.23 changed from a dilatant fluid to a Newtonian fluid, and then to a pseudoplastic fluid. When the silica fume content was less than 15%, the yield stress was close to 0. With the increase of silica fume content, the yield stress increased rapidly. The plastic viscosity and hysteresis loop area decreased slightly with the addition of a small amount of silica fume, but increased significantly with the continuous increase of silica fume. Compared with the Bingham and modified Bingham models, the Herschel–Buckley model is more applicable for this CSHWM.

Influence of Glass Powder on Rheological Properties of Ultra-High Performance Concrete Paste

2021 ◽  
Vol 1036 ◽  
pp. 419-431
Author(s):  
Xue Li Nan ◽  
Jian Rui Ji ◽  
Rong Yang Li ◽  
Yi Wang ◽  
Hao Chen ◽  
...  
Keyword(s):  
Rheological Properties ◽  
Yield Stress ◽  
Silica Fume ◽  
High Performance ◽  
Glass Powder ◽  
High Performance Concrete ◽  
Shear Thickening ◽  
Plastic Viscosity ◽  
Ecological Problem ◽  
Ultra High Performance Concrete

Replacing cement and silica fume with glass powder to prepare ultra-high performance concrete (UHPC) is beneficial to solve the ecological problem in the field of civil engineering, but the technologies of preparation, transportation, pumping, and hardening of UHPC mainly relate to its rheological property. Therefore, this paper studied the influence of glass powder on the rheological properties of UHPC paste by performing the flow and the rheological test. Experimental results showed that when the cement and silica fume partially replaced by glass powder, the UHPC paste appears shear thickening, yield stress, plastic viscosity, and area of hysteresis loop decrease. This means that mixing glass powder can somehow inhibit the problems of segregation and bleeding of UHPC during pumping. In this manner, the dosage of the superplasticizer in UHPC is appropriately reduced, the filling capacity of UHPC during pouring is improved, and the energy required for UHPC in the pumping process is weakened. Compared with replacing cement, replacing silica fume with glass powder significantly increases the shear thickening and fluidity of UHPC paste, and at the same, reduces its yield stress and plastic viscosity. This indicates that the construction performance of UHPC is greatly improved with the replacement of silica fume. The fluidity and yield stress of UHPC paste satisfy the quadratic polynomial function relationship, and the replacement of cement and silica fume with glass powder should be less than 33% and 50%, respectively. Under this condition, the rheological properties of the UHPC paste are greatly improved and result in little negative impact on the mechanical properties of UHPC.

scholarly journals Effects of Fly Ash and Chemical Admixtures on the Rheological Properties of High-Concentration Full-Tailing Filling Slurry

2020 ◽  
Vol 2020 ◽  
pp. 1-13
Author(s):  
Fulin Wang ◽  
Faguang Yang ◽  
Zhengping Yuan ◽  
Shijiao Yang
Keyword(s):  
Fly Ash ◽  
Rheological Properties ◽  
Yield Stress ◽  
Polyethylene Oxide ◽  
Viscosity Coefficient ◽  
Pipeline Transportation ◽  
High Concentration ◽  
Polycarboxylate Superplasticizer ◽  
Chemical Admixtures

Good fluidity is the precondition to ensure the pipeline transportation of the filling slurry. The admixture in the filling slurry will affect the rheological properties of the slurry. In this paper, yield stress (YS), viscosity coefficient (VC), and expansion (ED) of the filling slurry were measured by the MCR52 rheometer and expansion tester, respectively, and the influence regularities of the three kinds of admixtures including fly ash (FA), polycarboxylate superplasticizer (PS), and polyethylene oxide (PEO) on the rheological properties of the filling slurry were obtained. The results show that when other conditions are fixed, the fluidity of the slurry becomes worse with the increase of the amount of fly ash but improves with the increase of the amount of the polycarboxylate superplasticizer; polyethylene oxide is not suitable for the improvement of the fluidity of the high-concentration full-tailing filling slurry, and the fluidity of the slurry becomes worse rapidly with the increase of the amount of polyethylene oxide.

The flow properties of axoplasm in a defined chemical environment: influence of anions and calcium

1979 ◽  
Vol 205 (1160) ◽  
pp. 323-345 ◽  
Keyword(s):  
Protease Inhibitor ◽  
Rheological Properties ◽  
Cellulose Acetate ◽  
Yield Stress ◽  
Plastic Viscosity ◽  
Chemical Environment ◽  
Flow Properties ◽  
Giant Axons ◽  
The Matrix ◽  
Anion Composition

The flow properties of axoplasm have been studied in a defined chemical environment. Axoplasm extruded from squid giant axons was introduced into porous cellulose acetate tubes of diameter roughly equal to that of the original axon. Passage of axoplasm along the tube rapidly coated the tube walls with a layer of protein. By measuring the rate of flow back and forth along the tube, the rheological properties of the axoplasm plug were investigated at a range of pressures and in a variety of media. Axoplasm behaves as a classical Bingham body the motion of which can be characterized by a yield stress ( θ ) and a plastic viscosity ( η p1 ). In a potassium methanesulphonate medium containing 65 nM free Ca 2+ , θ averaged 109 ± 46 dyn/cm 2 and η p1 146 ± 83 P. † These values were little affected by ATP, colchicine, cytocholasin B or by replacing K by Na but were sensitive to the anion composition of the medium. The effectiveness of different anions at reducing θ and η p1 was in the order SCN > I > Br > Cl > methanesul­phonate. θ and η p1 were also drastically reduced by increasing the ionized Ca. This effect required millimolar amounts of Ca, was unaffected by the presence of ATP and was irreversible. It could be blocked by the protease inhibitor TLCK. E. p. r. measurements showed that within the matrix of the axoplasm gel there is a watery space that is largely unaffected by anions or calcium.

scholarly journals Analyzing Cement Rheological Properties Using Different Additive Schemes at High Pressure and High Temperature Conditions

2020 ◽  
Vol 39 (3) ◽  
pp. 466-474
Author(s):  
Khalil Rehman Memon ◽  
Aftab Ahmed Mahesar ◽  
Shahzad Ali Baladi ◽  
Muhannad Talib Sukar
Keyword(s):  
High Pressure ◽  
High Temperature ◽  
Rheological Properties ◽  
Silica Fume ◽  
Gel Strength ◽  
Water Quantity ◽  
Fluid Loss ◽  
Cement Slurry ◽  
Three Samples ◽  
Loss Control

The experimental study was conducted on rheological properties in laboratory to measure the integrity of cement slurry. Three samples were used and analyzed at different parameters to check the elasticity of cement slurry. Additives with various concentrations, i.e. silica fume % BWOC (Present by Weight on Cement) (15, 17, 19 and 21), dispersant % Wt (Percent Weight) (0.21, 0.26 and 0.31) and additional 1; % Wt of fluid losscontrol were used to improve the performance of the cement slurry at the temperature of 123oC. The results have shown that increase in the concentration of dispersants that have caused to decrease in the Plastic Viscosity (PV), Yield Point (YP) and GS (Gel Strength). The rheological properties of cement were improved with the addition of fluid loss control additive in 21 % BWOC (Present by Weight on Cement) silica fume increase the water quantity in cement slurry that improve its durability and to reduce the strength retrogression in High Temperature High Pressure (HTHP) environment. Results were achieved through HTHP OFITE Viscometer (Model 1100).

scholarly journals Rheological Properties Of Self-Consolidating Concrete Incorporating Natural And Industrial Pozzolans

2021 ◽  
Author(s):  
Asaad Mousa
Keyword(s):  
Rheological Properties ◽  
Yield Stress ◽  
Silica Fume ◽  
High Performance ◽  
High Performance Concrete ◽  
Cost Effective ◽  
Sustainable Construction ◽  
Self Consolidating Concrete ◽  
Supplementary Cementing Materials ◽  
Passing Ability

Self-consolidation concrete (SCC) is the latest version of high performance concrete with excellent workability and high resistance to segregation and bleeding. The main objective of this project is to study the rheological properties of SCC incorporating natural and industrial pozzolans (silica fume and metakaolin, repectively) as supplementary cementing materials (SCMs). Use of such pozzolanic materials in the development of environmentally friendly and cost effective SCC can lead to sustainable construction. In this project eleven SCC mixtures are developed by incorporating different percentages of silica fume (SF) and metakaolin (MK) as replacement of cement. However, the water cement ratio of all SCC mixtures are optimized so that all mixtures satisfied the requirements of SCC in terms of fresh properties such as workability, stability, passing ability, bleeding and segregation resistance. This study particularly concentrates on evaluation of the rheological properties such as viscosity and yield stress of developed silica fume and metakaolin based SCC mixtures. The influence of SF and MK dosages on viscosity and yield stress of SCC mixtures are evaluated. Correlations among fresh and rheological properties are developed and critically reviewed to make recommendations.

scholarly journals Analysis of the Effect of Various Types of Limestone as a Main Constituent of Cement on the Chosen Properties of Cement Pastes and Mortars

2019 ◽  
Vol 65 (3) ◽  
pp. 75-86
Author(s):  
J. Gołaszewski ◽  
G. Cygan ◽  
M. Gołaszewska
Keyword(s):  
Compressive Strength ◽  
Rheological Properties ◽  
Yield Stress ◽  
Drying Shrinkage ◽  
Plastic Viscosity ◽  
Main Constituent ◽  
Cement Pastes ◽  
Mortar Strength ◽  
The Impact

AbstractThe article is an attempt to compare the impact of the use of various types of limestone as the main constituent of cement on selected mortar properties. Four different limestones were added in amount of 15, 30, 40% to CEM I 42.5 R to obtain limestone cemens. Rheological properties (yield stress, plastic viscosity) of fresh mortar, tensile and compressive mortar strength, early shrinkage, and drying shrinkage were tested. Obtained results indicate that both tensile and compressive strength decreases with the increase of the limestone content in cement. Limestone can worsen or improve workability, depending on distribution of limestone grains. The addition of limestone increases the early shrinkage, but reduces the shrinkage after 28 days. Studies show that the granulation of limestone plays an important role in determining the influence of limestone on mortar properties.

scholarly journals Rheological Properties Of Self-Consolidating Concrete Incorporating Natural And Industrial Pozzolans

2021 ◽  
Author(s):  
Asaad Mousa
Keyword(s):  
Rheological Properties ◽  
Yield Stress ◽  
Silica Fume ◽  
High Performance ◽  
High Performance Concrete ◽  
Cost Effective ◽  
Sustainable Construction ◽  
Self Consolidating Concrete ◽  
Supplementary Cementing Materials ◽  
Passing Ability

Self-consolidation concrete (SCC) is the latest version of high performance concrete with excellent workability and high resistance to segregation and bleeding. The main objective of this project is to study the rheological properties of SCC incorporating natural and industrial pozzolans (silica fume and metakaolin, repectively) as supplementary cementing materials (SCMs). Use of such pozzolanic materials in the development of environmentally friendly and cost effective SCC can lead to sustainable construction. In this project eleven SCC mixtures are developed by incorporating different percentages of silica fume (SF) and metakaolin (MK) as replacement of cement. However, the water cement ratio of all SCC mixtures are optimized so that all mixtures satisfied the requirements of SCC in terms of fresh properties such as workability, stability, passing ability, bleeding and segregation resistance. This study particularly concentrates on evaluation of the rheological properties such as viscosity and yield stress of developed silica fume and metakaolin based SCC mixtures. The influence of SF and MK dosages on viscosity and yield stress of SCC mixtures are evaluated. Correlations among fresh and rheological properties are developed and critically reviewed to make recommendations.

scholarly journals Influence of Nano-SiO2, Nano-CaCO3 and Nano-Al2O3 on Rheological Properties of Cement–Fly Ash Paste

Materials ◽  
2019 ◽  
Vol 12 (16) ◽  
pp. 2598 ◽  
Author(s):  
Yiming Peng ◽  
Kunlin Ma ◽  
Guangcheng Long ◽  
Youjun Xie
Keyword(s):  
Fly Ash ◽  
Rheological Properties ◽  
Yield Stress ◽  
Free Water ◽  
Shear Thickening ◽  
Shear Thinning ◽  
Plastic Viscosity ◽  
Behavior Changes ◽  
Nano Sio2 ◽  
Resting Time

Rheological curves of cement–fly ash (C–FA) paste incorporating nanomaterials including nano-SiO2 (NS), nano-CaCO3 (NC) and nano-Al2O3 (NA) at different resting times (hydration time of 5 min, 60 min, and 120 min) were tested with a rheometer. The rheological behaviors were described by the Herschel–Bulkley (H–B) model, and the influences of these nanomaterials on rheological properties of C–FA paste were compared. Results show that the types, content of nanomaterials and resting time have great influences on the rheological properties of C–FA paste. Incorporating NS and NA increases yield stress and plastic viscosity, and decreases the rheological index of C–FA paste. When the content of NS and NA were 2 wt%, the rheological index of C–FA paste was less than 1, indicating rheological behavior changes from shear thickening to shear thinning. Meanwhile, with rising resting time, yield stress and plastic viscosity increased significantly, but the rheological index decreased evidently, showing paste takes on shear thinning due to the rise of resting time. However, incorporating 3 wt% NC and the rising of resting time did not change the rheological properties of C–FA paste. These differences are mainly that the specific surface area (SSA) of NS (150 m2/g) and NA (120 m2/g) are much larger than that of NC (40 m2/g). The huge SSA of NS and NA consume lots of free water and these tiny particles accelerate the hydration process during resting time.

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