Effect of Ether-Typed Polycarboxylate Superplasticizer on the Adsorption, Rheology and Concrete Properties

This article disclosed the influence of acid-ether ratio, n(SH)/n(IPEG), and n(APS)/n(IPEG) on adsorption and fluidity performance. The optimum synthetic parameters of acid-ether ratio, n(SH)/n(IPEG) and n(APS)/n(IPEG) were 0.5, 0.35 and 0.05, respectively. The rheology fitting equation was τ= 719.55γ+ 1834.54. And the correlation coefficient was 0.9843. The cement paste conformed to the law of pseudoplastic fluid. The preferred PCE-11 had excellent performance in freshly mixed and hardened concrete.

The combined plasticization of jute and tung oil anhydride for jute fiber reinforced poly(lactic acid) composites

In this work, novel plasticizing biodegradable poly (lactic acid) (PLA) composites were prepared by melt blending of jute and tung oil anhydride (TOA), and the physical and mechanical properties of PLA/jute/TOA composites were tested and characterized. The impact strength of PLA/jute/TOA composites significantly increases with increasing the content of TOA. The SEM images of fracture surface of PLA/jute/TOA composites become rough after the incorporation of TOA. In addition, TOA changes the crystallization temperature and decomposition process of PLA/jute/TOA composites. With increasing the amount of TOA, the value of storage modulus (E′) of PLA/jute/TOA composites gradually increases. The complex viscosity (η*) values for all samples reduce obviously with increasing the frequency, which means that the pure PLA and PLA/jute/TOA composites is typical pseudoplastic fluid. This is attributed to the formation of crosslinking, which restricts the deformation of the composites.

Effect of Different Temperature-Controlled Ultrasound on the Physical and Functional Properties of Micellar Casein Concentrate

Micellar casein concentrate (MCC) is a novel dairy ingredient with high protein content. However, its poor functional properties impair its potential for further application, highlighting the importance of using innovative processing methods to produce modified MCC, such as ultrasound (US). This work investigated the impact of US on the physical and functional properties of MCC under temperature-controlled and -uncontrolled conditions for different time intervals. Under temperature-controlled ultrasound (TC-US) treatment, a reduction was found in the supernatant particle size of casein micelles. Soluble calcium content and hydrophobicity increased following ultrasound treatment at 20 °C, resulting in a remarkable improvement in emulsification. However, long-time ultrasonication led to an unstable state, causing the MCC solutions to show shear thinning behavior (pseudoplastic fluid). Compared with 50 °C temperature-controlled ultrasonication, ultrasonication at 20 °C had a greater influence on particle size, viscosity and hydrophobicity. These findings indicate that 20 °C TC-US could be a promising technology for the modification of MCC.

Process Characteristics of Water-based Self-curing Coatings for Sand Casting

The rheological and gas evolution characteristics of water-based self-curing coatings for sand casting were analyzed and the influence of coating-thickness and graded coating on self-curing rate of coatings was studied. It can be seen from the test results that: the new water-based self-curing coating has both the characteristics of thixotropic fluid and pseudoplastic fluid, which has moderate thixotropy rate and high brushing index, good brushability and excellent comprehensive balance of flow-levelling and anti-flowability. It can meet the rheological requirements of various coating methods. The self-curing speed of water-based self-curing coating increases in an approximately linear manner with the decrease of its thickness. Thick coating should be best to paint at one time in the premise of ensuring its surface quality. Although the gas evolution volume of the new water-based self-curing coating is approximately equal to that of ordinary water-based baking coatings, but the gas evolution speed of self-curing coatings is almost half as that of the latter, which provides good conditions for preventing gas hole defect of casting.

The influence of different fly ash-cement replacement ratios on the pressure drop of a horizontal backfilling pipe

Fly ash (FA) is a kind of harmful by-product in thermal power generation plants, and finding a way to enhance the utility of fly ash has been widely discussed among civil engineering and mining sectors. To investigate the possible optimal ratios of replacing usually used bind agent namely Portland cement (PC) with fly ash, this paper designed different test groups with varying PC-FA replacement ratio. To identify the physical and chemical characteristics of mixing materials used to produce the backfilling slurries, a rheological experiment and X-ray diffraction test have been conducted. Rheological tests show all these three replacement ratio groups (60%, 65%, 70% respectively) are yield pseudoplastic fluid. Computational fluid dynamics as an efficient and money-saving method also has been introduced in the present research to duplicate the flow behaviors and calculate the pressure drop (PD) in the backfilling pipe circuits. The simulation results suggested that all these three RR categories experience an increasing tendency in pressure drop with increasing flow velocity, but in the velocity range of 2 m/s - 2.4 m/s, the increasing tendency is gentle until flow velocity reaches 2.6 m/s, the PD increase evidently. Furthermore, when the RR = 65%, the pressure drop is significantly lower than that of RR = 60% or RR = 70% at all the corresponding investigated flow particle sizes have significant impact on the pressure drop across a pipe and is dependent on solid fraction and flow rate and velocities. Therefore, we can conclude that a proper dosage of FA in mixing backfilling slurries can reduce pressure drop obviously and thereby decrease the expenses in bind agent. Given the FA’s significant effect on pressure drop, and comprehensive considering the backfilling capacity and backfilling cost, the combination of RR = 65% and velocity = 2.6 m/s is optimum.

Approximate Analytical Solution of a Power-Law Pseudoplastic Fluid in a Boundary Layer over a Porous Plate: A New Application of Multi-Stage Parker-Sochacki Method

In this paper, based on Parker-Sochacki method for solving a system of differential equations,a multistage technique is developed for solving the nonlinear boundary layer equations of powerlawfluid on infinite domain. The problem domain is split into subintervals over which the boundaryvalue problem is replaced with a sequence of subproblems. In a shooting-like approach, the boundarycondition at infinity is converted to an equivalent initial condition. By recasting the problem as apolynomial system of first-order autonomous equations, the sub-problems are solved with Parker-Sochacki method with very high accuracy. The interval of convergence of the solution is deriveda-priorly in terms of the parameters of the polynomial system, which guides optimal choice of thediscretization parameter. The technique yielded a convergent piecewise continuous solution over theproblem domain. The results obtained, demonstrated graphically and in tables, compared well withexisting ones in the literature.

Effect of Hall current on the flow and heat transfer of non-Newtonian power-law nanofluid in the presence of Cattaneo–Christov heat flux and free stream

The nanofluids are a recent challenging task in a nanotechnology field used in heat transfer enhancement for base fluids. The major purpose of this research is to examine the influences of Hall current on the non-Newtonian power-law nanofluid on an exponentially extending surface. Implementation in the Cattaneo–Christov heat flux and the free stream is performed to analyze the thermal relaxation features. Entropy generation evaluation and Bejan number during the convection flow are investigated. The Runge–Kutta–Fehlberg method is employed to resolve the transformed governing nonlinear equations. The impacts of the key physical factors on the profiles of primary and secondary velocities, temperature and entropy generation are discussed across the graphs. The local skin-friction coefficients, Nusselt and Sherwood numbers are demonstrated in a tabular form under the impacts of key physical parameters. Two different types of power-law indicators including pseudoplastic fluid [Formula: see text] and dilatant fluid [Formula: see text] are conducted. The results indicated that the flow speed decreases at dilatant fluid compared to pseudoplastic fluid due to higher viscosity. Increasing Hall current parameter powers the axial and secondary velocity profiles. Thermophoresis parameter powers the profiles of the temperature, nanoparticle volume fraction and local entropy generation. The dilatant fluid [Formula: see text] gives higher values of [Formula: see text] and [Formula: see text] compared to the pseudoplastic fluid [Formula: see text].

Toughening Modification of Polylactic Acid by Thermoplastic Silicone Polyurethane Elastomer

The melt blending of polylactic acid (PLA) and thermoplastic silicone polyurethane (TPSiU) elastomer was performed to toughen PLA. The molecular structure, crystallization, thermal properties, compatibility, mechanical properties and rheological properties of the PLA/TPSiU blends of different mass ratios (100/0, 95/5, 90/10, 85/15 and 80/20) were investigated. The results showed that TPSiU was effectively blended into PLA, but no chemical reaction occurred. The addition of TPSiU had no obvious effect on the glass transition temperature and melting temperature of PLA, but slightly reduced the crystallinity of PLA. The morphology and dynamic mechanical analysis results demonstrated the poor thermodynamic compatibility between PLA and TPSiU. Rheological behavior studies showed that PLA/TPSiU melt was typically pseudoplastic fluid. As the content of TPSiU increased, the apparent viscosity of PLA/TPSiU blends showed a trend of rising first and then falling. The addition of TPSiU had a significant effect on the mechanical properties of PLA/TPSiU blends. When the content of TPSiU was 15 wt%, the elongation at break of the PLA/TPSiU blend reached 22.3% (5.0 times that of pure PLA), and the impact strength reached 19.3 kJ/m2 (4.9 times that of pure PLA), suggesting the favorable toughening effect.

CFD Investigation Of Mixing Of Yield-Pseudoplastic Fluid With Anchor Impeller

The Anchor impeller, which is a close clearance impeller, produces high shear near the vessel wall and is recommended for mixing of highly viscous fluids. A thorough search of the literature suggests that few publications have beeen devoted to the computational fluid dynamics (CFD) modeling of mixing of non-Newtonian fluids with the anchor impeller. Thus the objectives of this study are (i)to generate a 3-D flow field for mixing of yield-pseudoplastic fluid in a flat bottom cylindrical tank equipped with two-and four-blade anchor impellers using CFD modeling technique, (ii) to evaluate the effects of fluid rheology agitator speed, number of blades, vessel clearance and impeller blade width on power consumption, mixing time and flow patterns, and (iii) to determine the optimum value of clearance to diameter ratio and impeller blade width to diameter ratio on the basis of minimum mixing time. The study was carried out for a yield-stress pseudoplastic fluid, using a CFD package (Fluent), to simulate the 3-D flow domain generated in a cylindrical tank equipped with two-and four-blade anchor impellers. The multiple reference frame (MRF) technique was employed to model the rotation of impellers. The rheology of the fluid was approximated using the Herschel-Bulkley model. To validate the model, CFD results for the power were compared to experimental data. After the flow fields were calculated, the simulations for tracer homogenization was performed to simulate the mixing time. The effect of impeller speed, fluid rheology, and number of impellers on power consumption, mixing time, and flow pattern were explored. The optimum values of c/D (clearance to diameter) and w/D (impeller blade width to diameter) ratios were determined on the basis of minimum mixing time.