scholarly journals Optimization of furfural extraction from Theobrama cacao wastes using response surface methodology

2019 ◽  
Vol 268 ◽  
pp. 06010
Author(s):  
John Rhen Uy ◽  
Neil Dominic Careo ◽  
Dominick Llarena ◽  
John Raymond Barajas
Keyword(s):  
Sodium Chloride ◽  
Hydrochloric Acid ◽  
Acid Concentration ◽  
Development Program ◽  
The Philippines ◽  
Extraction Yield ◽  
Government Support ◽  
Extraction Time ◽  
Hydrochloric Acid Concentration ◽  
Optimum Conditions

Cacao farming in the Philippines is continually expanding due to an influx of government support and funding. Although a comprehensive development program was implemented, the large volume of cacao biomass waste generated annually remains underutilized. In an attempt to provide a means of reusing this waste, we test the extent to which furfural can be extracted from cacao pod wastes. A box-behnken experimental design was used to obtain the optimal conditions in the acid-catalyzed extraction of crude furfural. Extraction time (min), hydrochloric acid concentration (M), and amount of sodium chloride (g) were found to have a significant influence on the extraction yield of crude furfural. Actual values of these independent variables were chosen on the basis of preliminary experimental results. Optimum conditions using ridge analysis were found to be: extraction time 35.0 min, hydrochloric acid concentration 5.0 M, and amount of sodium chloride 7.0 g. Furfural extraction was also performed at optimum conditions to assess the validity of the empirical model. In conclusion, the high furfural extraction yield obtained in our experiments presents an opportunity to harness these unregulated wastes in producing high quality products.

Experimental Study on Concentrating Scandium by Leaching from Associated Scandium Ore

2013 ◽  
Vol 734-737 ◽  
pp. 1033-1036
Author(s):  
Gui Fang Zhang ◽  
Peng Yan ◽  
Qing Rong Yang
Keyword(s):  
Experimental Study ◽  
Particle Size ◽  
Hydrochloric Acid ◽  
Acid Concentration ◽  
Hydrochloric Acid Concentration ◽  
Leaching Rate ◽  
Optimal Conditions ◽  
Research Results ◽  
Solid Ratio ◽  
Leaching Residue

Based on the benefication of the complex silicate ore containing scandium, the research about aid-leaching agent used in the leaching of the scandium concentrate was been conducted. And the suitable leaching agent and aid-leaching agent which the useful ions entered into leaching liquid and the harmful ions were kept in leaching residue were been found according to the experiment results. For the scandium of sample existed various complex silicate ore as isomorphism form, the research has adopted hydrochloric acid with aid-leaching agent to dissociate the silicate ore and make scandium entering into solution. The research results has shown that the scandium leaching rate could reach 92.06% under the optimal conditions which the hydrochloric acid concentration is 22.8%, the dosage of aid leaching agent is 6%, liquid solid ratio is 4:1, particle size of leaching material totally is less than 0.15mm and leaching time is 8h.

Effects of high hydrochloric acid concentration on aniline chemical polymerization

Polymer ◽  
1997 ◽  
Vol 38 (20) ◽  
pp. 5247-5250 ◽  
Author(s):  
Gustavo M. Morales ◽  
Marcos Llusa ◽  
Maria C. Miras ◽  
Cesar Barbero
Keyword(s):  
Hydrochloric Acid ◽  
Acid Concentration ◽  
Hydrochloric Acid Concentration ◽  
Chemical Polymerization

scholarly journals Extraction of Sm(III)and Nd(III) with N,N,N’,N’-tetrabutyl-3-oxy-diglycolamidefrom hydrochloric acid

2013 ◽  
Vol 78 (1) ◽  
pp. 93-100 ◽  
Author(s):  
J.H. Yang ◽  
Y. Cui ◽  
G.X. Sun ◽  
Y. Nie ◽  
G.M. Xia ◽  
...  
Keyword(s):  
Rare Earth ◽  
Hydrochloric Acid ◽  
Ir Spectra ◽  
Acid Concentration ◽  
Distribution Ratio ◽  
Hydrochloric Acid Concentration ◽  
Extractant Concentration ◽  
Extraction Mechanism ◽  
Extraction Behavior ◽  
Loaded Organic Phase

The extraction behavior of Sm(III) and Nd(III) with N,N,N?,N?-tetrabutyl-3-oxa-diglycolamide (TBDGA) in 70% kerosene-30% n-octanol from hydrochloride acid wasstudied. The effect of hydrochloric acid concentration, extractant concentration,and temperature on the distribution of rare earth elementswas investigated. The extraction mechanism was established and the stoichiometry of the main extracted species was confirm to be SmCl3?2TBDGA and NdCl3?2TBDGA for Sm(III) and Nd(III), respectively. The extraction distribution ratio decreases with an increase in temperature, which demonstrates that the extraction reaction is exothermic. The IR spectra of the loaded organic phase and free extractant were recorded and discussed.

scholarly journals Influence of Hydrolysis Conditions on Characteristics of Nanocrystalline Cellulose Extracted from Ramie Fibers by Hydrochloric Acid Hydrolysis

2020 ◽  
Author(s):  
Kusmono Kusmono ◽  
Dimas Abdillah Akbar
Keyword(s):  
Thermal Stability ◽  
Hydrochloric Acid ◽  
Acid Hydrolysis ◽  
Acid Concentration ◽  
Crystallinity Index ◽  
Hydrochloric Acid Concentration ◽  
Hydrolysis Time ◽  
Study Results ◽  
Ramie Fibers ◽  
Hydrolysis Conditions

Abstract Nanocrystalline celluloses (NCCs) were successfully extracted from ramie fibers using chemical pretreatments followed by hydrochloric acid hydrolysis. The effects of acid concentration and hydrolysis time on the characteristics of NCCs were investigated in this study. Results showed that the optimal hydrolysis conditions were found to be 6 M hydrochloric acid concentration at 45 °C for 70 min. The obtained NCC had a rod like-shape with an average of 8.07 nm in diameter, 158.51 nm in length, 22.37 in aspect ratio, 89.61% in the crystallinity index, and 5.81 nm in crystallite size. The higher crystallinity and thermal stability were exhibited by NCCs compared to both raw fibers and chemically purified cellulose. The hydrolysis time had a significant effect on crystallinity and thermal stability. The crystallinity index and thermal stability of NCCs were obtained to decrease with increasing hydrolysis time.

scholarly journals The Effect of Chloride Acid Concentration and Demineralization Time on Gelatin Characteristic of EEL Fish Bones (Anguilla marmorata (Q.) Gaimard) -

2019 ◽  
Vol 9 (1) ◽  
pp. 38-43
Author(s):  
Jamaluddin ◽  
Angriani Abdullah ◽  
Yonelian Yuyun
Keyword(s):  
Hydrochloric Acid ◽  
Protein Content ◽  
Water Content ◽  
Acid Concentration ◽  
Functional Group ◽  
Fish Bone ◽  
Ash Content ◽  
Hydrochloric Acid Concentration ◽  
Fish Bones ◽  
Anguilla Marmorata

Anguilla marmorata (Q.) Gaimard, eel bonefish is one of the potentials sources for gelatin manufacture. This study aims to determine the concentration of hydrochloric acid (3%; 4%) and to optimize demineralization time (12 hours; 24 hours) for thequality of gelatin. Characteristic of gelatin was determined by analysis of water content, ash content and protein content. To optimize gelatin extraction from eel fish bone, Mann Whitney test with 4 – factor was adopted. Spectrophotometer FTIR was used to analyze functional groups of gelatin. Values of water content, ash and protein content of each combination of acid chloride and demineralization time have met the requirements. The spectrum of FTIR showed a typical gelatin functional group. The best combination of treatment is at 3% hydrochloric acid concentration and 12 hours of demineralization time.

scholarly journals Extraction and Back-Extraction Behaviors of La(III), Ce(III), Pr(III), and Nd(III) Single Rare Earth and Mixed Rare Earth by TODGA

Sensors ◽  
2021 ◽  
Vol 21 (24) ◽  
pp. 8316
Author(s):  
Lina Qiu ◽  
Jiandi Li ◽  
Weiwei Zhang ◽  
Aijun Gong ◽  
Xiaotao Yuan ◽  
...  
Keyword(s):  
Rare Earth ◽  
Nitric Acid ◽  
Hydrochloric Acid ◽  
Liquid System ◽  
Extraction Time ◽  
Hydrochloric Acid Concentration ◽  
Back Extraction ◽  
Initial Concentration ◽  
Initial Stage ◽  
Acid Type

N,N,N′,N′-Tetraoctyl diglycolamide (TODGA), as a new extraction agent, is effective for its excellent performance and low environmental hazard, and it is very welcome for the rare earth separation process. In this paper, by controlling the extraction time, diluent type, acid type and its concentration, rare earth concentration, etc., the optimum extraction and back-extraction effects of TODGA on La(III), Ce(III), Pr(III), and Nd(III) and mixed rare earths were obtained. The experiment showed that 0.10 mol·L−1 TODGA had the best extraction effect on single rare earth under the conditions of using petroleum ether as diluent, 5 mol·L−1 nitric acid, 20 min extraction time, and 0.01 mol·L−1 rare earth. In the mixed rare earth extraction, the percentage concentrations of La(III), Ce(III), Pr(III), and Nd(III) could be achieved from 21.7%, 19.9%, 30.8%, and 22.2% at the initial stage to 90.5%, 37%, 51%, and 62% after extraction, respectively, by controlling the number of back-extraction cycles and the concentrations of hydrochloric acid and nitric acid in the back-extraction system. The TODGA–rare earth carrier system showed the best back-extraction effect when the hydrochloric acid concentration was 1 mol·L−1 and the back-extraction time was 20 min. At the same time, the mixed rare earth liquid system with low initial concentration was selected for extraction and separation of mixed rare earth. The separation effect was better, and the recovery rate was higher than that of mixed rare earth liquid system with a high initial concentration.

scholarly journals Shrinking core model of demineralization of chitin isolation from shrimp shell

2018 ◽  
Vol 154 ◽  
pp. 01014
Author(s):  
Ahmad Fadli ◽  
Subkhan Maulana ◽  
Drastinawati
Keyword(s):  
Hydrochloric Acid ◽  
Kinetic Model ◽  
Acid Concentration ◽  
Calcium Content ◽  
Core Model ◽  
Percentage Error ◽  
Hydrochloric Acid Concentration ◽  
Shrinking Core Model ◽  
Shrimp Shell ◽  
Shrinking Core

Chitin is a naturally abundant polymer and most of it was used as a surfactant and cosmetic raw materials. Chitin be able to derive from natural sources like shrimp shell waste. The aim of this research was to study the kinetic model of chitin demineralization with approach to shrinking core model (SCM) with variation of hydrochloric acid concentration. There models were used: Fluid Film Layer Diffusion, Ash Layer Diffusion and Chemical Reaction. It was began with deproteination at first with NaOH 3,5 % and continued with demineralization using hydrochloric acid at concentration 0,3 N; 0,6 N; 0,9 N and 1,2 N with variation of reaction time at 15, 30 and 15 minute. The calcium content in the product was analyzed after it was dried in the air oven. The results showed calcium concentration decrease along with increasing of hydrochloric acid concentration. It get kinetic model at concentration 0,3 N of hydrochloric acid usage with form: [see formula in PDF] with the highest value of R2 is 0,9555 and the smallest percentage error is 5,92%. Meanwhile with usage of hydrochloric acid at concentration 0,6 N; 0,9 N and 1,2 N were get kinetic model with form: [see formula in PDF] with the highest value of R2 is 0,9794.

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