scholarly journals Dispersion of Nano-materials in Polymer Composite Materials

2021 ◽  
Vol 333 ◽  
pp. 11003
Author(s):  
Tetsuya Yamamoto ◽  
Yuya Takahashi ◽  
Naoya Toyoda

Polymer composites materials are the subject of extensive studies because of their novel properties compared with their constituent materials. Dispersion stability of sub-micron sized particles in the medium is important from the point of colloidal views. In the present study, dispersion of nano-materials in the matrix polymer is one of the most important problems to enhance their mechanical properties. We tackled this problem to carry out surface modification of the nano-materials, such as carbon nano tubes (CNTs), using amphiphilic polymers, polyNvinylacetamide (PNVA), synthesized thorough radical polymerization. Hydrogen bond worked between PNVA onto the modified nano-materials and hydrophilic matrix, such as polyvinyl alcohol (PVA), to enhance surface adhesions and dispersions of the nano-materials in the matrix. As a result, the mechanical properties of their composites materials were strengthened. When CNTs were used in PVA, the transparency of the composite was also increased due to improvement of their dispersions. In addition, if the CNTs formed the networks in the composites, the highly conductive and transparent polymer composite films were fabricated.

Micromachines ◽  
2019 ◽  
Vol 10 (10) ◽  
pp. 651
Author(s):  
Xu Zheng ◽  
Qing Wang ◽  
Jinjin Luan ◽  
Yao Li ◽  
Ning Wang

Mechanical stability and repeatability are significant factors for the application of metal film flexible electronic devices. In this work, patterned metal/polymer composite films with good mechanical stability and repeatability were fabricated through nanoimprint technology. The mechanical properties characteristic of metal/polymer composite films were exhibited by resistance change (ΔR/R0) after cyclic tension and bending loading. It was found that the ΔR/R0 and error line of patterned metal/polymer composite film was far lower than the other control groups for repeated experiments, which indicates that patterned metal film has excellent mechanical properties and repeatability. The double cantilever beam method was employed to measure the interfacial adhesion properties of composite films. The average interfacial adhesion of patterned metal/polymer composite films is shown to be over 2.9 and 2.2 times higher than that of metal film deposited on bare polymer and metal nanowire-treated polymer substrates, respectively.


2020 ◽  
Vol 992 ◽  
pp. 415-420
Author(s):  
I.V. Zaychenko ◽  
V.V. Bazheryanu ◽  
A.G. Kim

The article considers the problem of the effect of uneven curing caused by the temperature gradient across the thickness of the material on the anisotropy of the strength properties of polymer composite materials. The effect of catalysts on the curing of the epoxy binder EDT-69N, used for the manufacture of multilayer polymer composite materials, was studied. According to dielectric spectrometry, the accelerating effect of the selected compounds on the curing process of the EDT-69N epoxy binder during fiberglass molding has been proved. The possibility of controlling the curing process using catalysts to reduce the influence of the temperature gradient on the anisotropy of the strength properties of the matrix in the manufacture of polymer composite materials is shown.


Metals ◽  
2020 ◽  
Vol 10 (7) ◽  
pp. 874
Author(s):  
Andrey A. Tsarkov ◽  
Vladislav Yu. Zadorozhnyy ◽  
Alexey N. Solonin ◽  
Dmitri V. Louzguine-Luzgin

High-strength crystalline/amorphous composites materials based on (Ti-Ni)-(Cu-Zr) system were developed. The optimal concentrations of additional alloying elements Al, Fe, and Cr were obtained. Structural investigations were carried out using X-ray diffraction equipment (XRD) and scanning electron microscope (SEM) with an energy-dispersive X-ray module (EDX). It was found that additives of aluminum and chromium up to 5 at% dissolve well into the solid matrix solution of the NiTi phase. At a concentration of 5 at%, the precipitation of the unfavorable NiTi2 phase occurs, which, as a result, leads to a dramatic decrease in ductility. Iron dissolves very well in the solid solution of the matrix phase due to chemical affinity with nickel. The addition of iron does not cause the precipitation of the NiTi2 phase in the concentration range of 0–8 at%, but with an increase in concentration, this leads to a decrease in the mechanical properties of the alloy. The mechanical behavior of alloys was studied in compression test conditions on a universal testing machine. The developed alloys have a good combination of strength and ductility due to their dual-phase structure. It was shown that additional alloying elements lead to a complete suppression of the martensitic transformation in the alloys.


2021 ◽  
Vol 2080 (1) ◽  
pp. 012011
Author(s):  
Di Sheng Lai ◽  
Sinar Arzuria Adnan ◽  
Azlin Fazlina Osman ◽  
Ismail Ibrahim ◽  
Hazrul Haq

Abstract Thermoplastic starch (TPS) was studied extensively to replace conventional plastic in packaging application. In this study, granule corn starch was first plasticized with water and glycerol to form TPS films and two different fillers were incorporated with TPS to form hybrid biocomposite films (TPSB). Two different fillers: Microcrystalline cellulose (MC) and Nano bentonite (NB) fixed at 1: 4 ratios in various loading (1wt%-6wt%) were incorporated in TPS to study effect of hybrid fillers on the mechanical properties of TPSB films. The effect of different loading of MC/NB on TPSB films was investigated through the structural, morphological and mechanical testing. Fourier Transform Infrared Spectroscopy (FTIR) shows TPS matrix and hybrid fillers are highly compatible due to hydroxyl bonding and verified through the shifting of spectra band. Scanning Electron Microscope (SEM) showed even distribution of fillers in the matrix of TPS. The TPSB films exhibited significant improvement 40% in elongation at break compared to pure TPS films. In this study, 5wt% is best loading of the hybrid fillers to incorporated in TPSB films as it achieved the highest value of tensile strength (8.52MPa), Young’s Modulus (42.0 MPa) and elongation at break (116.3%). Generally, previous studies showed flexibility of TPS composite films reduced with incorporating filler, however in this study, the flexibility TPSB show significant improvement compared to previous studies and exhibit promising potential in dry food packaging application.


2015 ◽  
Vol 813-814 ◽  
pp. 620-624
Author(s):  
S. Dhandapani ◽  
T. Rajmohan ◽  
K. Palanikumar ◽  
Charan Mugunthan

Metal Matrix Nano Composites (MMNC) consist of a metal matrix reinforced with nano-particles featuring physical and mechanical properties very different from those of the matrix. Especially carbon Nano tubes (CNT) can improve the matrix material in terms of wear resistance, damping properties and mechanical strength. The present investigation deals with the synthesis and characterization of aluminium matrix reinforced with micro B4C particles, and Multi Wall Carbon nano Tubes (MWCNT) were prepared by powder metallurgy route. Powder mixture containing fixed weight (%) of B4C and different wt% of MWCNT as reinforcement constituents that are uniaxial cold pressed and later green compacts are sintered in continues electric furnace. Microstructure and Mechanical properties such as micro hardness and density are examined. Micro structure of samples has been investigated using scanning electron microscope (SEM) .The results indicated that the increase in wt % of MWCNT improves the bonding and mechanical properties.


2016 ◽  
Vol 852 ◽  
pp. 49-54
Author(s):  
G. Anand ◽  
R. Dhinakaran ◽  
R. Elansezhian ◽  
N. Alagumurthi

In this paper, synthesis characterization and testing of hybrid polymer composite reinforced with electroless coated glass fiber is reported. The poly vinyl ester based composite is prepared with Electroless nickel phosphorus (Ni-P) coated glass fiber as the reinforcement. The glass fiber is coated with Ni-P by electroless plating method. The electroless Ni-P coating increases coating uniformity which in turn significantly improves properties such as hardness, strength and wear resistance of the glass fiber. Nano additives (0.5 wt.%) such as iron oxide, titanium oxide, copper oxide, aluminum oxide and zinc oxide are added into the matrix as fillers. The influence of different Nano fillers and its effect on the mechanical properties are examined. The result showed that after adding different nano particles, TiO2 exhibited better properties when compared to composites with other nano additives. The experimental results showed that after Ni-P coating on the glass fiber, the ultimate tensile strength and compressive strength improved by 18% and 10% respectively and TiO2 added PMC with 63%, 25% and 5% respectively.


2019 ◽  
Vol 1 (1) ◽  
pp. 276-280
Author(s):  
Lenka Markovičová ◽  
Viera Zatkalíková ◽  
Patrícia Hanusová

Abstract Carbon fiber reinforced composite materials offer greater rigidity and strength than any other composites, but are much more expensive than e.g. glass fiber reinforced composite materials. Continuous fibers in polyester give the best properties. The fibers carry mechanical loads, the matrix transfers the loads to the fibers, is ductile and tough, protect the fibers from handling and environmental damage. The working temperature and the processing conditions of the composite depend on the matrix material. Polyesters are the most commonly used matrices because they offer good properties at relatively low cost. The strength of the composite increases along with the fiber-matrix ratio and the fiber orientation parallel to the load direction. The longer the fibers, the more effective the load transfer is. Increasing the thickness of the laminate leads to a reduction in the strength of the composite and the modulus of strength, since the likelihood of the presence of defects increases. The aim of this research is to analyze the change in the mechanical properties of the polymer composite. The polymer composite consists of carbon fibers and epoxy resin. The change in compressive strength in the longitudinal and transverse directions of the fiber orientation was evaluated. At the same time, the influence of the wet environment on the change of mechanical properties of the composite was evaluated.


Variations in the mechanical properties of the glass fibre reinforced polymers were seen when exploring nano fillers such as Multi Walled Carbon Nano Tubes (MWCNTs) and graphene powders for reinforcement. GFRP composites when fabricated with increase in percentage weights of MWCNTs and graphene get better interfacial bonding with the matrix. Nano fillers improve the performance of the composites. This paper deals with the examination and experimental investigations carried out for the prediction of the enhancement of mechanical properties on GFRP reinforced with MWCNTs and graphene powders. GFRP composites were fabricated with variations in the amount of nano fillers in percentage weights of 2%, 4%, 6%, 8% and 10% wt. MWCNTs and graphene powders. The method used for reinforcement of resin with nano fillers was ultrasonication method meant for avoiding voids. A tendency for the mechanical properties to deteriorate was observed when nano fillers added were beyond certain weights of MWCNTs and graphene powders. This could be due to the agglomeration of nano fillers that change the fibre/matrix interface. Graphene nano fillers opts to be better compared to MWCNTs since the fabricated graphene reinforced glass fibre specimens have a better performance than GFRP specimens reinforced with MWCNTs.


2016 ◽  
Vol 1 (2) ◽  
Author(s):  
Jagdale Pravin ◽  
Aamer. A. Khan ◽  
Rovere Massimo ◽  
Rosso Carlo ◽  
Tagliaferro Alberto

Carbon nanotubes (CNTs), a rather fascinating material, are among the pillars of nanotechnology. CNTs exhibit unique electrical, mechanical, adsorption, and thermal properties with high aspect ratio, exceptional stiffness, excellent strength, and low density, which can be exploited in the manufacturing of revolutionary smart nano composite materials. The demand for lighter and stronger polymer composite material in various applications is increasing every day. Among all the possibilities to research and exploit the exceptional properties of CNTs in polymer composites we focused on the reinforcement of epoxy resin with different types of multiwalled carbon nano tubes (MWCNTs). We studied mechanical properties such as stress, strain, ultimate tensile strength, yield point, modulus and fracture toughness, and Young's modulus by plotting and calculating by means of the off-set method. The mechanical strength of epoxy composite is increased intensely with 1 and 3 wt.% of filler.


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