Tertiary Alkylative Suzuki-Miyaura couplings
Keyword(s):
The Suzuki-Miyaura coupling is extremely useful to construct Csp2-Csp2 carbon bonds. On the other hand, Csp2-Csp3 coupling reactions are do not work well, and tert-alkylative Suzuki-Miyaura coupling is particularly challenging due to problematic oxidative addition and beta-hydride elimination side reactions. In this short review, we will introduce recent examples of tert-alkylative Suzuki-Miyaura couplings with tert-alkyl electrophiles or -boron reagents. The review will mainly focus on catalyst and product structures and the proposed mechanisms .
2016 ◽
Vol 01
(01)
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pp. 27
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2012 ◽
Vol 07
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pp. 165-173
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1994 ◽
Vol 67
(2)
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pp. 299-313
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1980 ◽
Vol 45
(10)
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pp. 2847-2854
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1999 ◽
Vol 173
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pp. 249-254
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1969 ◽
Vol 27
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pp. 6-7
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1980 ◽
Vol 38
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pp. 30-33
2005 ◽
Vol 19
(3)
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pp. 129-132
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