Revisiting petroleum systems in the Gippsland Basin using new geochemical data
The Gippsland Basin is one of the most prolific petroleum provinces in Australia, yet the understanding of source, migration and secondary alteration of petroleum is often based on data and concepts that have been developed decades ago. For instance, the Gippsland Basin is commonly cited as an explicit example of a province dominated by oil from coal, yet there is no literature using molecular and isotope geochemistry explicitly demonstrating that generation and expulsion has been from the coal seams and not the intervening carbonaceous mudstones. In this study we will present insights from the evaluation of quantitative analyses of aromatic hydrocarbons, which will be evaluated together with low molecular weight hydrocarbon distributions from whole oil gas chromatography and aliphatic biomarker distributions of the oils. Oils are commonly incrementors of different charge events, and hence extending molecular and isotopic information from a wide molecular weight range offers a more detailed insight into the charge history of an oil field. Oil-bearing fluid inclusions are additional archives that hold keys to the fill history of petroleum reservoirs, and this contribution will also present new data on the distribution and composition of palaeo-oils trapped in fluid inclusions. Lastly, examples will be presented of how modern tools for analysis such as compound specific isotopic analysis (CSIA) of n-alkanes and isoprenoids as well as how understanding relationships between organic facies and source rock kinetics can contribute to refining our understanding of petroleum systems in the Gippsland Basin.