Correlation between the emulsion oligomerization parameters for C9 fraction and the characteristics of hydrocarbon resins

This paper investigates the production of hydrocarbon resins by emulsion oligomerization of the С9 fraction hydrocarbons in liquid by-products of oil refining. Such oligomers have a wide range of applications as film-forming agents in paints and anti-color coatings. Emulsion oligomerization was carried out using emulsifiers of the first and second kind. The study was performed at different values of the reaction temperature of the reaction duration, the intensity of agitation; concentrations of the emulsifier; С9:water fraction ratio. The resulting products were estimated according to the following indicators: the yield, unsaturation degree, softening temperature, mean molecular weight, color. Statistical analysis was carried out, the correlation of parameters of emulsion oligomerization and the yield and characteristics of oligomers was established. Given that, it would be possible to establish the optimal conditions for emulsion oligomerization and predict the properties of the products obtained. Specifically, it was established that the yield of hydrocarbon resins does not correlate with the reaction temperature (0.15 and 0.30) and the concentration of emulsifiers (0.08 and 0.03). It was proven that in the intervals studied the variable yield of oligomers depends on the duration of the reaction (correlation 0.88 and 0.81). In the case of oligomerization in the reverse emulsion, a significant correlation with the yield is also demonstrated by agitation intensity (0.51) and a С9:water fraction ratio (0.51). That has made it possible to derive an equation of the yield multiple linear regression dependent on the most significant process parameters. The high values of the yield and bromine number correlation (0.94 and 0.93) give grounds to argue about the progress of oligomerization reaction. The relationship among the characteristics of oligomers has been confirmed. This indicates the possibility of directed adjustment of certain characteristics of hydrocarbon resins.

Caught in the Act: Core-powered Mass-loss Predictions for Observing Atmospheric Escape

Past studies have demonstrated that atmospheric escape by the core-powered mass-loss mechanism can explain a multitude of observations associated with the radius valley that separates the super-Earth and sub-Neptune planet populations. Complementing such studies, in this work, we present a shortlist of planets that could be losing their atmospheres today if their evolution is indeed primarily dictated by core-powered mass-loss. We use Bayesian inference analysis on our planet evolution and mass-loss model to estimate the posteriors of the parameters that encapsulate the current state of a given planet, given their published masses, radii and host star properties. Our models predict that the following planets could be losing their atmospheres today at a rate ≳ 107 g/s at 50% confidence level: pi Men c, Kepler-60 d, Kepler-60 b, HD 86226 c, EPIC 249893012 b, Kepler-107 c, HD 219134 b, Kepler-80 e, Kepler-138 d and GJ 9827 d. As a by-product of our Bayesian inference analysis, we were also able to identify planets that most-likely harbor either secondary atmospheres abundant with high mean-molecular weight species, low-density interiors abundant with ices, or both. The planets belonging to this second category are WASP-47 e, Kepler-78 b, Kepler-10 b, CoRoT-7 b, HD 80653 b, 55 Cnc e and Kepler-36 b. While the aforementioned lists are by no means exhaustive, we believe that candidates presented here can serve as useful input for target selection for future surveys and for testing the importance of core-powered mass-loss in individual planetary systems.

To cool is to keep: residual H/He atmospheres of super-Earths and sub-Neptunes

ABSTRACT Super-Earths and sub-Neptunes are commonly thought to have accreted hydrogen/helium envelopes, consisting of a few to ten percent of their total mass, from the primordial gas disc. Subsequently, hydrodynamic escape driven by core-powered mass-loss and/or photoevaporation likely stripped much of these primordial envelopes from the lower mass and closer-in planets to form the super-Earth population. In this work, we show that after undergoing core-powered mass-loss, some super-Earths can retain small residual H/He envelopes. This retention is possible because, for significantly depleted atmospheres, the density at the radiative–convective boundary drops sufficiently such that the cooling time-scale becomes shorter than the mass-loss time-scale. The residual envelope is therefore able to contract, terminating further mass-loss. Using analytic calculations and numerical simulations, we show that the mass of primordial H/He envelope retained as a fraction of the planet’s total mass, fret, increases with increasing planet mass, Mc, and decreases with increasing equilibrium temperature, Teq, scaling as $f_\mathrm{ret} \propto M_\mathrm{c}^{3/2} T_\mathrm{eq}^{-1/2} \exp {[M_\mathrm{c}^{3/4} T_\mathrm{eq}^{-1}]}$. fret varies from <10−8 to about 10−3 for typical super-Earth parameters. To first order, the exact amount of left-over H/He depends on the initial envelope mass, the planet mass, its equilibrium temperature, and the envelope’s opacity. These residual hydrogen envelopes reduce the atmosphere’s mean molecular weight compared to a purely secondary atmosphere, a signature observable by current and future facilities. These remnant atmospheres may, however, in many cases be vulnerable to long-term erosion by photoevaporation. Any residual hydrogen envelope likely plays an important role in the long-term physical evolution of super-Earths, including their geology and geochemistry.

Losing oceans: The effects of composition on the thermal component of impact-driven atmospheric loss

ABSTRACT The formation of the Solar system’s terrestrial planets concluded with a period of giant impacts. Previous works examining the volatile loss caused by the impact shock in the moon-forming impact find atmospheric losses of at most 20–30 per cent and essentially no loss of oceans. However, giant impacts also result in thermal heating, which can lead to significant atmospheric escape via a Parker-type wind. Here we show that H2O and other high-mean molecular weight outgassed species can be efficiently lost through this thermal wind if present in a hydrogen-dominated atmosphere, substantially altering the final volatile inventory of terrestrial planets. We demonstrate that a giant impact during terrestrial planet formation can remove several Earth oceans’ worth of H2O, and other heavier volatile species, together with a primordial hydrogen-dominated atmosphere. These results may offer an explanation for the observed depletion in Earth’s light noble gas budget and for its depleted xenon inventory, which suggest that Earth underwent significant atmospheric loss by the end of its accretion. Because planetary embryos are massive enough to accrete primordial hydrogen envelopes and because giant impacts are stochastic and occur concurrently with other early atmospheric evolutionary processes, our results suggest a wide diversity in terrestrial planet volatile budgets.

Hurricanes on tidally locked terrestrial planets: fixed surface temperature experiments

Aims. In this work, we study the presence of hurricanes on exoplanets. Tidally locked terrestrial planets around M dwarfs are the main targets of space missions looking to discover habitable exoplanets. The question of whether hurricanes can form on this kind of planet is important for determining their climate and habitability. Methods. Using a high-resolution global atmospheric circulation model, we investigated whether there are hurricanes on tidally locked terrestrial planets under fixed surface temperatures (TS). The relevant effects of the planetary rotation rate, surface temperature, and bulk atmospheric compositions were examined. Results. We find that hurricanes can form on the planets but not on all of them. For planets near the inner edge of the habitable zone of late M dwarfs, there are more numerous and stronger hurricanes on both day and night sides. For planets in the middle and outer ranges of the habitable zone, the possibility of hurricane formation is low or even close to zero, as has been suggested in recent studies. Earth-based hurricane theories are applicable to tidally locked planets only when the atmospheric compositions are similar to that of Earth. However, if the background atmosphere is lighter than H2O, hurricanes can hardly be produced because convection is always inhibited due to the effect of the mean molecular weight, similarly to the case of Saturn. These results have broad implications on the precipitation, ocean mixing, climate, and atmospheric characterization of tidally locked planets. Finally, A test with a coupled slab ocean and an Earth-like atmosphere in a tide-locked orbit of ten Earth days demonstrates that there are also hurricanes present in the experiment.

Mineral cloud and hydrocarbon haze particles in the atmosphere of the hot Jupiter JWST target WASP-43b

Context. Having a short orbital period and being tidally locked makes WASP-43b an ideal candidate for the James Webb Space Telescope (JWST) phase curve measurements. Phase curve observations of an entire orbit will enable the mapping of the atmospheric structure across the planet, with different wavelengths of observation allowing different atmospheric depths to be seen. Aims. We provide insight into the details of the clouds that may form on WASP-43b and their impact on the remaining gas phase, in order to prepare the forthcoming interpretation of the JWST and follow-up data. Methods. We follow a hierarchical modelling strategy. We utilise 3D GCM results as input for a kinetic, non-equilibrium model for mineral cloud particles and for a kinetic model to study a photochemically-driven hydrocarbon haze component. Results. Mineral condensation seeds form throughout the atmosphere of WASP-43b. This is in stark contrast to the ultra-hot Jupiters, such as WASP-18b and HAT-P-7b. The dayside is not cloud free but it is loaded with few yet large mineral cloud particles in addition to hydrocarbon haze particles of a comparable abundance. Photochemically driven hydrocarbon haze appears on the dayside, but it does not contribute to the cloud formation on the nightside. The geometrical cloud extension differs across the globe due to the changing thermodynamic conditions. Day and night differ by 6000 km in pressure scale height. As reported for other planets, the C/O is not constant throughout the atmosphere and varies between 0.74 and 0.3. The mean molecular weight is approximately constant in a H2-dominated WASP-43b atmosphere because of the moderate day/night-temperature differences compared to the super-hot Jupiters. Conclusions. WASP-43b is expected to be fully covered in clouds which are not homogeneously distributed throughout the atmosphere. The dayside and the terminator clouds are a combination of mineral particles of locally varying size and composition as well as of hydrocarbon hazes. The optical depth of hydrocarbon hazes is considerably lower than that of mineral cloud particles such that a wavelength-dependent radius measurement of WASP-43b would be determined by the mineral cloud particles but not by hazes.

Drag Reduction Performance of Mechanically Degraded Dilute Polyethylene Oxide Solutions

Mechanical degradation of dilute solutions of polyethylene oxide (PEO) via chain scission was investigated within a turbulent pipe flow. Comparisons of the drag reduction performance with and without degradation were made by matching the onset of drag reduction conditions, which has been shown for PEO to be related to the mean molecular weight. The bulk flow behavior of both the degraded and nondegraded samples were generally consistent with trends observed in the literature, but a subset of conditions showed significant deviation in the slope increment (drag reduction performance) between the degraded and nondegraded samples. When they deviated, the degraded samples were consistently more efficient than the nondegraded samples even though they had the same mean molecular weight. The deviations were shown to scale with the normalized difference between the initial and final molecular weights. The current data and analysis as well as the literature suggest that the deviations in the polymer performance (slope increment) are related to changes in the molecular weight distribution. More specifically, the improved performance of the degraded samples relative to the nondegraded ones at the mean molecular weight of the degraded sample indicates an excess of longer polymer chains since the higher chain fractions in a degraded solution more effectively control the flow properties when within a certain degree of degradation and Reynolds number.

Properties of sub-Neptune atmospheres: TOI-270 system

ABSTRACT We investigate the potential for the James Webb Space Telescope (JWST) to detect and characterize the atmospheres of the sub-Neptunian exoplanets in the TOI-270 system. Sub-Neptunes are considered more likely to be water worlds than gas dwarfs. We model their atmospheres using three atmospheric compositions – two examples of hydrogen-dominated atmospheres and a water-dominated atmosphere. We then simulate the infrared transmission spectra of these atmospheres for JWST instrument modes optimized for transit observation of exoplanet atmospheres: NIRISS, NIRSpec, and MIRI. We then predict the observability of each exoplanet’s atmosphere. TOI-270c and d are excellent targets for detecting atmospheres with JWST transmission spectroscopy, requiring only 1 transit observation with NIRISS, NIRSpec, and MIRI; higher signal-to-noise ratio can be obtained for a clear H-rich atmosphere. Fewer than three transits with NIRISS and NIRSpec may be enough to reveal molecular features. Water-dominated atmospheres require more transits. Water spectral features in water-dominated atmospheres may be detectable with NIRISS in two or three transits. We find that the detection of spectral features in a cloudy, H-rich atmosphere does not require integrations as long as those required for the water-dominated atmosphere, which is consistent with the differences in atmospheric mean molecular weight. TOI-270c and d could be prime targets for JWST transit observations of sub-Neptune atmospheres. These results provide useful predictions for observers who may propose to use JWST to detect and characterize the TOI-270 planet atmospheres.

Modelling the He I triplet absorption at 10 830 Å in the atmosphere of HD 209458 b

Context. HD 209458 b is an exoplanet with an upper atmosphere undergoing blow-off escape that has mainly been studied using measurements of the Lyα absorption. Recently, high-resolution measurements of absorption in the He I triplet line at 10 830 Å of several exoplanets (including HD 209458 b) have been reported, creating a new opportunity to probe escaping atmospheres. Aims. We aim to better understand the atmospheric regions of HD 209458 b from where the escape originates. Methods. We developed a 1D hydrodynamic model with spherical symmetry for the HD 209458 b thermosphere coupled with a non-local thermodynamic model for the population of the He I triplet state. In addition, we performed high-resolution radiative transfer calculations of synthetic spectra for the helium triplet lines and compared them with the measured absorption spectrum in order to retrieve information about the atmospheric parameters. Results. We find that the measured spectrum constrains the [H]/[H+] transition altitude occurring in the range of 1.2 RP–1.9 RP. Hydrogen is almost fully ionised at altitudes above 2.9 RP. We also find that the X-ray and extreme ultraviolet absorption takes place at effective radii from 1.16 to 1.30 RP, and that the He I triplet peak density occurs at altitudes from 1.04 to 1.60 RP. Additionally, the averaged mean molecular weight is confined to the 0.61–0.73 g mole−1 interval, and the thermospheric H/He ratio should be larger than 90/10, and most likely approximately 98/2. We also provide a one-to-one relationship between mass-loss rate and temperature. Based on the energy-limited escape approach and assuming heating efficiencies of 0.1–0.2, we find a mass-loss rate in the range of (0.42–1.00) ×1011 g s−1 and a corresponding temperature range of 7125–8125 K. Conclusions. The analysis of the measured He I triplet absorption spectrum significantly constrains the thermospheric structure of HD 209458 b and advances our knowledge of its escaping atmosphere.