Influence of Compressed Carbon Dioxide on the Oxidation of Cyclohexane with Hydrogen Peroxide in Acetic Acid
Keyword(s):
The oxidation of cyclohexane with H2O2 in a compressed CO2/acetic acid binary system was studied at 60.0 and 80.0°C, at pressures up to 18 MPa, and with the zeolite TS-1 as catalyst. The phase behaviour of the reaction system was also observed. There are three fluid phases in the reaction system at lower pressure but two at higher pressures. In the three-phase region the yields of the products, cyclohexanol and cyclohexanone, increase considerably with increasing pressure and reaches a maximum near the phase-separating pressure. CO2 can thus enhance the reaction effectively. However, the effect of pressure on the yield is very limited after the transition to a two-phase system.
1971 ◽
Vol 26
(1)
◽
pp. 150-153
◽
Keyword(s):
Keyword(s):
Keyword(s):
Keyword(s):
Keyword(s):
Keyword(s):
Keyword(s):
1995 ◽
Vol 62
(2)
◽
pp. 257-267
◽
Keyword(s):
1980 ◽
Vol 298
(1442)
◽
pp. 495-540
◽