scholarly journals Programmable active kirigami metasheets with more freedom of actuation

2019 ◽  
Vol 116 (52) ◽  
pp. 26407-26413 ◽  
Author(s):  
Yichao Tang ◽  
Yanbin Li ◽  
Yaoye Hong ◽  
Shu Yang ◽  
Jie Yin
Keyword(s):  
Mechanical Properties ◽  
Degrees Of Freedom ◽  
Universal Design ◽  
Environmental Temperature ◽  
Mechanical Forces ◽  
Stimuli Responsive ◽  
Responsive Materials ◽  
Promising Strategy ◽  
Unit Cells ◽  
Potential Applications

Kirigami (cutting and/or folding) offers a promising strategy to reconfigure metamaterials. Conventionally, kirigami metamaterials are often composed of passive cut unit cells to be reconfigured under mechanical forces. The constituent stimuli-responsive materials in active kirigami metamaterials instead will enable potential mechanical properties and functionality, arising from the active control of cut unit cells. However, the planar features of hinges in conventional kirigami structures significantly constrain the degrees of freedom (DOFs) in both deformation and actuation of the cut units. To release both constraints, here, we demonstrate a universal design of implementing folds to reconstruct sole-cuts–based metamaterials. We show that the supplemented folds not only enrich the structural reconfiguration beyond sole cuts but also enable more DOFs in actuating the kirigami metasheets into 3 dimensions (3D) in response to environmental temperature. Utilizing the multi-DOF in deformation of unit cells, we demonstrate that planar metasheets with the same cut design can self-fold into programmable 3D kirigami metastructures with distinct mechanical properties. Last, we demonstrate potential applications of programmable kirigami machines and easy-turning soft robots.

scholarly journals Developing the structure–property relationship to design solid state multi-stimuli responsive materials and their potential applications in different fields

2018 ◽  
Vol 9 (14) ◽  
pp. 3592-3606 ◽  
Author(s):  
Bibhisan Roy ◽  
Mallu Chenna Reddy ◽  
Partha Hazra
Keyword(s):  
Charge Transfer ◽  
Solid State ◽  
Stimuli Responsive ◽  
Structure Property ◽  
Responsive Materials ◽  
Property Relationship ◽  
Structure Property Relationship ◽  
Potential Applications

Establishing the structure–property relationship for multi-stimuli responsive mechanochromic materials based on charge transfer luminogens.

scholarly journals Mechanical Bending and Modulation of Photoactuation Properties in a One-Dimensional Pb(II) Coordination Polymer

2021 ◽  
Author(s):  
Bibhuti Bhusan Rath ◽  
Jagadese J. Vittal
Keyword(s):  
Mechanical Properties ◽  
Plastic Deformation ◽  
Coordination Polymer ◽  
Elastic Deformation ◽  
Coordination Polymers ◽  
Stimuli Responsive ◽  
Responsive Materials ◽  
One Dimensional ◽  
Different Shapes ◽  
Mechanical Bending

With emergent research on stimuli responsive materials, dynamic crystals are at the forefront of investigation. However, research on the mechanical properties of coordination polymers (CPs) is still in its infancy. Elastic deformation induced by pressure and photoactuation are rare occurrences in CPs, let alone their combination in a single CP. Here, we report a one-dimensional (1D) CP comprising PbBr2 chains with 3-fluoro-4’-styrylpyridine arms showing excellent elasticity and photomechanical properties. A slender crystal can be bent to make a circle and write different shapes with restoration of original shape upon removal of the applied force. In addition, photomechanical properties triggered by [2+2] cycloaddition of the olefinic ligand can be modulated easily by variation of the crystal sizes. Crystals with bigger width show destructive photosalient effects while the smaller ones show plastic deformation like bending, twisting, curling etc. upon UV irradiation. This example provides avenue for designing CPs for multi-stimuli responsive actuating properties.

scholarly journals 2D Dynamic Directional Amplification (DDA) in Phononic Metamaterials

Materials ◽  
2021 ◽  
Vol 14 (9) ◽  
pp. 2302
Author(s):  
Moris Kalderon ◽  
Andreas Paradeisiotis ◽  
Ioannis Antoniadis
Keyword(s):  
Degrees Of Freedom ◽  
Damping Ratio ◽  
Low Frequency ◽  
Vibration Isolators ◽  
Spatial Periodicity ◽  
Unit Cells ◽  
Acoustic Waveguides ◽  
Potential Applications ◽  
Propagation Properties

Phononic structures with unit cells exhibiting Bragg scattering and local resonance present unique wave propagation properties at wavelengths well below the regime corresponding to bandgap generation based on spatial periodicity. However, both mechanisms show certain constraints in designing systems with wide bandgaps in the low-frequency range. To face the main practical challenges encountered in such cases, including heavy oscillating masses, a simple dynamic directional amplification (DDA) mechanism is proposed as the base of the phononic lattice. This amplifier is designed to present the same mass and use the same damping element as a reference two-dimensional (2D) phononic metamaterial. Thus, no increase in the structure mass or the viscous damping is needed. The proposed DDA can be realized by imposing kinematic constraints to the structure’s degrees of freedom (DoF), improving inertia and damping on the desired direction of motion. Analysis of the 2D lattice via Bloch’s theory is performed, and the corresponding dispersion relations are derived. The numerical results of an indicative case study show significant improvements and advantages over a conventional phononic structure, such as broader bandgaps and increased damping ratio. Finally, a conceptual design indicates the usage of the concept in potential applications, such as mechanical filters, sound and vibration isolators, and acoustic waveguides.

scholarly journals Programmable Stimuli-Responsive Actuators for Complex Motions in Soft Robotics: Concept, Design and Challenges

Actuators ◽  
2020 ◽  
Vol 9 (4) ◽  
pp. 131
Author(s):  
Gilles Decroly ◽  
Antoniya Toncheva ◽  
Loïc Blanc ◽  
Jean-Marie Raquez ◽  
Thomas Lessinnes ◽  
...  
Keyword(s):  
Material Science ◽  
Degrees Of Freedom ◽  
Soft Materials ◽  
Soft Robotics ◽  
Concept Design ◽  
Stimuli Responsive ◽  
Responsive Materials ◽  
Stimulus Responsive ◽  
Future Challenges ◽  
Soft Actuators

During the last years, great progress was made in material science in terms of concept, design and fabrication of new composite materials with conferred properties and desired functionalities. The scientific community paid particular interest to active soft materials, such as soft actuators, for their potential as transducers responding to various stimuli aiming to produce mechanical work. Inspired by this, materials engineers today are developing multidisciplinary approaches to produce new active matters, focusing on the kinematics allowed by the material itself more than on the possibilities offered by its design. Traditionally, more complex motions beyond pure elongation and bending are addressed by the robotics community. The present review targets encompassing and rationalizing a framework which will help a wider scientific audience to understand, sort and design future soft actuators and methods enabling complex motions. Special attention is devoted to recent progress in developing innovative stimulus-responsive materials and approaches for complex motion programming for soft robotics. In this context, a challenging overview of the new materials as well as their classification and comparison (performances and characteristics) are proposed. In addition, the great potential of soft transducers are outlined in terms of kinematic capabilities, illustrated by the related application. Guidelines are provided to design actuators and to integrate asymmetry enabling motions along any of the six basic degrees of freedom (translations and rotations), and strategies towards the programming of more complex motions are discussed. As a final note, a series of manufacturing methods are described and compared, from molding to 3D and 4D printing. The review ends with a Perspectives section, from material science and microrobotic points of view, on the soft materials’ future and close future challenges to be overcome.

scholarly journals Mechanical Bending and Modulation of Photoactuation Properties in a One-Dimensional Pb(II) Coordination Polymer

2021 ◽  
Author(s):  
Bibhuti Bhusan Rath ◽  
Jagadese J. Vittal
Keyword(s):  
Mechanical Properties ◽  
Plastic Deformation ◽  
Coordination Polymer ◽  
Elastic Deformation ◽  
Coordination Polymers ◽  
Stimuli Responsive ◽  
Responsive Materials ◽  
One Dimensional ◽  
Different Shapes ◽  
Mechanical Bending

With emergent research on stimuli responsive materials, dynamic crystals are at the forefront of investigation. However, research on the mechanical properties of coordination polymers (CPs) is still in its infancy. Elastic deformation induced by pressure and photoactuation are rare occurrences in CPs, let alone their combination in a single CP. Here, we report a one-dimensional (1D) CP comprising PbBr2 chains with 3-fluoro-4’-styrylpyridine arms showing excellent elasticity and photomechanical properties. A slender crystal can be bent to make a circle and write different shapes with restoration of original shape upon removal of the applied force. In addition, photomechanical properties triggered by [2+2] cycloaddition of the olefinic ligand can be modulated easily by variation of the crystal sizes. Crystals with bigger width show destructive photosalient effects while the smaller ones show plastic deformation like bending, twisting, curling etc. upon UV irradiation. This example provides avenue for designing CPs for multi-stimuli responsive actuating properties.

scholarly journals Helical Actuators Inspired by Chiral Seedpod Opening and Tendril Coiling

2018 ◽  
Author(s):  
Guangchao Wan ◽  
Congran Jin ◽  
Ian Trase ◽  
Shan Zhao ◽  
Zi Chen
Keyword(s):  
Multiwall Carbon Nanotubes ◽  
Artificial Muscles ◽  
Stimuli Responsive ◽  
Helical Structures ◽  
Responsive Materials ◽  
Intelligent Machines ◽  
Essential Components ◽  
Potential Applications ◽  
External Stimuli ◽  
Tendril Coiling

Actuators are essential components for intelligent machines that can fulfill certain tasks in response to environmental stimuli. In recent years, actuators that can transform from a 2D ribbon shape to a 3D helical configuration under certain external stimuli have attracted significant attention due to the potential applications of the targeted helical structures in springs, propulsion generation, and artificial muscles. Inspired by the chiral opening of Bauhinia variegate‘s seedpods and the coiling of the Towel Gourd tendril with perversions, researchers have made significant breakthroughs in synthesizing state-of-the-art actuators capable of mimicking helical transformations. In this review, we give a brief overview of the shape evolution mechanisms of these two plant structures and then review recent progress in the fabrication of biomimetic helical actuators. These structures are categorized by the stimuli-responsive materials involved, including hydrogels, liquid crystal networks/elastomers, shape memory polymers, and multiwall carbon nanotubes. By providing this survey on important recent advances along with our perspectives, we hope to solicit new inspirations and insights on the development and fabrication of smart actuators, as well as the future development of interdisciplinary research at the interface of physics, engineering, and biology.

Smart Polymers and their Applications: A Review

2017 ◽  
Vol 8 (03) ◽  
Author(s):  
Gore S. A. ◽  
Gholve S. B. ◽  
Savalsure S. M. ◽  
Ghodake K. B. ◽  
Bhusnure O. G. ◽  
...  
Keyword(s):  
Oil Recovery ◽  
Water Soluble ◽  
Solution Temperature ◽  
Smart Polymers ◽  
Stimuli Responsive ◽  
Responsive Materials ◽  
Water Soluble Polymers ◽  
Commercial Applications ◽  
Stimuli Sensitive ◽  
External Stimuli

Smart polymers are materials that respond to small external stimuli. These are also referred as stimuli responsive materials or intelligent materials. Smart polymers that can exhibit stimuli-sensitive properties are becoming important in many commercial applications. These polymers can change shape, strength and pore size based on external factors such as temperature, pH and stress. The stimuli include salt, UV irradiation, temperature, pH, magnetic or electric field, ionic factors etc. Smart polymers are very promising applicants in drug delivery, tissue engineering, cell culture, gene carriers, textile engineering, oil recovery, radioactive wastage and protein purification. The study is focused on the entire features of smart polymers and their most recent and relevant applications. Water soluble polymers with tunable lower critical solution temperature (LCST) are of increasing interest for biological applications such as cell patterning, smart drug release, DNA sequencing etc.

Sensitive Mechanocontrolled Luminescence in Cross-Linked Polymer Films

2019 ◽  
Author(s):  
Ayumu Karimata ◽  
Pradnya Patil ◽  
Eugene Khaskin ◽  
Sébastien Lapointe ◽  
robert fayzullin ◽  
...  
Keyword(s):  
Mechanical Stress ◽  
Polymer Films ◽  
Soft Matter ◽  
Small Strain ◽  
Visual Methods ◽  
Photoluminescence Intensity ◽  
Stimuli Responsive ◽  
Responsive Materials ◽  
Highly Sensitive ◽  
Mechanical Stretching

Direct translation of mechanical force into changes in chemical behavior on a molecular level has important implication not only for the fundamental understanding of mechanochemical processes, but also for the development of new stimuli-responsive materials. In particular, detection of mechanical stress in polymers via non-destructive methods is important in order to prevent material failure and to study the mechanical properties of soft matter. Herein, we report that highly sensitive changes in photoluminescence intensity can be observed in response to the mechanical stretching of cross-linked polymer films when using stable, (pyridinophane)Cu-based dynamic mechanophores. Upon stretching, the luminescence intensity increases in a fast and reversible manner even at small strain (< 50%) and applied stress (< 0.1 MPa) values. Such sensitivity is unprecedented when compared to previously reported systems based on organic mechanophores. The system also allows for the detection of weak mechanical stress by spectroscopic measurements or by direct visual methods.<br>

scholarly journals Dynamic Manipulation of THz Waves Enabled by Phase-Transition VO2 Thin Film

Nanomaterials ◽  
2021 ◽  
Vol 11 (1) ◽  
pp. 114
Author(s):  
Chang Lu ◽  
Qingjian Lu ◽  
Min Gao ◽  
Yuan Lin
Keyword(s):  
Optical Methods ◽  
Stimuli Responsive ◽  
Device Structure ◽  
Current State ◽  
Insulator Metal Transition ◽  
Potential Applications ◽  
Fs Laser ◽  
External Stimuli ◽  
Thz Applications ◽  
Thz Waves

The reversible and multi-stimuli responsive insulator-metal transition of VO2, which enables dynamic modulation over the terahertz (THz) regime, has attracted plenty of attention for its potential applications in versatile active THz devices. Moreover, the investigation into the growth mechanism of VO2 films has led to improved film processing, more capable modulation and enhanced device compatibility into diverse THz applications. THz devices with VO2 as the key components exhibit remarkable response to external stimuli, which is not only applicable in THz modulators but also in rewritable optical memories by virtue of the intrinsic hysteresis behaviour of VO2. Depending on the predesigned device structure, the insulator-metal transition (IMT) of VO2 component can be controlled through thermal, electrical or optical methods. Recent research has paid special attention to the ultrafast modulation phenomenon observed in the photoinduced IMT, enabled by an intense femtosecond laser (fs laser) which supports “quasi-simultaneous” IMT within 1 ps. This progress report reviews the current state of the field, focusing on the material nature that gives rise to the modulation-allowed IMT for THz applications. An overview is presented of numerous IMT stimuli approaches with special emphasis on the underlying physical mechanisms. Subsequently, active manipulation of THz waves through pure VO2 film and VO2 hybrid metamaterials is surveyed, highlighting that VO2 can provide active modulation for a wide variety of applications. Finally, the common characteristics and future development directions of VO2-based tuneable THz devices are discussed.

scholarly journals A Slot-Die Technique for the Preparation of Continuous, High-Area, Chitosan-Based Thin Films

Polymers ◽  
2021 ◽  
Vol 13 (10) ◽  
pp. 1566
Author(s):  
Oliver J. Pemble ◽  
Maria Bardosova ◽  
Ian M. Povey ◽  
Martyn E. Pemble
Keyword(s):  
Thin Films ◽  
Mechanical Properties ◽  
High Volume ◽  
Mechanical Anisotropy ◽  
Diverse Range ◽  
Direction Parallel ◽  
High Area ◽  
Wide Range ◽  
Slot Die ◽  
Potential Applications

Chitosan-based films have a diverse range of potential applications but are currently limited in terms of commercial use due to a lack of methods specifically designed to produce thin films in high volumes. To address this limitation directly, hydrogels prepared from chitosan, chitosan-tetraethoxy silane, also known as tetraethyl orthosilicate (TEOS) and chitosan-glutaraldehyde have been used to prepare continuous thin films using a slot-die technique which is described in detail. By way of preliminary analysis of the resulting films for comparison purposes with films made by other methods, the mechanical strength of the films produced was assessed. It was found that as expected, the hybrid films made with TEOS and glutaraldehyde both show a higher yield strength than the films made with chitosan alone. In all cases, the mechanical properties of the films were found to compare very favorably with similar measurements reported in the literature. In order to assess the possible influence of the direction in which the hydrogel passes through the slot-die on the mechanical properties of the films, testing was performed on plain chitosan samples cut in a direction parallel to the direction of travel and perpendicular to this direction. It was found that there was no evidence of any mechanical anisotropy induced by the slot die process. The examples presented here serve to illustrate how the slot-die approach may be used to create high-volume, high-area chitosan-based films cheaply and rapidly. It is suggested that an approach of the type described here may facilitate the use of chitosan-based films for a wide range of important applications.

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