Improved scaling law for the prediction of deuterium retention in beryllium co-deposits

2021 ◽  
Author(s):  
Anze Zaloznik ◽  
Matthew J Baldwin ◽  
Russell P Doerner ◽  
Gregory de Temmerman ◽  
Richard A Pitts
Keyword(s):  
Hydrogen Isotope ◽  
Deposition Temperature ◽  
Scaling Law ◽  
High Energy ◽  
Retention Mechanism ◽  
Particle Energy ◽  
First Wall ◽  
Temperature Deposition ◽  
Free Parameters ◽  
Deuterium Retention

Abstract Hydrogen isotope co-deposition with Be eroded from the first wall is expected to be the main fusion fuel retention mechanism in ITER. Since good fuel accounting is crucial for economic and safety reasons, reliable predictions of hydrogen isotope retention are needed. This study builds upon the well-established empirical De Temmerman scaling law [1] that predicts D/Be ratios in co-deposited layers based on deposition temperature, deposition rate, and deuterium particle energy. Expanding the data used in the original development of the scaling law with an additional dataset obtained with more recent measurements using a different technique to the original De Temmerman approach, allows us to obtain new values for free parameters and improve the prediction capabilities of the new scaling law. In an effort to improve the model even further, scaling with D2 background pressure was included and a new two-term model derived, describing D retention in low- and high-energy traps separately.

scholarly journals Ionization Dosimetry Principles for Conventional and Laser-Driven Clinical Particle Beams

2018 ◽  
Vol 3 (2) ◽  
Keyword(s):  
Ionizing Radiation ◽  
Heavy Particle ◽  
Absorbed Dose ◽  
High Energy ◽  
Particle Energy ◽  
Particle Accelerators ◽  
Carbon Ions ◽  
Particle Beams ◽  
Radiation Fields ◽  
Number Of Particles

In this paper after mentioning the clinical radiation fields of 20 keV-450 MeV/u, they are characterized by the number of particles and their energy. Particle energy is the quantity that determines radiation penetration at the depth at which the tumor is situated (Fig. 1). The number of particles (or beam intensity) is the second major quantity that assures the administration of the absorbed dose in the tumor. The first application shows the radiation levels planned for various radiation fields. Prior to interacting with the medium, the intensity (or energy fluence rate) allows the determination of energy density, energy, power and relativistic force. In the interaction process, it determines the absorbed dose, kerma and exposure. Non-ionizing radiations in the EM spectrum are used as negative energy waves to accelerate particles charged into special installations called particle accelerators. The particles extracted from the accelerator are the source of the corpuscular radiation for high-energy radiotherapy. Of these, light particle beams (electrons and photons) for radiotherapy are generated by betatron, linac, microtron, and synchrotron and heavy particle beams (protons and heavy ions) are generated by cyclotron, isochronous cyclotron, synchro-cyclotron and synchrotron. The ionization dosimetry method used is the ionization chamber for both indirectly ionizing radiation (photons and neutrons) and for directly ionizing radiation (electrons, protons and carbon ions). Because the necessary energies for hadrons therapy are relatively high, 50-250 MeV for protons and 100-450 MeV/u for carbon ions, the alternative to replace non-ionizing radiation with relativistic laser radiation for generating clinical corpuscular radiation through radiation pressure acceleration mechanism (RPA) is presented.

Nonequilibrium effects in α-particle-induced reactions in Cs and I

2000 ◽  
Vol 78 (2) ◽  
pp. 133-139 ◽  
Author(s):  
M K Bhardwaj ◽  
I A Rizvi ◽  
A K Chaubey
Keyword(s):  
Cross Sections ◽  
Gamma Ray ◽  
Theoretical Calculations ◽  
High Energy ◽  
Particle Energy ◽  
Substantial Contribution ◽  
Equilibrium Geometry ◽  
Activation Technique ◽  
Excitation Functions ◽  
Stacked Foil Activation Technique

The excitation functions for the reactions 127I(α,n)130Cs, 127I(α,2n)129Cs, 127I(α,4n)127Cs, 133Cs(α,2n)135La, and 133Cs(α,4n)133La have been measured up to 50 MeV alpha-particle energy using the stacked-foil activation technique and Ge(Li) gamma-ray spectroscopy. The measured cross sections were compared with theoretical calculations considering equilibrium as well as the pre-equilibrium geometry-dependent hybrid models of Blann. The high-energy tails of the excitation functions show a substantial contribution from pre-equilibrium emission. A general agreement is observed between the experimental results and theoretical predictions with an initial exciton configuration n0 = 4(2n + 2p + 0h).PACS No. 25.40-h

scholarly journals Inverse Compton Scattering in pulsar physics

1996 ◽  
Vol 160 ◽  
pp. 159-162
Author(s):  
G.J. Qiao
Keyword(s):  
Radio Emission ◽  
Compton Scattering ◽  
Low Frequency ◽  
Position Angle ◽  
High Energy ◽  
Particle Energy ◽  
Important Process ◽  
Frequency Wave ◽  
Inverse Compton Scattering ◽  
Inverse Compton

AbstractInverse Compton Scattering (ICS) is a very important process not only in inner gap physics, but also for radio emission. ICS of high energy particles with thermal photons is the dominant and a very efficient mechanism of the particle energy loss above the neutron star surface, and is an important process in causing gap breakdown. The pulsar distribution in theP−Pdiagram and the observed mode changing phenomenon of some pulsars can be expained by the sparking conditions due to ICS. ICS of the secondary particles with the low frequency wave from the inner gap sparking can be responsible for radio emission. In this ICS model, many observational features of pulsar radio emission can be explained, such as: one core and two conal emission components, their different emission altitudes and relative time delay effects; spectral behavior of pulse profiles; the behavior of the linear polarization and position angle.

ULTRAFINE GRAINED AND NANOSTRUCTURED MATERIALS FOR ADVANCED ENERGY APPLICATIONS

2008 ◽  
Vol 22 (18n19) ◽  
pp. 2887-2895 ◽  
Author(s):  
CONSTANTIN POLITIS
Keyword(s):  
Ball Milling ◽  
Power Plants ◽  
Nuclear Reactor ◽  
Fission Products ◽  
High Energy ◽  
Interfacial Behavior ◽  
First Wall ◽  
Energy Applications ◽  
Ultrafine Grained ◽  
Nanoscale Interactions

The understanding of nanoscale interactions of nuclear materials will help to mastering the complex behavior of actinides and of fission products, and the interfacial behavior of fuel-cladding under extreme conditions. Ultrafine grained and nanostructured engineering materials are also suggested as protective armors on the plasma-facing first wall of D-T fusion power plants. We review the constitution and preparation by arc-melting and ball milling of ultrafine grained materials for the advanced nuclear reactor fuels UC, UC-W, UN, UN- Mo , and UN-W. We report also the preparation of the first wall armour materials nano-W, nano W-Y alloys, nano-graphite, and nano- B 4 C by high energy ball milling and their characterization by metallography, XRD, DSC and HRTEM.

Additions and corrections: Transverse compression and the secondary H/D isotope effects in intramolecular SN2 methyl-transfer reactions

1998 ◽  
Vol 76 (3) ◽  
pp. 359-370 ◽  
Author(s):  
Saul Wolfe ◽  
Chan-Kyung Kim ◽  
Kiyull Yang ◽  
Noham Weinberg ◽  
Zheng Shi
Keyword(s):  
Transition State ◽  
Isotope Effect ◽  
Isotope Effects ◽  
High Energy ◽  
Retention Mechanism ◽  
Sigmatropic Rearrangement ◽  
Orbital Theory ◽  
Bending Vibration ◽  
Kinetic Isotope ◽  
Methyl Transfer

Using ab initio molecular orbital theory mainly at the 3-21+G level, intramolecular SN2 methyl transfer between two oxygens confined within a rigid template is found to proceed exclusively by a high energy retention mechanism when the oxygens are separated by three or four bonds, and by a high energy inversion mechanism when the oxygens are separated by six bonds. Both mechanisms exist when the oxygens are separated by five bonds. The CH3/CD3 kinetic isotope effects are normal (1.21-1.34) in the retention processes and inverse (0.66-0.81) in the inversion reactions. In the case of inversion, compression of C-H bonds of the transition state by structural effects in the plane perpendicular to the O-C-O plane increases the inverse isotope effect. The retention barriers are high because retention is inherently unfavorable, even when pericyclic stabilization of the transition state is possible. The inversion barriers are high because a rigid template cannot accommodate a linear O-CH3 -O structure, and the O-C-O bending vibration is stiff (the Eschenmoser effect). Using a novel design strategy, a nonrigid template has been found in which the barrier and the CH3/CD3 kinetic isotope effect are the same as in an intermolecular reaction.Key words: Eschenmoser effect, isotope effect, compression, SN2, sigmatropic rearrangement.

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