scholarly journals Top of line corrosion in gas-condensate pipelines

2021 ◽  
Vol 1201 (1) ◽  
pp. 012082
Author(s):  
M. Seiersten ◽  
A. Dugstad ◽  
J. Nossen ◽  
O. Sendstad
Keyword(s):  
Mass Transfer ◽  
Organic Acids ◽  
Aqueous Phase ◽  
Prediction Models ◽  
Gas Condensate ◽  
Liquid Droplets ◽  
Pipe Surface ◽  
Process Plant ◽  
The Difference ◽  
Monoethylene Glycol

Abstract Low alloyed carbon steel is the only viable material of construction for long pipelines transporting unprocessed gas-condensate. The water that condenses is highly corrosive because it contains dissolved acid gases, i.e., CO2, H2S and organic acids like acetic and formic acid. The high velocity gas also contains droplets of water and condensate, and these will deposit if they hit the steel surface. Monoethylene glycol (MEG) injected to prevent ice and hydrates must be considered when predicting the composition and corrosivity of the aqueous phases in the pipeline. The liquids gathering at the bottom of the pipe have a higher heat capacity than the gas, and the temperature at the top of the pipe will be slightly lower than at the bottom. As the produced fluids cool during the transport from the hot wells to the process plant, water will condense on the cold pipe surface and more at the top than at the bottom. The literature on Top-of-line corrosion (ToLC) has grown steadily since the first reported case in 1960. There are also several prediction models for ToLC. This review is an overview of the main factors that cause ToLC and how these are modelled. Mass transfer from the aqueous phase at the bottom to the top contribute to the condensation. Despite the low MEG to water ratio in the gas due to the difference in vapour pressure, the fraction of MEG in the condensing water may be considerable. The concentration of MEG in the aqueous phase at the top depends on the mass transfer from bottom. The same is the case for organic acids. Liquid droplets entrained in the gas may deposit top of line and contribute to the chemistry of the aqueous phase. Models for ToLC must thus not only predict the composition of the condensing phases but also the mass transfer to be able to estimate the corrosion rate.

Analysis and calculation of the process of low-pressure reverse osmosis during recycling of hygienic water

2019 ◽  
pp. 28-36
Author(s):  
Leonid S. Bobe ◽  
Nikolay A. Salnikov
Keyword(s):  
Mass Transfer ◽  
Reverse Osmosis ◽  
Life Support ◽  
Space Station ◽  
Low Pressure ◽  
Operating Pressure ◽  
Life Support System ◽  
Cleaning Agent ◽  
The Difference ◽  
Pressure Channel

Analysis and calculation have been conducted of the process of low-pressure reverse osmosis in the membrane apparatus of the system for recycling hygiene water for the space station. The paper describes the physics of the reverse osmosis treatment and determines the motive force of the process, which is the difference of effective pressures (operating pressure minus osmotic pressure) in the solution near the surface of the membrane and in the purified water. It is demonstrated that the membrane scrubbing action is accompanied by diffusion outflow of the cleaning agent components away from the membrane. The mass transfer coefficient and the difference of concentrations (and, accordingly, the difference of osmotic pressures) in the boundary layer of the pressure channel can be determined using an extended analogy between mass transfer and heat transfer. A procedure has been proposed and proven in an experiment for calculating the throughput of a reverse osmosis apparatus purifying the hygiene water obtained through the use of a cleaning agent used in sanitation and housekeeping procedures on Earth. Key words: life support system, hygiene water, water processing, low-pressure reverse osmosis, space station.

Possible application of approximate models for calculation of selectivity of consecutive reactions under the effect of mass transfer

1982 ◽  
Vol 47 (5) ◽  
pp. 1301-1309 ◽  
Author(s):  
František Kaštánek ◽  
Marie Fialová
Keyword(s):  
Mass Transfer ◽  
Numerical Method ◽  
Analytical Method ◽  
Approximate Analytical Method ◽  
Approximate Models ◽  
Consecutive Reactions ◽  
The Difference

The possibility of use of approximate models for calculation of selectivity of consecutive reactions is critically analysed. Simple empirical criteria are proposed which enable safer application of approximate analytical reactions. A more universal modification has been formulated by use of which the difference of selectivity calculated by the exact numerical method and by the approximate analytical method is at maximum 12%.

scholarly journals A Semi-Theoretical Model for Water Condensation: Dew Used in Conservation of Earthen Heritage Sites

Water ◽  
2020 ◽  
Vol 13 (1) ◽  
pp. 52
Author(s):  
Xiang He ◽  
Sijia Wang ◽  
Bingjian Zhang
Keyword(s):  
Mass Transfer ◽  
Theoretical Model ◽  
Field Experiments ◽  
Environmental Control ◽  
Mass Transfer Process ◽  
Formation Processes ◽  
Heritage Sites ◽  
Dew Formation ◽  
The Difference ◽  
Two Parameter

Dew is a common but important phenomenon. Though water is previously considered to be a threat to earthen heritage sites, artificial dew is showing potential in relic preservation. A model of dew prediction on earthen sites will be essential for developing preventive protection methods, but studies of dew formation processes on relics are limited. In this study, a two parameter model is proposed. It makes approximations according to the features of earthen heritage sites, assuming that a thin and steady air layer exists close to the air–solid interface. This semi-theoretical model was based on calculations of the mass transfer process in the air layer, and was validated by simulations of laboratory experiments (R > 0.9) as well as field experiments. Additionally, a numerical simulation, performed by the commercial software COMSOL, confirmed that the difference between fitting parameter δ and the thickness of assumed mass transfer field was not significant. This model will be helpful in developing automatic environmental control systems for stabilizing water and soluble salts, thus enhancing preventive protection of earthen heritage sites.

scholarly journals Ripeness Prediction of Postharvest Kiwifruit Using a MOS E-Nose Combined with Chemometrics

Sensors ◽  
2019 ◽  
Vol 19 (2) ◽  
pp. 419 ◽  
Author(s):  
Dongdong Du ◽  
Jun Wang ◽  
Bo Wang ◽  
Luyi Zhu ◽  
Xuezhen Hong
Keyword(s):  
Prediction Models ◽  
Extraction Methods ◽  
Oxide Semiconductor ◽  
Soluble Solids ◽  
Support Vector ◽  
Least Squares Regression ◽  
Accuracy Rate ◽  
Linear Discriminant ◽  
The Difference ◽  
Ripe Stage

Postharvest kiwifruit continues to ripen for a period until it reaches the optimal “eating ripe” stage. Without damaging the fruit, it is very difficult to identify the ripeness of postharvest kiwifruit by conventional means. In this study, an electronic nose (E-nose) with 10 metal oxide semiconductor (MOS) gas sensors was used to predict the ripeness of postharvest kiwifruit. Three different feature extraction methods (the max/min values, the difference values and the 70th s values) were employed to discriminate kiwifruit at different ripening times by linear discriminant analysis (LDA), and results showed that the 70th s values method had the best performance in discriminating kiwifruit at different ripening stages, obtaining a 100% original accuracy rate and a 99.4% cross-validation accuracy rate. Partial least squares regression (PLSR), support vector machine (SVM) and random forest (RF) were employed to build prediction models for overall ripeness, soluble solids content (SSC) and firmness. The regression results showed that the RF algorithm had the best performance in predicting the ripeness indexes of postharvest kiwifruit compared with PLSR and SVM, which illustrated that the E-nose data had high correlations with overall ripeness (training: R2 = 0.9928; testing: R2 = 0.9928), SSC (training: R2 = 0.9749; testing: R2 = 0.9143) and firmness (training: R2 = 0.9814; testing: R2 = 0.9290). This study demonstrated that E-nose could be a comprehensive approach to predict the ripeness of postharvest kiwifruit through aroma volatiles.

scholarly journals Modelling of a hybrid culture system with a stationary layer of liquid perfluorochemical applied as oxygen carrier

2016 ◽  
Vol 37 (1) ◽  
pp. 149-158
Author(s):  
Maciej Pilarek ◽  
Katarzyna Dąbkowska
Keyword(s):  
Mass Transfer ◽  
Aqueous Phase ◽  
Culture System ◽  
Oxygen Carrier ◽  
Published Data ◽  
Monod Kinetics ◽  
Batch Cultures ◽  
Whole Process ◽  
Hybrid Culture ◽  
Stationary Layer

Abstract A mathematical model of a hybrid culture system supported with a stationary layer of liquid perfluorochemical (PFC) as a source of O2 for cells which grow in the aqueous phase of culture medium has been developed and discussed. The two-substrate Monod kinetics without inhibition effects, i.e. the Tsao-Hanson equation, has been assumed to characterise the biomass growth. The Damköhler number which relates the growth rate to the mass transfer effects has been used to appraise the regime (i.e. diffusion-limited or kinetics) of the whole process. The proposed model predicted accurately previously published data on the submerged batch cultures of Nicotiana tabacum BY-2 heterotrophic cells performed in a culture system supported with a stationary layer of hydrophobic perfluorodecalin as a liquid O2 carrier. Estimated values of the parameters of the model showed that the process proceeded in the kinetics regime and the growth kinetics, not the effects of the mass transfer between aqueous phase and liquid PFC, had essential influence on the growth of biomass.

A Practical Approach to Expedite a Pore to Process Simulation Model for a Rich Gas Condensate Reservoir – Case Study

2021 ◽  
Author(s):  
Mohamed Ibrahim Mohamed ◽  
Ahmed Mahmoud El-Menoufi ◽  
Eman Abed Ezz El-Regal ◽  
Ahmed Mohamed Ali ◽  
Khaled Mohamed Mansour ◽  
...  
Keyword(s):  
Simulation Model ◽  
Production Optimization ◽  
Operating Conditions ◽  
Gas Condensate ◽  
Western Desert ◽  
Design Parameters ◽  
Compositional Approach ◽  
Process Plant ◽  
Black Oil

Abstract Field development planning of gas condensate fields using numerical simulation has many aspects to consider that may lead to a significant impact on production optimization. An important aspect is to account for the effects of network constraints and process plant operating conditions through an integrated asset model. This model should honor proper representation of the fluid within the reservoir, through the wells and up to the network and facility. Obaiyed is one of the biggest onshore gas field in Egypt, it is a highly heterogeneous gas condensate field located in the western desert of Egypt with more than 100 wells. Three initial condensate gas ratios are existing based on early PVT samples and production testing. The initial CGRs as follows;160, 115 and 42 STB/MMSCF. With continuous pressure depletion, the produced hydrocarbon composition stream changes, causing a deviation between the design parameters and the operating parameters of the equipment within the process plant, resulting in a decrease in the recovery of liquid condensate. Therefore, the facility engineers demand a dynamic update of a detailed composition stream to optimize the system and achieve greater economic value. The best way to obtain this compositional stream is by using a fully compositional integrated asset model. Utilizing a fully compositional model in Obaiyed is challenging, computationally expensive, and impractical, especially during the history match of the reservoir numerical model. In this paper, a case study for Obaiyed field is presented in which we used an alternative integrated asset modeling approach comprising a modified black-oil (MBO) that results in significant timesaving in the full-field reservoir simulation model. We then used a proper de-lumping scheme to convert the modified black oil tables into as many components as required by the surface network and process plant facility. The results of proposed approach are compared with a fully compositional approach for validity check. The results clearly identified the system bottlenecks. The model can be used to propose the best tie-in location of future wells in addition to providing first-pass flow assurance indications throughout the field's life and under different network configurations. The model enabled the facility engineers to keep the conditions of the surface facility within the optimized operating envelope throughout the field's lifetime.

Applying electrohydrodynamic atomization to enhance mass transfer of metal salts from an aqueous phase towards ionic liquids

2016 ◽  
Vol 80 ◽  
pp. 1-7 ◽  
Author(s):  
Dries Parmentier ◽  
Anna Rybałtowska ◽  
Jasper van Smeden ◽  
Maaike C. Kroon ◽  
Jan C.M. Marijnissen ◽  
...  
Keyword(s):  
Mass Transfer ◽  
Ionic Liquids ◽  
Aqueous Phase ◽  
Metal Salts ◽  
Electrohydrodynamic Atomization ◽  
Enhance Mass

Selective Transport of Water-Soluble Proteins from Aqueous to Ionic Liquid Phase via a Temperature-Sensitive Phase Change of These Mixtures

2012 ◽  
Vol 65 (11) ◽  
pp. 1548 ◽  
Author(s):  
Yuki Kohno ◽  
Nobuhumi Nakamura ◽  
Hiroyuki Ohno
Keyword(s):  
Phase Change ◽  
Aqueous Phase ◽  
Selective Dissolution ◽  
Selective Extraction ◽  
Soluble Proteins ◽  
Water Soluble ◽  
Temperature Sensitive ◽  
Salting Out ◽  
Key Factor ◽  
The Difference

Mixtures of some ionic liquids (ILs) and water show reversible phase change between a homogeneous mixture and phase-separated state by a small change in temperature. Some water-soluble proteins have been migrated from the aqueous to the IL phase. When tetrabutylphosphonium 2,4,6-trimethylbenzenesulfonate was used as an IL, cytochrome c (Cyt.c) was found to be extracted from the water phase to the IL phase. Conversely, both horseradish peroxidase (HRP) and azurin remained in the aqueous phase. This selective extraction was comprehended to be due to the difference in solubility of these proteins in both phases. The separated aqueous phase contained a small amount of IL, which induced the salting-out of Cyt.c. On the other hand, condensed IL phase promoted the salting-in of Cyt.c. As a result, Cyt.c was preferably dissolved in the hydrated IL phase rather than aqueous phase. In the case of HRP, there was only a salting-out profile upon increasing the concentration of IL, which induced selective dissolution of HRP in the aqueous phase. These results clearly suggest that the profile of salting-out and salting-in for proteins is the key factor to facilitate the selective extraction of proteins from aqueous to the IL phase.

scholarly journals THE ACCUMULATION OF ELECTROLYTES

1932 ◽  
Vol 15 (6) ◽  
pp. 667-689 ◽  
Author(s):  
W. J. V. Osterhout ◽  
W. M. Stanley
Keyword(s):  
Steady State ◽  
Osmotic Pressure ◽  
Aqueous Phase ◽  
Thermodynamic Potential ◽  
Ph Value ◽  
Molecular Form ◽  
External Solution ◽  
Aqueous Layer ◽  
The Difference ◽  
Pass Through

Inasmuch as attempts to explain accumulation by the Donnan principle have failed in the case of Valonia, a hypothesis of the steady state has been formulated to explain what occurs. In order to see whether this hypothesis is in harmony with physico-chemical laws attempts have been made to imitate its chief features by means of a model. The model consists of a non-aqueous layer (representing the protoplasmic surface) placed between an alkaline aqueous phase (representing the external solution) and a more acid aqueous phase (representing the cell sap). The model reproduces most of the features of the hypothesis. Attention may be called to the following points. 1. The semipermeable surface is a continuous non-aqueous phase. 2. Potassium penetrates by combining with an acid HX in the non-aqueous layer to form KX which in turn reacts with an acid HA in the sap to form KA. Since KX is little dissociated in the non-aqueous layer potassium appears to pass through it chiefly in molecular form. 3. The internal composition depends on permeability, e.g., sodium penetrates less rapidly than potassium and in consequence potassium predominates over sodium in the "artificial sap." The order of penetration in the model is the same as in Valonia, i.e., K > Na > Ca > Mg, and Cl > SO4, but the quantitative resemblance is not close, e.g., the difference between potassium and sodium, and chloride and sulfate is much less in the model. 4. The formation of KA and NaA in the sap raises its osmotic pressure and water enters. 5. The concentration of potassium and sodium and the osmotic pressure become much greater inside than outside. For example, potassium may become 200 times as concentrated inside as outside. 6. No equilibrium occurs but a steady state is reached in which water and salt enter at the same rate so that the composition of the sap remains constant as its volume increases. 7. Since no equilibrium occurs there is a difference of thermodynamic potential between inside and outside. At the start the thermodynamic potential of KOH is much greater outside than inside. This difference gradually diminishes and in the steady state has about the same value as in Valonia. The difference in pH value between the internal and external solutions is also similar in both cases (about 2 pH units). 8. Accumulation does not depend on the presence of molecules or ions inside which are unable to pass out. One important feature of the hypothesis is not seen in the model: this is the exchange of HCO3 for Cl-. Experiments on this point are in progress.

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