The thermodynamics of intracrystalline sorption II. Argon in chabazite
The experimentally observed isotherms and entropies of the intracrystalline sorbed phase of argon in natural and calcium chabazites are compared with those predicted by models. For sorbate concentrations between approximately θ = 0.1 and 0.7, the experimental data are incompatible with the properties of a localized phase but are in agreement with those of a mobile phase. It is demonstrated that it is impossible for the argon to possess two degrees of translational freedom and that it is best described as having one translational degree of freedom and two vibrational degrees of freedom each with a frequency of 1 x 10 12 to 2 x 10 12 s -1 . The examination of the entropy of the system also shows that at concentrations greater than θ = 0.7 the mobile concept breaks down and it is probable that the translational degree of freedom passes to a vibration due to the mutual caging action of sorbate molecules, so that the phase becomes a system of oscillators.