scholarly journals IV. Physico-chemical determinations at high pressures by optical methods

In the course of his well-known investigations concerning the compressibility of gases and liquids, Amagat made some series of measurements taking observations through two small glass windows fitted to his high-pressure bomb (“méthode des regards”),* and he also twice made an attempt to use a similar arrangement for the determination of melting and crystallization at high pressures. His first paper on these subjects deals with the melting and with the formation of two different kinds of crystals of carbon tetrachloride. The highest pressure employed was 1,160 atmospheres. The second paper, in which a somewhat different arrangement of the glass windows was used, deals with the crystallization of ice at temperatures below zero under the influence of high pressures.^ In a summarizing paper Amagat§states that he occasionally was able to reach pressures of about 1,600 atmospheres before the glass windows were broken, but observations were not actually made at higher pressures than 1,000 atmospheres. In this paper a sketch of the apparatus is also given. Amagat states that he met with severe difficulties during these investigations, and he has not pursued the subject further. Later melting-points and transition-points of some “liquo-crystalline” substances have been measured in Jena glass tubes up to 300 atmospheres by Hullett, and other optical observations at pressures above that of the atmosphere have been made by Rothmund (maximum 500 atmospheres), Röntgen and Zehnder, Sierstema, Liveing and Dewar, Hutton and Petavel,§§ and Duffield, but in these investigations the pressures have, as a rule, not exceeded 100 atmospheres.

Apparatus for Optical Measurements at High Pressures . The apparatus consists of three chief units:— (1) Plant for the production and measurement of pressures up to 4000 kgrm./cm. 2 . (2) A “pressure-bomb” to hold the substances under investigation. (3) An optical bench for observations in polarised light, and for measurements of the change of refractive index, dispersion, rotatory power, absorption, double-refraction and optical-axial-angle, by pressure.


2018 ◽  
Vol 16 (1) ◽  
pp. 1227-1232 ◽  
Author(s):  
S. Anas Boussaa ◽  
A. Kheloufi ◽  
N. Boutarek Zaourar

AbstractDune sand, from Biskra, Algeria which is in the Great Algerian huge desert attracts tourists from all over the world. Dune sand composes around 80% of the total area of the desert. To date only a few studies have been conducted on this sand. The purpose of the present study is to shed light on the textural and physico-chemical characteristics of this sand using several characterization methods, and to understand the potential for using for photovoltaic applications. The chemical composition of Biskra sand indicated a high purity quartz with 97.6% silica, and a presence of others oxides. Granular analysis enabled the determination of the size of the sand grains which was found to be fine to medium. On the other hand, a Scanning Electron Microscopy and optical observations were carried out, the micrographs observations indicated the presence of different shapes of sand grain, some rounded whereas others are angular edged or elongated. X-ray diffraction indicates the highly crystalline nature of the Biskra sand.


1862 ◽  
Vol 4 ◽  
pp. 315-317
Author(s):  
J. A. Wanklyn

Considerable difficulties attend the preparation of zinc-methyl. Frankland, who discovered the body, obtained it by heating pure iodide of methyl and zinc enclosed in small glass tubes. Owing to the high temperature at which reaction takes place, much gas is formed; hence the operation must be confined to very small quantities of materials.No determination of the boiling-point, specific gravity, nor yet of the vapour density of zinc-methyl, was made by its discoverer; from which fact may be inferred how small was the product available for investigation.


2020 ◽  
pp. 23-33
Author(s):  
Elena A. Zaeva-Burdonskaya ◽  
Yuri V. Nazarov

This article addresses one of the most actively developing types of design activities – light design. The article comprises quotes of the leading Russian and foreign light design specialists published over the previous five years, as well as the authors’ own conclusions. The thoughts quoted in the article are sometimes opposite to each other and reflect the wide spectrum of professional practice. They reflect the initial opinions of analysts and experts which are often diverging. All of the specialists point at the interdisciplinary nature of the new profession, which imposes additional load on a designer overloaded enough already by the scope and speed of the problems being solved nowadays. The discussion of the new profession of light designer initiated on the pages of professional publications is especially important in view of the development of professional standards and standards of design and architectural education, as well as creation of new educational programmes based on various approaches to the subject in technical and humanitarian institutions. The goal of this article is to introduce light design into the field of fully legitimate sections of design culture, to define the authentic scientific basis of the new creative profession, to initiate a foundation for self-determination of the new synthetic area, which materially affects the state of the profession as a whole and the life standards of a wide variety of consumers. In order to reach the set goal, a comparative and analytical method of study was selected, which allows studying the problem to a large extent and from all angles and finding the ways of overcoming the challenges emerging in the area of the new activity.


Author(s):  
Evgeniya Mikhailovna Popova ◽  
Guzel Mukhtarovna Guseinova ◽  
Sergei Borisovich Milov

The deficit of subnational budgets and deceleration capital investments in multiple Russian regions increase the relevance of research aimed at improvement of tax incentivizing practice of the regional investment process. The studies focused on determination of the impact of socioeconomic and institutional factors upon the efficiency of investment tax expenses obtained wide circulation within the foreign scientific literature. The subject of this article is the assessment of sensitivity of the efficiency of regional tax expanses towards investment attractiveness of the types of economic activity carried out by the residents of territories of advanced socioeconomic development, created in the subjects of Far Easter Federal District. The scientific novelty and practical values of this research consists in substantiation of the reasonableness of assessment of investment attractiveness of the types of economic activity that are stimulated by tax incentives. Methodology for assessing investment attractiveness is proposed and tested. The conclusion is made that in case of low investment attractiveness of the type of economic activity, which was planned to support by tax incentives, it is required to conduct and additional analysis to avoid unjustified tax expanses.


2019 ◽  
Vol 15 (4) ◽  
pp. 312-318
Author(s):  
Shuoye Yang

Background: The therapeutic ability and application of antifungal peptide (APs) are limited by their physico-chemical and biological properties, the nano-liposomal encapsulation would improve the in vivo circulation and stability. </P><P> Objective: To develop a long-circulating liposomal delivery systems encapsulated APs-CGA-N12 with PEGylated lipids and cholesterol, and investigated through in vivo pharmacokinetics. Methods: The liposomes were prepared and characterized, a rapid and simple liquid chromatographytandem mass spectrometry (LC-MS/MS) assay was developed for the determination of antifungal peptide in vivo, the pharmacokinetic characteristics of APs liposomes were evaluated in rats. Results: Liposomes had a large, unilamellar structure, particle size and Zeta potential ranged from 160 to 185 nm and -0.55 to 1.1 mV, respectively. The results indicated that the plasma concentration of peptides in reference solutions rapidly declined after intravenous administration, whereas the liposomeencapsulated ones showed slower elimination. The AUC(0-∞) was increased by 3.0-fold in liposomes in comparison with standard solution (20 mg·kg-1), the half-life (T1/2) was 1.6- and 1.5-fold higher compared to the reference groups of 20 and 40 mg·kg-1, respectively. Conclusion: Therefore, it could be concluded that liposomal encapsulation effectively improved the bioavailability and pharmacokinetic property of antifungal peptides.


2019 ◽  
pp. 129-136 ◽  
Author(s):  
E. A. Khorova ◽  
A. V. Myshlyavtsev

The subject of the study were rubber mixtures based on hydrogenated butadiene-nitrile rubbers (HNBR) Therban, Zetpol, NBR-B with an acrylonitrile (AN) content of 34% to 49% and unsaturation of 0.9% to 22% with sulfuric, peroxide and sulfuric-peroxide cure systems. The purpose of the study was to determine the effect of the AN content and the degree of unsaturation of HNBR on the properties of rubbers in products designed for operation under the influence of fuels and oils at increased temperatures.The results of the determination of the mass swelling of rubbers in hydrocarbon media and the relative elongation in the process of thermal aging in air and in oil at increased temperatures are presented. The conclusion was made on the use of HNBR mixture with maximum content of AN (49%), with low (6%) and extremely low (0.9%) ODS content and sulfuric peroxide cure system to extend the product service temperature limit to 150°C.


Author(s):  
Chakravarthi Ram-Prasad

The Introduction outlines the various chapters. It then situates the question of ‘body’ in the modern Western philosophical tradition following Descartes, and argues that this leaves subsequent responses to come under one of three options: metaphysical dualism of body and subject; any anti-dualist reductionism; or the overcoming of the divide. Describing the Phenomenology of Merleau-Ponty as a potent example of the third strategy, the Introduction then suggests his philosophy will function as foil to the ecological phenomenology developed and presented in the book. Moreover, one approach within the Western Phenomenological tradition, of treating phenomenology as a methodology for the clarification of experience (rather than the means to the determination of an ontology of the subject) is compared to the approach in this book. Since classical India, while understanding dualism, did not confront the challenge of Descartes (for better or for worse), its treatment of body follows a different trajectory.


1998 ◽  
Vol 188 ◽  
pp. 388-389
Author(s):  
A. Kubota ◽  
K. Makishima ◽  
T. Dotani ◽  
H. Inoue ◽  
K. Mitsuda ◽  
...  

About 10 X-ray binaries in our Galaxy and LMC/SMC are considered to contain black hole candidates (BHCs). Among these objects, Cyg X-1 was identified as the first BHC, and it has led BHCs for more than 25 years(Oda 1977, Liang and Nolan 1984). It is a binary system composed of normal blue supergiant star and the X-ray emitting compact object. The orbital kinematics derived from optical observations indicates that the compact object is heavier than ~ 4.8 M⊙ (Herrero 1995), which well exceeds the upper limit mass for a neutron star(Kalogora 1996), where we assume the system consists of only two bodies. This has been the basis for BHC of Cyg X-1.


2021 ◽  
Vol 13 (3) ◽  
pp. 1232
Author(s):  
Natalie Szeligova ◽  
Marek Teichmann ◽  
Frantisek Kuda

The subject of the work is the research on relevant factors influencing participation in the success of brownfield revitalization, especially in the territory of small municipalities. Research has so far dealt with the issue of determining disparities in the municipalities of the Czech Republic, not excluding small municipalities, but their subsequent application has usually been presented in larger cities. The focus on smaller municipalities or cities was usually addressed only in general. The introduction provides an overview of theoretical knowledge in the field of brownfield revitalization. Defining the level of knowledge of the monitored issues is an essential step for the purposes of more effective determination of disparities. Disparities will be determined on the basis of information on localities that have been successfully revitalized. The identified disparities are then monitored in the territory of small municipalities. For the purposes of processing, it was determined that a small municipality or city is an area with a maximum of 5000 inhabitants. Using appropriately selected statistical methods, an overview of disparities and their weights is determined, which significantly affect the success of revitalization. In small municipalities, the issue of brownfields is not emphasized but, in terms of maintaining community strength and reducing population turnover, the reuse of brownfields is a crucial theme.


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