Origin of quasi-mosaic effect for symmetric skew planes in a silicon or germanium plate

2016 ◽  
Vol 49 (5) ◽  
pp. 1810-1813
Author(s):  
Valerio Bellucci ◽  
Riccardo Camattari ◽  
Gianfranco Paternò ◽  
Vincenzo Guidi ◽  
Andrea Mazzolari

Bent silicon and germanium crystals are used for several modern physics applications, above all for focusing of hard X-rays and for steering of charged particle beams by means of channeling and related coherent phenomena. In particular, anisotropic deformations are effectively exploited for these applications. A typical anisotropic deformation that is used is the quasi-mosaic (QM) curvature. It involves the bending of crystallographic planes that would be otherwise flat in the case of an isotropic medium. Here, the curvature the {110} planes was obtained through the quasi-mosaic effect in the symmetric configuration for the first time. This achievement is important because the {110} family of planes is highly efficient for both the applications mentioned above. Until now, the curvature of {110} planes in the QM configuration has not been used because it vanishes if the direction of the planes is aligned with the applied moment that bends the crystal plate. Indeed, to obtain the curvature of this particular family of crystallographic planes, the 〈110〉 direction has not to be aligned with respect to the imparted moment that bends the plate, i.e. the {110} planes have to be skew planes. Experimental verification of the quasi-mosaic curvature for the {110} planes was provided through hard X-ray diffraction at beamline ID15A of the European Synchrotron Radiation Facility in Grenoble, France, showing good agreement with the theoretical expectation.

2015 ◽  
Vol 48 (4) ◽  
pp. 977-989 ◽  
Author(s):  
Riccardo Camattari ◽  
Vincenzo Guidi ◽  
Valerio Bellucci ◽  
Andrea Mazzolari

`Quasi-mosaicity' is an effect of anisotropy in crystals that permits one to obtain a curvature of internal crystallographic planes that would be flat otherwise. The term `quasi-mosaicity' was introduced by O. Sumbaev in 1957. The concept of `quasi-mosaicity' was then retrieved about ten years ago and was applied to steering of charged-particle beams at the Super Proton Synchrotron at CERN. Beams were deviated by exploiting channeling and volume reflection phenomena in curved crystals that show the `quasi-mosaic' effect. More recently, a crystal of this kind was installed in the Large Hadron Collider at CERN for beam collimation by the UA9 collaboration. Since 2011, another important application involving the `quasi-mosaic' effect has been the focalization of hard X-rays and soft γ-rays. In particular, the possibility of obtaining both high diffraction efficiency and the focalization of a diffracted beam has been proved, which cannot be obtained using traditional diffracting crystals. A comprehensive survey of the physical properties of `quasi-mosaicity' is reported here. Finally, experimental demonstrations for adjustable values of the `quasi-mosaic' curvature are provided.


1936 ◽  
Vol 40 (309) ◽  
pp. 586-621 ◽  
Author(s):  
H. J. Gough ◽  
W. A. Wood

SummaryThe strengths of the metals at present available to industry are of especial importance to the aeronautical engineer who is also in a position to appreciate the need for greatly improved materials, the absence of which often places restriction on much needed developments. Although the materials of the future may become available by the somewhat fortuitous development methods at present employed, it is undeniable that greatly accelerated developments would result if a correct understanding was obtained of the fundamental characteristics of the cohesion and fracture of metals, of which the former belongs to the field of the atomic physicist.It has been found possible, for the first time, to show that failure under static and fatigue stressing is associated with changes in the crystalline structure which are identical. These changes are (1) a dislocation of the initially perfect grains into large components which vary in orientation from that of the internal grain by amounts up to about 2°,(2) the formation of “crystallites,” approximately 10-4 to 10-5 cm. in size, whose orientation varies widely from that of the original grains, and (3) the presence of severe internal stresses in the crystallites. At fracture, whatever the type of applied stressing, the whole of the specimen behaves to the X-ray beam as a medium of crystallites showing marked lattice distortion and oriented completely at random. X-ray diffraction methods are shown to distinguish clearly between the effects of the application of safe and unsafe ranges of stress; the first method that has been successful in this respect.In order to show the relationship between the new work described and previous work dealing with the use of X-rays in studying the deformation characteristics of metals, a preliminary section of the paper deals with cold-rolling and drawing. A survey is also presented of the present position regarding strength and atomic structure, together with references to various theories regarding the imperfections of crystals as encountered in practice. An introductory section describes briefly the atomic structure of metals, as revealed by X-rays.


2019 ◽  
Vol 26 (1) ◽  
pp. 96-101 ◽  
Author(s):  
R. Briggs ◽  
R. Torchio ◽  
A. Sollier ◽  
F. Occelli ◽  
L. Videau ◽  
...  

Time-resolved X-ray diffraction measurements have been carried out on dynamically compressed Sn up to a maximum pressure of ∼13 GPa at the European Synchrotron Radiation Facility. The phase transition from β-Sn to body-centered tetragonal (b.c.t.) Sn has been observed using synchrotron X-ray diffraction for the first time undergoing shock compression and release. Following maximum compression, the sample releases to lower pressures for several nanoseconds until the reverse transition occurs. The data are in good agreement with previous shock boundaries that indicate that the β-Sn phase is stable ∼2 GPa higher than the static boundary upon compression and the b.c.t.-Sn phase is stable ∼1 GPa lower upon release. The transition to the high-pressure phase reveals a loss of texture in the X-ray diffraction data from the `quasi' single-crystal β-Sn structure to a more powder-like Debye–Scherrer ring.


2019 ◽  
Vol 75 (3) ◽  
pp. 483-488 ◽  
Author(s):  
Kouhei Okitsu ◽  
Yasuhiko Imai ◽  
Yoshitaka Yoda

Non-coplanar 18-beam X-ray pinhole topographs for a silicon crystal were computer simulated by fast Fourier transforming the X-ray rocking amplitudes that were obtained by solving the n-beam (n = 18) Ewald–Laue dynamical theory (E-L&FFT method). They were in good agreement with the experimentally obtained images captured using synchrotron X-rays. From this result and further consideration based on it, it has been clarified that the X-ray diffraction intensities when n X-ray waves are simultaneously strong in the crystal can be computed for any n by using the E-L&FFT method.


2014 ◽  
Vol 9 (9) ◽  
pp. 1934578X1400900 ◽  
Author(s):  
Juan D. Hernández-Hernández ◽  
Hugo A. García-Gutiérrez ◽  
Luisa U. Román-Marín ◽  
Yunuen I. Torres-Blanco ◽  
Carlos M. Cerda-García-Rojas ◽  
...  

The stems of Bursera multijuga afforded (-)-(1 S,3 E,7 R,8 R,11 E)-7,8-epoxycembra-3,11-dien-1-ol (1) and its acetate 2, together with cembrene A (3), nephthenol (4), and cembrenol (5). The structures of 1 and 2 were elucidated by 1D and 2D NMR, HRESIMS, and X-ray diffraction. The conformational preference of flexible 1 was studied by molecular modeling at the DFT B3LYP/DGDZVP level of theory. Good agreement between calculated and experimental vibrational circular dichroism curves established the absolute configuration of 1. This is the first time that cembrane derivatives have been isolated from the genus Bursera.


1983 ◽  
Vol 38 (5) ◽  
pp. 533-539 ◽  
Author(s):  
R. Caminiti ◽  
P. Cucca ◽  
A. D′Andrea

The scattering of X-rays from a concentrated Ce(NO3)3 aqueous solution has been measured and analyzed. The experimental correlation function appears to be mainly characterized by the hydration of the cation: peaks at about 2.55 and 4.65 Å. Good agreement with experimental data is achieved through a model in which the Ce(III) ions have a first and a second hydration shell and also the nitrate group is considered hydrated. Complex formation between cation and anion is confirmed by using Raman spectroscopy.


Metals ◽  
2018 ◽  
Vol 8 (11) ◽  
pp. 913
Author(s):  
Zhimao Wang ◽  
Jean-Luc Grosseau-Poussard ◽  
Benoît Panicaud ◽  
Guillaume Geandier ◽  
Pierre-Olivier Renault ◽  
...  

In order to clarify the mechanical features of a metal under thermal cyclic loading for the system Ni30Cr-Cr2O3, a specific study has been carried out. In the present work, the residual stresses in both the metal and the oxide layer have been investigated. An adapted method is applied to process the experimental results that were obtained by using in-situ high temperature synchrotron diffraction at European Synchrotron Radiation Facility. The sin2ψ analysis provides information about the stress in metal and oxide. X-ray diffraction provides also the lattice parameter between crystallographic planes in the metal. To obtain correct stress values, a correction method is also proposed taking into account different discrepancies sources to ensure the equation of mechanical balance.


1983 ◽  
Vol 1 (3) ◽  
pp. 231-239 ◽  
Author(s):  
R. G. Evans

A simple model is presented for the thermodynamic and hydrodynamic behaviour of solid targets heated by intense charged particle beams. The model gives the temperature and pressure generated by the beam and allows a direct comparison with the pressure generated by laser beams. The model is in good agreement with a coupled thermodynamic hydrodynamic computer simulation.


2020 ◽  
Author(s):  
Sander Brugman ◽  
Paolo Raiteri ◽  
Paolo Accordini ◽  
Frank Megens ◽  
Julian Gale ◽  
...  

<div>Adsorption and incorporation of ions is known to influence the morphology and growth of calcite. Using surface X-ray diffraction, the interfacial structure of calcite in contact with CaCO3, MgCl2, CaCl2</div><div>and BaCl2 solutions was determined. All of these conditions yield a comparable interfacial structure,</div><div>meaning that there is no significant ion adsorption. This allows for the first time a thorough comparison in all three dimensions with state-of-the-art computer simulations, involving molecular dynamics</div><div>based on both DFT and two different force field models. Additionally, the simulated structures are</div><div>used to calculate the corresponding structure factors, which in turn are compared to those obtained</div><div>from experiment, thereby avoiding the need for fitting or subjective interpretation. In general, there</div><div>is a good agreement between experiment and the simulations, though there are some small discrepancies in the atomic positions, which lead to an inadequate fit of certain features characteristic of the</div><div>structure of water at the interface. Of the three simulation methods examined, the DFT results were</div><div>found to agree best with the experimental structure.</div>


2017 ◽  
Vol 50 (1) ◽  
pp. 145-151 ◽  
Author(s):  
Riccardo Camattari ◽  
Gianfranco Paternò ◽  
Marco Romagnoni ◽  
Valerio Bellucci ◽  
Andrea Mazzolari ◽  
...  

A technique to obtain self-standing curved crystals has been developed. The method is based on a sandblasting process capable of producing an amorphized layer on the substrate. It is demonstrated that the amorphized layer behaves as a thin compressive film, causing the curvature of the substrate. This procedure permits the fabrication of homogeneously curved crystals in a fast and economical way. It is shown that a sandblasted crystal can be used as an X-ray optical element for astrophysical or medical applications. A sandblasted bent crystal can also be used as an optical element for steering charged particles in accelerator beamlines. Several samples were manufactured and bent using the sandblasting method at the Sensor and Semiconductor Laboratory of Ferrara, Italy. Their curvature was verified using interferometric profilometry, showing a deformation in agreement with the Stoney formalism. The curvature of the machined samples was also tested using γ-ray diffraction at the Institut Laue–Langevin (ILL), Grenoble, France. A good agreement with the dynamical theory of diffraction was observed. In particular, the experiment showed that the crystalline quality of the bulk was preserved. Moreover, the method allowed curved samples to be obtained free of any additional material. Finally, a crystalline undulator was produced using sandblasting and tested using γ-ray diffraction at the ILL. The crystal showed a precise undulating pattern, so it will be suitable for hard X-ray production.


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