scholarly journals NOVEL PALM OIL BASED POLYOLS WITH AMINE FUNCTIONALITY SYNTHESIS VIA RING OPENING REACTION OF EPOXIDIZED PALM OIL

2018 ◽  
Vol 80 (6) ◽  
Author(s):  
Sabrina Soloi ◽  
Rohah Abdul Majid ◽  
Abdul Razak Rahmat
Keyword(s):  
Reaction Time ◽  
Palm Oil ◽  
Ring Opening ◽  
Market Price ◽  
Chemical Properties ◽  
Oxirane Ring ◽  
Epoxidized Palm Oil ◽  
Ring Opening Reaction ◽  
Twin Band ◽  
Physical And Chemical

In polymer chemistry, polyol usually used as starting materials for polyurethane (PU) production in which upon reacted with isocyanate will affect the physical and chemical properties of the obtained PU. Polyols that are mostly derived from petrochemical resources are facing issues such as depletion of petroleum sources as well as the increasing in market price. Ring opening reaction (ROR) of epoxidized palm oil (EPO) had been carried out using isopropanolamine (IPA) to impart polyol with amine functionality. The effect of reaction time on the opening of oxirane ring was investigated. FTIR spectra showed that the oxirane ring opening of EPO can occur at 6 hours reaction time, corresponding to the deacreasing intensity of  oxirane COO twin band at 824-830 cm-1. The OH value of the amine- functionalized-polyol was calculated at around 240-253 mg KOH/g. By prolonging the reaction time the OH value has slightly reduced. Mass spectroscopy analysis revealed that the polyol has a molecular weight in the range of oligo-polyols (400 – 500 Da).

Modification of Used Palm Oil: Preliminary Study of its Potentiality as Polyurethane Foam Precursors

2016 ◽  
Vol 705 ◽  
pp. 50-54
Author(s):  
Duangporn Riyapan ◽  
Nitinart Saetung ◽  
Anuwat Saetung
Keyword(s):  
Reaction Time ◽  
Palm Oil ◽  
Ring Opening ◽  
Chemical Structure ◽  
Increase Reaction Time ◽  
H Nmr ◽  
Pu Foam ◽  
Ring Opening Reaction ◽  
Preliminary Study ◽  
Used Palm Oil

Polyol was successfully synthesized from used palm oil (UPO) via epoxidation and ring opening reaction. The mole ratio of UPO: formic acid: hydrogen peroxide was 0.3: 8: 1.5. The reaction had been continuously stirred at 400 rpm at 65°C with varied reaction time for 0.5, 1.0, 1.5, 2.0, and 4.0 h. The chemical structure of modified used palm oil (MUPO) or polyol was confirmed by 1H-NMR. OH number of polyols increased with an increase reaction time. Moreover, the preliminary study for the preparation of MUPO-based polyurethane (PU) foam was performed. A new MUPO-based PU foam was successfully prepared and theirs foam behaviors were investigated.

scholarly journals Kinetika reaksi hidroksilasi epoksi minyak jarak pagar menggunakan katalis bentonit

2018 ◽  
Vol 12 (2) ◽  
pp. 257
Author(s):  
Ratni Ariatmi Nugrahani ◽  
Flora Elvistia Firdaus ◽  
Yeti Widyawati ◽  
Hana Firginia ◽  
Riris Purnama
Keyword(s):  
Jatropha Curcas ◽  
Ring Opening ◽  
Reaction System ◽  
Chemical Properties ◽  
Oxirane Ring ◽  
Hydroxyl Groups ◽  
Jatropha Oil ◽  
Jatropha Curcas Oil ◽  
Ring Opening Reaction ◽  
Kinetics Of

Hydroxylation kinetics of jatropha oil epoxy using bentonite catalyst. Based on chemical properties such as fatty acid compositions and iodium value, jatropha curcas oil can potentially be applied as lubricant. Unsaturation of this oil decreases its  oxidative stability. Improvement of this property may be done by chemical modification involving epoxidation and oxirane ring opening with bentonite catalyst, forming polyol by hydroxylation. The purpose of this research is to characterize the products and kinetics of the oxirane ring opening reaction. The results of chemical analysis by titration for residual oxiranes and hydroxyl formed in the reaction system, was showed using ir spectroscopy. Their effects were to reduce epoxy groups at 824-842 cm−1 and appearance of hydroxyl groups at the oh characteristic absorption peak from 3450-3800 cm−1. The oxirane number of epoxidized jatropha oil was reduced from 4.7% to 0.05% by ring opening. The kinetics of the oxirane ring opening of epoxidized jatropha curcas oil by methanol with bentonite was studied at 50, 60, and 65 oc. The oxirane ring opening analyzed by the pseudo-homogeneous approach followed a pseudo-first order kinetics. From the temperature dependence of the  rate, reaction enthalpy (δh) and activation energy (δea) were found to be 8,27 kcal mol−1 and 7,63 kcal mol−1, respectively.Keywords: epoxidized jatropha curcas, hydroxyl, oxirane, bentonite, kinetic AbstrakBerdasarkan sifat-sifat komposisi asam lemak dan bilangan iodium, minyak jarak pagar (Jatropha curcas) berpotensi menjadi bahan dasar pelumas. Meskipun demikian, kandungan ikatan tidak jenuh minyak ini menurunkan kestabilan oksidasinya. Kestabilan oksidasi ini dapat diperbaiki melalui modifikasi kimiawi dengan reaksi epoksidasi yang menghilangkan ikatan rangkap.  Ini dilakukan melalui reaksi hidroksilasi dengan membuka ikatan gugus oksirana epoksi. Tujuan penelitian ini adalah mengkarakterisasi produk, serta mempelajari kinetika reaksi pembukaan cincin oksirana oleh metanol dengan katalis bentonit untuk membentuk poliol. Hasil analisis FTIR produk reaksi menunjukkan penurunan intensitas gugus epoksi pada bilangan gelombang 824-842 cm−1 dan munculnya gugus hidroksil pada bilangan gelombang 3450-3800 cm−1. Bilangan oksirana epoksi jarak pagar berkurang dari 4,7% menjadi 0,05% setelah pembukaan cincin. Bilangan hidroksil poliol adalah sebesar 165,77. Pengukuran kinetika pembukaan cincin pada gugus oksirana dari epoksi jarak pagar dilakukan pada 50, 60, dan 65oC. Analisis data laju reaksi yang dianalisis dengan pendekatan sistem pseudohomogen menunjukkan bahwa reaksi mengikut kinetika orde-1 semu. Dari perubahan laju reaksi terhadap temperatur diperoleh nilai entalpi reaksi dan energi aktivasi sebesar masing-masing 8,27 kkal mol-1 dan 7,63 kkal mol-1.Kata kunci: epoksi jarak pagar, hidroksil, oksirana, bentonit, kinetika

Synthesis and Characterization of Palm Oil Based Polyol

2013 ◽  
Vol 812 ◽  
pp. 275-280
Author(s):  
Yahaya Siti Munira ◽  
Ahmad Faiza Mohd ◽  
Mohamed Rahmah
Keyword(s):  
Nuclear Magnetic Resonance ◽  
Fourier Transform ◽  
Palm Oil ◽  
Ring Opening ◽  
Hydroxyl Group ◽  
Synthesis And Characterization ◽  
Epoxidized Palm Oil ◽  
Ring Opening Reaction ◽  
Epoxy Groups

In this study, palm oil-based polyols were prepared and characterized. In order to prepare the polyol, Epoxidized palm oil (EPO) was reacted with glycerol and undergoes ring opening reaction. The synthesized oil was characterized by oxygen oxirane content titration (OOC), hydroxyl value test (HV), fourier transform infrared (FTIR) and nuclear magnetic resonance (NMR). Based on the FTIR spectrum of polyols, the disappearance of epoxy groups at 825cm-1, 843cm-1 and the emergence of hydroxyl group at 3394cm-1 are obvious indicating that hydroxyl group of the polyols formed. In NMR, the presence of new signal at δ 3.46ppm (-CH-OH) showed the attachment of hydroxyl group onto the epoxidized palm oil.

scholarly journals Optimization of the Ring Opening of Epoxidized Palm Oil using D-Optimal Design

2020 ◽  
Vol 33 (1) ◽  
pp. 67-75
Author(s):  
Nurazira Mohd Nor ◽  
Nadia Salih ◽  
Jumat Salimon
Keyword(s):  
Response Surface Methodology ◽  
Reaction Time ◽  
Optimal Design ◽  
Reaction Temperature ◽  
Palm Oil ◽  
Ring Opening ◽  
Oxirane Oxygen ◽  
Process Variables ◽  
Optimum Conditions ◽  
Epoxidized Palm Oil

In the presence of a catalyst, p-toluenesulfonic acid (PTSA), the ring of epoxidized palm oil (EPO) was opened using oleic acid (OA). The optimization effects of different process variables including the mol ratio of EPO/OA, reaction temperature, PTSA percentage and reaction time was performed by response surface methodology (RSM). To assess the effects of process variables and interactions among them, a D-optimal design was used as an RSM tool to acquire the maximum response value. The following are the optimum conditions achieved at the reaction time of 4.73 h in the RSM study: 1.02% PTSA, 3 EPO/OA mol ratio and 119.14 ºC reaction temperature. These conditions resulted in 84% yield, 0.041% oxirane oxygen content (OOC), 59.4 mg/g iodine value (IV), and118.7 mg/g hydroxyl value (HV). The results are in a excellent agreement with the values predicted using a regression model.

Synthesis of Quaternary Ammonium Cationic Polymer PEA

2013 ◽  
Vol 690-693 ◽  
pp. 1599-1603
Author(s):  
Rong Ming Zhang ◽  
Hong Man Shan ◽  
Min Zhao ◽  
Dong Hui Ma ◽  
Wei Li
Keyword(s):  
Reaction Time ◽  
Water Absorption ◽  
Reaction Temperature ◽  
Quaternary Ammonium ◽  
Ring Opening ◽  
Cationic Polymer ◽  
Ring Opening Reaction ◽  
Epoxy Value ◽  
Polymerization Conditions

The cationic polymer PEA was synthesized by ring-opening reaction and quaterisation with epichlorohydrin and β-hydroxy alkyl propyl ether amine as the main materials.Study on the efffect of rate of charge, reaction time and reaction temperature on cationic degree and epoxy value. Capability of adsorption on the sand and anti-swelling resistance were studied. The results showed that the best polymerization conditions as follows,reaction temperature was 60 °C, reaction time was 6 h, the rate of charge of epichlorohydrin toβ-hydroxy alkyl propyletheramine was 2.5:1. Under these conditions , the cationic degree of PEA was 3.962 mmol/g, epoxy value was 0.12. Then it was performed the water absorption.

scholarly journals Optimization of the oxirane ring opening reaction in biolubricant base oil production

2016 ◽  
Vol 9 ◽  
pp. S1053-S1058 ◽  
Author(s):  
Jumat Salimon ◽  
Bashar Mudhaffar Abdullah ◽  
Nadia Salih
Keyword(s):  
Ring Opening ◽  
Oil Production ◽  
Oxirane Ring ◽  
Base Oil ◽  
Ring Opening Reaction

scholarly journals SYNTHESIS AND PROPERTIES OF ETHOXYLATED GLYCEROL MONOOLEATE AS PALM OIL BASED NONIONIC SURFACTANTS

2015 ◽  
Vol 17 (1) ◽  
pp. 49-55 ◽  
Author(s):  
Indri Badria Adilina ◽  
Egi Agustian ◽  
Yenny Meliana ◽  
Anny Sulaswatty
Keyword(s):  
Palm Oil ◽  
Nonionic Surfactants ◽  
Chemical Properties ◽  
Acid Value ◽  
Molar Ratio ◽  
Alkaline Catalyst ◽  
Surface Active Agents ◽  
Hydrophilic Lipophilic Balance ◽  
Physical And Chemical ◽  
Glycerol Monooleate

Palm oil based nonionic surfactants were synthesized by reacting glycerol monooleate with ethylene oxide at 80 ºC in the prescence of an alkaline catalyst. Purification of the products was conducted by use of acetic acid and black carbon which gave ethoxylated products (EGMO) with a higher level of viscocity and greater solubility in water. Physical and chemical properties of the product such as surface activity, cloud point, acid value, ester value, hydroxyl value, and hydrophilic-lipophilic balance was also determined and results varied depending on the reagent molar ratio. The synthesized EGMO were soluble in water and therefore show potential use as surface active agents in personal care and cosmetic products.Keywords:   nonionic surfactant, ethoxylation, glycerol monooleate, palm oil

scholarly journals Use of Palm Oil Clinker in Concrete Research: A Review

CONSTRUCTION ◽  
2021 ◽  
Vol 1 (1) ◽  
pp. 35-43
Author(s):  
NUR FARAH AZIERA JAMALUDIN ◽  
Khairunisa Muthusamy ◽  
Mohd Faizal Md. Jaafar ◽  
Fadzil Mat Yahaya
Keyword(s):  
Palm Oil ◽  
Concrete Strength ◽  
Chemical Properties ◽  
Concrete Research ◽  
Lightweight Aggregates ◽  
Cement Replacement ◽  
Suitable Amount ◽  
Partial Cement Replacement ◽  
Physical And Chemical ◽  
Good Workability

Palm oil clinker (POC) is a stone like by-product which is formed in the palm oil mill incinerator after extracted palm oil fibres and shells are  burt to generate electricity for mill operation. The electricity is continuously generated. Then, the burnt fibres and shells are thrown at dumping areas as waste. This practice consumes a larger area at the landfills, causing environmental pollution. A review on the physical and chemical properties of POC was presented. The effect of using POC as lightweight aggregates and partial cement replacement on the mechanical properties of concrete produced was reviewed. The integration of suitable amount of POC as cement replacement and lightweight aggregates provided good workability and enhanced the concrete strength. Conclusively, this article has presented information regarding the development in POC concrete research, including the research gaps that remain to be filled.

scholarly journals Selenium-Epoxy ‘Click’ Reaction and Se-Alkylation—Efficient Access to Organo-Selenium and Selenonium Compounds

Chemistry ◽  
2020 ◽  
Vol 2 (4) ◽  
pp. 827-836
Author(s):  
Taejun Eom ◽  
Anzar Khan
Keyword(s):  
Red Blood Cells ◽  
Blood Cells ◽  
Ring Opening ◽  
Click Reaction ◽  
Oxirane Ring ◽  
New Class ◽  
Ring Opening Reaction ◽  
Efficient Access ◽  
High Concentrations ◽  
Cationic Materials

This work establishes the ‘click’ nature of the base-catalyzed oxirane ring opening reaction by the selenolate nucleophile. The ‘click’-generated ß-hydroxy selenide can be alkylated to afford cationic selenium species. Hemolytic studies suggest that selenonium cations do not lyse red blood cells even at high concentrations. Overall, these results indicate the future applicability of the developed organo-selenium chemistry in the preparation of a new class of cationic materials based on the seleno-ether motif.

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