Investigation of the Tribological Properties of Surfactant-Modified MoS2 Microsized Spheres in Base Oil 500 SN

2007 ◽  
Vol 129 (4) ◽  
pp. 913-919 ◽  
Author(s):  
Xun Fu ◽  
Xiaodong Zhou ◽  
Huaqiang Shi ◽  
Danmei Wu ◽  
Zhengshui Hu
Keyword(s):  
Tribological Properties ◽  
Photoelectron Spectroscopy ◽  
Friction And Wear ◽  
Friction Reduction ◽  
Wear Volume ◽  
Reaction Products ◽  
Tribochemical Reaction ◽  
Adsorption Film ◽  
Base Oil ◽  
Flat Disk

The tribological properties of MoS2 microsized spheres (MS-MoS2) with diameter of 0.5–3μm modified by self-prepared surfactant quaternary ammonium salt of 2-undecyl-1-dithioureido-ethyl-imidazoline (SUDEI) as an additive in base oil 500 SN were investigated and compared with those of commercial colloidal MoS2(CC-MoS2) on a four-ball tester and an Optimol SRV oscillating friction and wear tester in a ball-on-disk contact configuration. The worn surfaces of the bottom flat disk were examined with scanning electron microscopy and X-ray photoelectron spectroscopy. It was found that the MoS2 microsized spheres product was a much better extreme-pressure additive and antiwear and friction-reduction additive in 500 SN than commercial colloidal MoS2(CC-MoS2). Under the appropriate concentration of 0.1% and 0.25% for MS-MoS2 and CC-MoS2 and the load of 400N, the friction coefficient of MS-MoS2/oil and CC-MoS2/oil decreased about 25.0% and 12.5% and the wear volume loss decreased about 50.4% and 12.9% compared with the pure base stock. The boundary lubrication mechanism could be deduced as the effective chemical adsorption film formed by the long chain alkyl (C11H23) and active elements (S and N) in the surfactant SUDEI and tribochemical reaction film composed of the tribochemical reaction products.

Preparation and tribological properties of a kind of lubricant containing cerium borate nanoparticles as additives

2019 ◽  
Vol 234 (11) ◽  
pp. 1789-1797 ◽  
Author(s):  
Lifeng Hao ◽  
Feng Cao ◽  
Zewen Jiang ◽  
Jiusheng Li ◽  
Tianhui Ren
Keyword(s):  
Tribological Properties ◽  
Photoelectron Spectroscopy ◽  
Lubricant Additive ◽  
Wear Property ◽  
Reaction Products ◽  
Tribochemical Reaction ◽  
Base Oil ◽  
Reducing Ability ◽  
Borate Ester ◽  
Friction Reducing

Oil-soluble compounds containing boron as lubricating additives were restricted by the hydrolysis of borate ester. In order to overcome this problem, cerium borate nanoparticles modified with oleic acid (O-CeB) as a potential substitute for conventional lubricant additive were studied in detail. The microstructures of the prepared nanoparticles were characterized. Tribological properties of cerium borate nanoparticles used as additive in base oil were evaluated, and the worn surface of the steel ball was investigated. The results show that O-CeB possesses better anti-wear ability at relatively higher concentration; in particular, it shows better friction-reducing ability under all these studied concentrations. Under higher load, its anti-wear property and friction-reducing property are better than that of Vanlube 289 in the base oil. Based on these results of interferometric surface profilometer and X-ray photoelectron spectroscopy, it can be deduced that a continuous resistance film containing depositions and the tribochemical reaction products was formed during the sliding process.

scholarly journals Tribological Properties of SiO2@Cu And SiO2@MoS2 Core-Shell Microspheres As Lubricant Additives

2021 ◽  
Author(s):  
Xiaoliang Ma ◽  
Chaoliang Gan ◽  
Xiaopeng Li ◽  
Yuting Li ◽  
Peng Feng ◽  
...  
Keyword(s):  
Tribological Properties ◽  
Friction And Wear ◽  
Hard Core ◽  
Lubricant Additives ◽  
Friction Reduction ◽  
Wear Volume ◽  
Core Shell ◽  
Base Oil ◽  
Tribological Behaviors ◽  
Lubrication Performance

Abstract Herein, core-shell structural SiO2@Cu and SiO2@MoS2 microspheres were prepared using SiO2 as hard core, Cu and MoS2 as shell. As lubricant additives were introduced into base oil (PAO 40), their friction-reduction and wear-resistance were investigated in detail. Comparing with onefold additive (SiO2, Cu and MoS2), such core-shell structure additives can improve the tribological behaviors at the Hertz contact stress range of 1.26 ~ 2.72 GPa (SiO2@Cu reduces the friction and wear up to 32.47% and 67.86% at 2.72 GPa, respectively). Besides, the tribological properties of SiO2@Cu microspheres are superior to that of SiO2@MoS2 (the wear volume was reduced by 48.45% at 2.72 GPa). The excellent tribological behaviors of SiO2@Cu microspheres can be ascribed to its structural advantage, the synergistic effect of hard SiO2 core and Cu shell. The rolling effect of SiO2, easy-shearing and self-repairing of Cu shell offer a synergistic lubrication function and form a dense protection film, thereby contributing to the optimal lubrication performance.

Experimental Research on Tribological Properties of Mn0.78Zn0.22Fe2O4 Magnetic Fluids

2008 ◽  
Vol 130 (3) ◽  
Author(s):  
Wang Li-jun ◽  
Guo Chu-wen ◽  
Ryuichiro Yamane
Keyword(s):  
Tribological Properties ◽  
Friction And Wear ◽  
Chemical Properties ◽  
Friction Reduction ◽  
Experimental Investigations ◽  
Wear Scar Diameter ◽  
Base Oil ◽  
Turbine Oil ◽  
Physical And Chemical ◽  
And Chemical Properties

The synthesis and application of nanometer-sized particles have received considerable attention in recent years because of their different physical and chemical properties from those of the bulk materials or individual molecules; however, few experimental investigations on the tribological properties of lubricating oils with and without nanoferromagnetic particles have been performed. This work investigates the tribological properties of Mn0.78Zn0.22Fe2O4 nanoferromagnetic as additive in 46# turbine oil using a four-ball friction and wear tester. It is shown that the 46# turbine oil containing Mn0.78Zn0.22Fe2O4 nanoparticles has much better friction reduction and antiwear abilities than the base oil. The 46# turbine oil doped with 6wt%Mn0.78Zn0.22Fe2O4 nanoparticles show the best tribological properties among the tested oil samples, and PB value is increased by 26%, and the decreasing percentage of wear scar diameter is 25.45% compared to base oil.

scholarly journals Tribological properties of novel palygorskite nanoplatelets used as oil-based lubricant additives

Friction ◽  
2020 ◽  
Vol 9 (2) ◽  
pp. 332-343 ◽  
Author(s):  
Kunpeng Wang ◽  
Huaichao Wu ◽  
Hongdong Wang ◽  
Yuhong Liu ◽  
Lv Yang ◽  
...  
Keyword(s):  
Tribological Properties ◽  
Magnesium Silicate ◽  
Treatment Method ◽  
Lubricant Additives ◽  
Wear Volume ◽  
Wear Scar Diameter ◽  
Tribochemical Reaction ◽  
Base Oil ◽  
Transmission Electron ◽  
Ball Surface

AbstractLayered palygorskite (PAL), commonly called attapulgite, is a natural inorganic clay mineral composed of magnesium silicate. In this study, an aqueous miscible organic solvent treatment method is adopted to prepare molybdenum-dotted palygorskite (Amo-PMo) nanoplatelets, which greatly improved the specific surface area of PAL and the dispersion effect in an oil-based lubricant system. Their layered structure and size were confirmed using transmission electron microscopy (TEM) and atomic force microscopy. Following a tribological test lubricated with three additives (PAL, organic molybdenum (SN-Mo), and Amo-PMo), it was found that the sample of 0.5 wt% Amo-PMo exhibited the best tribological properties with a coefficient of friction of 0.09. Moreover, the resulting wear scar diameter and wear volume of the sliding ball surface were 63% and 49.6% of those lubricated with base oil, respectively. Its excellent lubricating performance and self-repairing ability were mainly attributed to the generated MoS2 adsorbed on the contact surfaces during the tribochemical reaction, thereby effectively preventing the direct collision between asperities on sliding solid surfaces. Thus, as-prepared Amo-PMo nanoplatelets show great potential as oil-based lubricant additives, and this study enriches the existing application of PAL in industry.

Effect of Ultrasonic Vibration on the Friction and Wear Properties of GCr15/45# Steel Frictional Pairs Lubricated by n-Al2O3 Additives

2012 ◽  
Vol 538-541 ◽  
pp. 1920-1923
Author(s):  
Yu Lin Qiao ◽  
Shan Lin Yang ◽  
Yan Zang ◽  
Xin Yu Dong ◽  
Qing Sheng Cui
Keyword(s):  
Friction Coefficient ◽  
Ultrasonic Vibration ◽  
Photoelectron Spectroscopy ◽  
Friction And Wear ◽  
Ball Bearing ◽  
Wear Scar ◽  
Friction Reduction ◽  
Wear Volume ◽  
Wear Properties ◽  
Friction And Wear Properties

The friction and wear properties of GCr15/45# steel frictional pairs lubricated by n- Al2O3 additives under ultrasonic vibration or not were studied. The scanning electron microscope(SEM), X-ray photoelectron spectroscopy(XPS) and energy dispersive spectrometer (EDS) were carried out to analyse the wear scar surface. The effect mechanism of ultrasonic vibration on friction pairs was discussed. The results indicated that ultrasonic vibration could decrease the friction and wear of GCr15/45# friction pairs, when the content of n-Al2O3 was 0.5wt%, the effect of ultrasonic vibration on friction pairs was most obvious. The friction coefficient, wear volume and wear scar depth under ultrasonic vibration decreased 10%, 34% and 13%, respectively. The friction reduction and anti-wear mechanism of n-Al2O3 was single “micro ball bearing” without ultrasonic vibration, and it changed to “micro ball bearing” and adsorption penetration film with ultrasonic vibration, so the friction coefficient and wear volume was reduced.

Synthesis and Lubrication Characteristics of Aryloxycyclophosphazenes Substituted With Imidazolium

2009 ◽  
Vol 131 (3) ◽  
Author(s):  
Jinlong Li ◽  
Feng Zhou ◽  
Dapeng Feng ◽  
Yanqiu Xia ◽  
Weimin Liu
Keyword(s):  
Ionic Liquids ◽  
Tribological Properties ◽  
Friction And Wear ◽  
Ambient Condition ◽  
Wear Volume ◽  
Tribochemical Reaction ◽  
Lubricating Film ◽  
Strong Adsorption ◽  
Contact Surfaces ◽  
Lubrication Characteristics

A series of new aryloxycyclophosphazene derivatives substituted with imidazolium ionic liquids was synthesized. Their tribological properties were investigated on an Optimol SRV IV oscillating friction and wear tester in ambient condition. An electric field was imposed between the ball and disk to monitor the tribochemical reaction by means of “contact resistance.” These ionic liquids substituted cyclophosphazene derivatives present lower friction coefficient and wear volume loss than tetrakis-(3-trifluoromethylphenoxy)-bis(4-fluorophenoxy)cyclotriphosphazene. The polarity of ionic liquids is believed to provide strong adsorption to contact surfaces and can form a boundary lubricating film leading to friction and wear reductions. Introducing the ionic liquids to cyclophosphazene may be a new method to improve the tribological properties of cyclophosphazene derivatives.

Effects of Vanadium Oxide Nanoparticles on Friction and Wear Reduction

2017 ◽  
Vol 139 (6) ◽  
Author(s):  
Wei Dai ◽  
Kyungjun Lee ◽  
Alexander M. Sinyukov ◽  
Hong Liang
Keyword(s):  
Friction And Wear ◽  
Hydrodynamic Lubrication ◽  
Tribological Performance ◽  
Friction Reduction ◽  
Tribochemical Reaction ◽  
Base Oil ◽  
Lubrication Regimes ◽  
Wear Reduction ◽  
Light Mineral ◽  
Effective Additive

In this research, rheological and tribological performance of additive V2O5 nanoparticles in a light mineral oil has been investigated. For rheological performance, the addition of 0.2 wt. % V2O5 could reduce the viscosity of the base oil for 6%. Considering the overall friction reduction in boundary, mixed, and hydrodynamic lubrication regimes, that with 0.1 wt. % V2O5 exhibited the best effect. Friction coefficient of base oil could be reduced by 33%. In terms of wear, the addition of 0.2 wt. % V2O5 showed the lowest wear rate, which is 44% reduction compared to base oil. Through Raman spectrum and energy dispersive spectroscopy (EDS) analysis, it was found that V2O5 involved tribochemical reaction during rubbing. Vanadium intermetallic alloy (V–Fe–Cr) was found to enhance the antiwear performance. This research revealed that V2O5 nanoparticles could be an effective additive to improve tribological performance.

Effects of Friction Load and Ultrasonic Vibration on the Tribological Properties of Al2O3/Al2O3 Ceramic Friction Pairs under Liquid Paraffin Lubrication

2013 ◽  
Vol 652-654 ◽  
pp. 1881-1885
Author(s):  
Xin Yu Dong ◽  
Yu Lin Qiao ◽  
Yan Zang ◽  
Qing Sheng Cui
Keyword(s):  
Friction Coefficient ◽  
Ultrasonic Vibration ◽  
Tribological Properties ◽  
Friction And Wear ◽  
Liquid Paraffin ◽  
Friction Reduction ◽  
Wear Volume ◽  
Oil Lubrication ◽  
Wear Properties ◽  
Load Range

The effects of friction load and ultrasonic vibration on friction reduction and anti-wear properties of Al2O3/Al2O3 ceramic frictional pairs under oil lubrication were investigated by a modified MFT-R4000 reciprocating friction and wear tester. The mechanism of friction reduction and anti-wear under ultrasonic vibration was discussed. The results showed that, the ultrasonic vibration could influence the friction reduction and anti-wear properties of Al2O3/Al2O3 ceramic friction pairs due to it could reduce the stress between the friction pairs and destroy the oil film on the surface of samples. When the friction frequency was 2Hz, the ultrasonic vibration could reduce the friction coefficient within experiment load range. When the loads were 70N, 80N, 90N and 100N, the average friction coefficient were reduced by 16.1%, 14.5%, 9.7% and 2.6%,and wear volume of frictional pairs decreased 35%、32%、31% and 12%.

Polyaniline as an additive towards improving tribological properties and anti-corrosion performance of ionic liquids-based greases

2020 ◽  
Vol 72 (7) ◽  
pp. 851-856
Author(s):  
Zhengfeng Cao ◽  
Yanqiu Xia ◽  
Chuan Chen ◽  
Kai Zheng ◽  
Yi Zhang
Keyword(s):  
Ionic Liquids ◽  
Peer Review ◽  
Tribological Properties ◽  
Photoelectron Spectroscopy ◽  
Salt Spray ◽  
Lubricant Additive ◽  
Friction Reduction ◽  
Content Type ◽  
Base Oil ◽  
Worn Surfaces

Purpose This paper aims to explore polyaniline (PANI) as a lubricant additive to improve the anti-corrosion and tribological properties of ionic liquids (ILs) for actual applications. Design/methodology/approach ILs were synthesized by dissolving lithium salts in synthetic oil and were used as a base oil to prepare ILs-based greases. PANI was used as an additive. The tribological properties were investigated in detail and the anti-corrosion ability was also assessed via salt spray test. After friction test, the worn surfaces were characterized by scanning electron microscopy, Raman spectroscopy and X-ray photoelectron spectroscopy to analyze the lubrication mechanisms. Findings PANI not only reduces the corrosion but also improves the friction reduction and anti-wear abilities of the ILs-based greases. The analysis indicates that the protective films generated on the worn surfaces were responsible for the preferable anti-corrosion and tribological properties. Originality/value This paper provides an effective approach to improve the anti-corrosion and tribological properties of ILs for actual applications. Peer review The peer review history for this article is available at: https://publons.com/publon/10.1108/ILT-11-2019-0469/

Effects of Ultrasonic Vibration on Tribological Properties of GCr15/45# Steel Frictional Pairs in Lubricated Sliding Conditions under Various Friction Speed

2011 ◽  
Vol 338 ◽  
pp. 599-602 ◽  
Author(s):  
Yu Lin Qiao ◽  
Shan Lin Yang ◽  
Yan Zang ◽  
Xin Yu Dong
Keyword(s):  
Friction Coefficient ◽  
Ultrasonic Vibration ◽  
Tribological Properties ◽  
Friction And Wear ◽  
Friction Reduction ◽  
Wear Volume ◽  
Oil Lubrication ◽  
Wear Properties ◽  
Oil Film ◽  
Lubricated Sliding

The effects of friction speed and ultrasonic vibration on friction reduction and anti-wear properties of GCr15/45# steel frictional pairs under oil lubrication were investigated by a modified MFT-R4000 reciprocating friction and wear tester. The mechanism of friction reduction and anti-wear under ultrasonic vibration was discussed. The results showed that, the ultrasonic vibration could influence the friction reduction and anti-wear properties of frictional pairs due to it could reduce the stress between the friction pairs and destroy the oil film on the surface of samples. When the friction frequency was 2Hz，ultrasonic vibration would reduce the friction coefficient and wear volume of the frictional pairs. When the load was 40N, the friction coefficient and wear volume of the frictional pairs attained under ultrasonic vibration decreased 8% and 44% respectively. However, ultrasonic vibration would increase the friction coefficient and wear volume when the friction frequency was 5Hz. When the load was 30N, friction coefficient and wear volume of frictional pairs increased 11% and 74% than that without ultrasonic vibration respectively.

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