Evolution of NOx Abatement Techniques Through Combustor Design for Heavy-Duty Gas Turbines

1984 ◽  
Vol 106 (4) ◽  
pp. 825-832 ◽  
Author(s):  
M. B. Hilt ◽  
J. Waslo

The role played by oxides of nitrogen in the formation of photochemical smog has been known for many years. However, because of the relatively small fraction of power generated by gas turbines, there were no significant attempts at limiting gas turbine NOx emissions in the United States until about 15 years ago. This paper outlines General Electric’s experience with NOx abatement techniques from then until the present.

Author(s):  
Wolfgang Kappis ◽  
Stefan Florjancic ◽  
Uwe Ruedel

Market requirements for the heavy duty gas turbine power generation business have significantly changed over the last few years. With high gas prices in former times, all users have been mainly focusing on efficiency in addition to overall life cycle costs. Today individual countries see different requirements, which is easily explainable picking three typical trends. In the United States, with the exploitation of shale gas, gas prices are at a very low level. Hence, many gas turbines are used as base load engines, i.e. nearly constant loads for extended times. For these engines reliability is of main importance and efficiency somewhat less. In Japan gas prices are extremely high, and therefore the need for efficiency is significantly higher. Due to the challenge to partly replace nuclear plants, these engines as well are mainly intended for base load operation. In Europe, with the mid and long term carbon reduction strategy, heavy duty gas turbines is mainly used to compensate for intermittent renewable power generation. As a consequence, very high cyclic operation including fast and reliable start-up, very high loading gradients, including frequency response, and extended minimum and maximum operating ranges are required. Additionally, there are other features that are frequently requested. Fuel flexibility is a major demand, reaching from fuels of lower purity, i.e. with higher carbon (C2+), content up to possible combustion of gases generated by electrolysis (H2). Lifecycle optimization, as another important request, relies on new technologies for reconditioning, lifetime monitoring, and improved lifetime prediction methods. Out of Alstom’s recent research and development activities the following items are specifically addressed in this paper. Thermodynamic engine modelling and associated tasks are discussed, as well as the improvement and introduction of new operating concepts. Furthermore extended applications of design methodologies are shown. An additional focus is set ono improve emission behaviour understanding and increased fuel flexibility. Finally, some applications of the new technologies in Alstom products are given, indicating the focus on market requirements and customer care.


Author(s):  
John Hartranft ◽  
Bruce Thompson ◽  
Dan Groghan

Following the successful development of aircraft jet engines during World War II (WWII), the United States Navy began exploring the advantages of gas turbine engines for ship and boat propulsion. Early development soon focused on aircraft derivative (aero derivative) gas turbines for use in the United States Navy (USN) Fleet rather than engines developed specifically for marine and industrial applications due to poor results from a few of the early marine and industrial developments. Some of the new commercial jet engine powered aircraft that had emerged at the time were the Boeing 707 and the Douglas DC-8. It was from these early aircraft engine successes (both commercial and military) that engine cores such as the JT4-FT4 and others became available for USN ship and boat programs. The task of adapting the jet engine to the marine environment turned out to be a substantial task because USN ships were operated in a completely different environment than that of aircraft which caused different forms of turbine corrosion than that seen in aircraft jet engines. Furthermore, shipboard engines were expected to perform tens of thousands of hours before overhaul compared with a few thousand hours mean time between overhaul usually experienced in aircraft applications. To address the concerns of shipboard applications, standards were created for marine gas turbine shipboard qualification and installation. One of those standards was the development of a USN Standard Day for gas turbines. This paper addresses the topic of a Navy Standard Day as it relates to the introduction of marine gas turbines into the United States Navy Fleet and why it differs from other rating approaches. Lastly, this paper will address examples of issues encountered with early requirements and whether current requirements for the Navy Standard Day should be changed. Concerning other rating approaches, the paper will also address the issue of using an International Organization for Standardization, that is, an International Standard Day. It is important to address an ISO STD DAY because many original equipment manufacturers and commercial operators prefer to rate their aero derivative gas turbines based on an ISO STD DAY with no losses. The argument is that the ISO approach fully utilizes the power capability of the engine. This paper will discuss the advantages and disadvantages of the ISO STD DAY approach and how the USN STD DAY approach has benefitted the USN. For the future, with the advance of engine controllers and electronics, utilizing some of the features of an ISO STD DAY approach may be possible while maintaining the advantages of the USN STD DAY.


Author(s):  
Ralph A. Dalla Betta ◽  
James C. Schlatter ◽  
Sarento G. Nickolas ◽  
Martin B. Cutrone ◽  
Kenneth W. Beebe ◽  
...  

The most effective technologies currently available for controlling NOx emissions from heavy-duty industrial gas turbines are either diluent injection in the combustor reaction zone, or lean premixed Dry Low NOx (DLN) combustion. For ultra low emissions requirements, these must be combined with selective catalytic reduction (SCR) DeNOx systems in the gas turbine exhaust. An alternative technology for achieving comparable emissions levels with the potential for lower capital investment and operating cost is catalytic combustion of lean premixed fuel and air within the gas turbine. The design of a catalytic combustion system using natural gas fuel has been prepared for the GE model MS9OOIE gas turbine. This machine has a turbine inlet temperature to the first rotating stage of over 1100°C and produces approximately 105 MW electrical output in simple cycle operation. The 508 mm diameter catalytic combustor designed for this gas turbine was operated at full-scale conditions in tests conducted in 1992 and 1994. The combustor was operated for twelve hours during the 1994 test and demonstrated very low NOx emissions from the catalytic reactor. The total exhaust NOx level was approximately 12–15 ppmv and was produced almost entirely in the preburner ahead of the reactor. A small quantity of steam injected into the preburner reduced the NOx emissions to 5–6 ppmv. Development of the combustion system has continued with the objectives of reducing CO and UHC emissions, understanding the parameters affecting reactor stability and spatial non-uniformities which were observed at low inlet temperature, and improving the structural integrity of the reactor system to a level required for commercial operation of gas turbines. Design modifications were completed and combustion hardware was fabricated for additional full-scale tests of the catalytic combustion system in March 1995 and January 1996. This paper presents a discussion of the combustor design, the catalytic reactor design and the results of full-scale testing of the improved combustor at MS9OOIE cycle conditions in the March 1995 and January 1996 tests. Major improvements in performance were achieved with CO and UHC emissions of 10 ppmv and 0 ppmv at base load conditions. This ongoing program will lead to two additional full-scale combustion system tests in 1996. The results of these tests will be available for discussion at the June 1996 Conference in Birmingham.


Author(s):  
Karen A. Walder ◽  
Steven D’Alessio

Demand for power in the United States is projected to increase between 2 and 4 percent per year for the next 10 years based on various studies. At the same time, the rise in environmental regulatory restrictions has made it increasingly difficult and expensive for utilities to meet these growing power demands with traditional power sources. During the 1960’s and 70’s hundreds of gas turbine electric generating units were installed in the United States. Many are now approaching the end of their useful economic lives owing to increased maintenance and fuel costs. With the major advances in both fuel efficiency and exhaust gas emission quality power producers are looking toward the repowering of existing plants with modern gas turbines such as the FT8. (Day and Koehler, 1988) This paper describes the design of Turbo Power and Marine Systems’ (Turbo Power) FT8® repowering package for the present FT4 powered plant at Public Service Electric and Gas Company’s (PSE&G) Burlington Generating Station. Given the objectives of minimum design effort and minimum field construction time, the retrofit package provides an optimal blending of existing FT4 and standard FT8 equipment. Performance, impact on operation, reliability, and availability of the FT8 industrial gas turbine were also important considerations in the retrofit design.


Author(s):  
Justin Zachary

Since 1998, the United States has experienced a tremendous increase in power generation projects using gas turbine technology. By burning natural gas as the primary fuel and low sulfur oil as a back-up fuel, gas turbines are the cleanest form of fossil power generation.


1997 ◽  
Vol 119 (4) ◽  
pp. 844-851 ◽  
Author(s):  
R. A. Dalla Betta ◽  
J. C. Schlatter ◽  
S. G. Nickolas ◽  
M. B. Cutrone ◽  
K. W. Beebe ◽  
...  

The most effective technologies currently available for controlling NOx emissions from heavy-duty industrial gas turbines are diluent injection in the combustor reaction zone, and lean premixed Dry Low NOx (DLN) combustion. For ultralow emissions requirements, these must be combined with selective catalytic reduction (SCR) DeNOx systems in the gas turbine exhaust. An alternative technology for achieving comparable emissions levels with the potential for lower capital investment and operating cost is catalytic combustion of lean premixed fuel and air within the gas turbine. The design of a catalytic combustion system using natural gas fuel has been prepared for the GE model MS9OO1E gas turbine. This machine has a turbine inlet temperature to the first rotating stage of over 1100°C and produces approximately 105 MW electrical output in simple cycle operation. The 508-mm-dia catalytic combustor designed for this gas turbine was operated at full-scale conditions in tests conducted in 1992 and 1994. The combustor was operated for twelve hours during the 1994 test and demonstrated very low NOx emissions from the catalytic reactor. The total exhaust NOx level was approximately 12–15 ppmv and was produced almost entirely in the preburner ahead of the reactor. A small quantity of steam injected into the preburner reduced the NOx emissions to 5–6 ppmv. Development of the combustion system has continued with the objectives of reducing CO and UHC emissions, understanding the parameters affecting reactor stability and spatial nonuniformities that were observed at low inlet temperature, and improving the structural integrity of the reactor system to a level required for commercial operation of gas turbines. Design modifications were completed and combustion hardware was fabricated for additional full-scale tests of the catalytic combustion system in March 1995 and January 1996. This paper presents a discussion of the combustor design, the catalytic reactor design, and the results of full-scale testing of the improved combustor at MS9OO1E cycle conditions in the March 1995 and January 1996 tests. Major improvements in performance were achieved with CO and UHC emissions of 10 ppmv and 0 ppmv at baseload conditions. This ongoing program will lead to two additional full-scale combustion system tests in 1996. The results of these tests will be available for discussion at the June 1996 Conference in Birmingham.


1955 ◽  
Vol 59 (530) ◽  
pp. 127-150 ◽  
Author(s):  
J. L. Edwards

Some five years ago the author was privileged to deliver a Section Lecture to the Royal Aeronautical Society on the subject of reheat. The present paper attempts to summarise the problems which now arise and to give some idea of the progress which has been made in the intervening years.In 1949, reheat was in its infancy in Great Britain. A certain amount of progress had been made in the United States but the information from that source was scanty and vague. Tests at the National Gas Turbine Establishment (N.G.T.E.) had given some engine data but this was in the nature of preliminary information only and was by no means complete. In fact the majority of the problems which now beset us were then completely unknown or were considered unimportant. The N.G.T.E. work was valuable, however, in that it demonstrated the practicability of reheat, although at the time the comments of many who saw this and other schemes in operation were somewhat sceptical and definitely unflattering.


Author(s):  
William D. York ◽  
Willy S. Ziminsky ◽  
Ertan Yilmaz

Interest in hydrogen as a primary fuel stream in heavy-duty gas turbine engines has increased as precombustion carbon capture and sequestration (CCS) has become a viable option for integrated gasification combined cycle (IGCC) power plants. The U.S. Department of Energy has funded the Advanced IGCC/Hydrogen Gas Turbine Program since 2005 with an aggressive plant-level NOx target of 2 ppm at 15% O2 for an advanced gas turbine cycle. Approaching this NOx level with highly reactive hydrogen fuel at the conditions required is a formidable challenge that requires novel combustion technology. This study begins by measuring entitlement NOx emissions from perfectly premixed combustion of the high-hydrogen fuels of interest. A new premixing fuel injector for high-hydrogen fuels was designed to balance reliable flashback-free operation, reasonable pressure drop, and low emissions. The concept relies on small-scale jet-in-crossflow mixing that is a departure from traditional swirl-based premixing concepts. Single nozzle rig experiments were conducted at pressures of 10 atm and 17 atm, with air preheat temperatures of about 650 K. With nitrogen-diluted hydrogen fuel, characteristic of carbon-free syngas, stable operation without flashback was conducted up to flame temperatures of approximately 1850 K. In addition to the effects of pressure, the impacts of nitrogen dilution levels and amounts of minor constituents in the fuel—carbon monoxide, carbon dioxide, and methane—on flame holding in the premixer are presented. The new fuel injector concept has been incorporated into a full-scale, multinozzle combustor can with an energy conversion rate of more than 10 MW at F-class conditions. The full-can testing was conducted at full gas turbine conditions and various fuel compositions of hydrogen, natural gas, and nitrogen. This combustion system has accumulated over 100 h of fired testing at full load with hydrogen comprising over 90% of the reactants by volume. NOx emissions (ppm) have been measured in the single digits with hydrogen-nitrogen fuel at target gas turbine pressure and temperatures. Results of the testing show that small-scale fuel-air mixing can deliver a reliable, low-NOx solution to hydrogen combustion in advanced gas turbines.


Author(s):  
A. H. Lefebvre

The attainment of very low pollutant emissions, in particular oxides of nitrogen (NOx), from gas turbines is not only of considerable environmental concern but has also become an area of increasing competitiveness between the different engine manufacturers. For stationary engines, the attainment of ultra-low NOx has become the foremost marketing issue. This paper is devoted primarily to current and emerging technologies in the development of ultra-low emissions combustors for application to aircraft and stationary engines. Short descriptions of the basic design features of conventional gas turbine combustors and the methods of fuel injection now in widespread use are followed by a review of fuel spray characteristics and recent developments in the measurement and modeling of these characteristics. The main gas turbine generated pollutants and their mechanisms of formation are described, along with related environmental risks and various issues concerning emissions regulations and recently-enacted legislation for limiting the pollutant levels emitted by both aircraft and stationary engines. The impact of these emissions regulations on combustor and engine design are discussed first in relation to conventional combustors and then in the context of variable-geometry and staged combustors. Both these concepts are founded on emissions reduction by control of flame temperature. Basic approaches to the design of “dry” low NOx and ultra-low NOx combustors are reviewed. At the present time lean, premix, prevaporize, combustion appears to be the only technology available for achieving ultra-low NOx emissions from practical combustors. This concept is discussed in some detail, along with its inherent problems of autoignition, flashback, and acoustic resonance. Attention is also given to alternative methods of achieving ultra-low NOx emissions, notably the rich-bum, quick-quench, lean-burn and catalytic combustors. These concepts are now being actively developed, despite the formidable problems they present in terms of mixing and durability. The final section reviews the various correlations which are now being used to predict the exhaust gas concentrations of the main gaseous pollutant emissions from gas turbine engines. Comprehensive numerical methods have not yet completely displaced these semi-empirical correlations but are nevertheless providing useful insight into the interactions of swirling and recirculating flows with fuel sprays, as well as guidance to the combustion engineer during the design and development stages. Throughout the paper emphasis is placed on the important and sometimes pivotal role played by the fuel preparation process in the reduction of pollutant emissions from gas turbines.


Author(s):  
William D. York ◽  
Willy S. Ziminsky ◽  
Ertan Yilmaz

Interest in hydrogen as a primary fuel stream in heavy-duty gas turbine engines has increased as pre-combustion carbon capture and sequestration (CCS) has become a viable option for integrated gasification combined cycle (IGCC) power plants. The US Department of Energy has funded the Advanced IGCC/Hydrogen Gas Turbine Program since 2005 with an aggressive plant-level NOx target of 2 ppm @ 15% O2 for an advanced gas turbine cycle. Approaching this NOx level with highly-reactive hydrogen fuel at the conditions required is a formidable challenge that requires novel combustion technology. This study begins by measuring entitlement NOx emissions from perfectly-premixed combustion of the high-hydrogen fuels of interest. A new premixing fuel injector for high-hydrogen fuels was designed to balance reliable, flashback-free operation, reasonable pressure drop, and low emissions. The concept relies on distributed, small-scale jet-in-crossflow mixing that is a departure from traditional swirl-based premixing concepts. Single nozzle rig experiments were conducted at pressures of 10 atm and 17 atm, with air preheat temperatures of about 650K. With nitrogen-diluted hydrogen fuel, characteristic of carbon-free syngas, stable operation without flashback was conducted up to flame temperatures of approximately 1850K. In addition to the effects of operating pressure, the impact of minor constituents in the fuel — carbon monoxide, carbon dioxide, and methane — on flame holding in the premixer is presented. The new fuel injector concept has been incorporated into a full-scale, multi-nozzle combustor can with an energy conversion rate of more than 10 MW at F-class conditions. The full-can testing was conducted at full gas turbine conditions and various fuel compositions of hydrogen, natural gas, and nitrogen. This combustion system has accumulated over 100 hours of fired testing at full-load with hydrogen comprising over 90 percent of the reactants by volume. NOx emissions (ppm) have been measured in the single digits with hydrogen-nitrogen fuel at target gas turbine pressure and temperatures. Results of the testing show that small-scale fuel-air mixing can deliver a reliable, low-NOx solution to hydrogen combustion in advanced gas turbines.


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