An Innovative Gas Turbine Cycle With Methanol Fuelled Chemical-Looping Combustion

Author(s):  
Hongguang Jin ◽  
Xiaosong Zhang ◽  
Hui Hong ◽  
Wei Han

In this paper, a novel gas turbine cycle integrating methanol decomposition and the chemical-looping combustion (CLC) is proposed. The system study on two methanol-fuelled power plants, the new gas turbine cycle with CLC combustion, and a chemically intercooled gas turbine cycle, has been investigated with the aid of the exergy analysis (EUD methodology). In the proposed system, methanol fuel is decomposed into syngas mainly containing H2 and CO by recovering low-temperature thermal energy from an intercooler of the air compressor. After the decomposition of methanol, the resulting product of syngas is divided into two parts: the most part reacting with Fe2O3, is sent into the CLC subsystem, and the other part is introduced into a supplement combustor to enhance the inlet temperatures of turbine to 1100–1500°C. As a result, the new methanol-fuelled gas turbine cycle with CLC had a breakthrough in performance, with at least about 10.7 percentage points higher efficiency compared to the chemically intercooled gas turbine cycle with recovery of CO2 and is environmentally superior due to the recovery of CO2. This new system can achieve 60.6% net thermal efficiency with CO2 separation. The promising results obtained here indicated that this novel gas turbine cycle with methanol-fuelled chemical looping combustion could provide a promising approach of both effective use of alternative fuel and recovering low-grade waste heat, and offer a technical probability for CLC in applying into the advanced gas turbine with high temperatures above 1300°C.

Author(s):  
Hongguang Jin ◽  
Xiaosong Zhang ◽  
Hui Hong ◽  
Wei Han

In this paper, a novel gas turbine cycle integrating methanol decomposition and the chemical-looping combustion (CLC) is proposed. Two types of methanol-fueled power plants, including the new gas turbine cycle with CLC combustion and a chemically intercooled gas turbine cycle, have been investigated with the aid of the T-Q diagram. In the proposed system, methanol fuel is decomposed into syngas mainly containing H2 and CO by recovering low-temperature thermal energy from an intercooler of the air compressor. After the decomposition of methanol, the resulting product of syngas is divided into two parts: the part reacting with Fe2O3 is sent into the CLC subsystem, and the other part is introduced into a supplement combustor to enhance the inlet temperatures of the gas turbine to 1100–1500°C. As a result, the new methanol-fueled gas turbine cycle with CLC had a breakthrough in thermodynamic and environmental performance. The thermal efficiency of the new system can achieve 60.6% with 70% of CO2 recovery at a gas turbine inlet temperature of 1300°C. It would be expected to be at least about 10.7 percentage points higher than that of the chemically intercooled gas turbine cycle with the same recovery of CO2 and is environmentally superior due to the recovery of CO2. The promising results obtained here indicated that this novel gas turbine cycle with methanol-fueled chemical-looping combustion could provide a promising approach of both effective use of alternative fuel and recovering low-temperature waste heat and offer a technical probability of blending a combination of the chemical-looping combustion and the advanced gas turbine for carbon capture and storage.


2016 ◽  
Vol 139 (3) ◽  
Author(s):  
Bilal Hassan ◽  
Oghare Victor Ogidiama ◽  
Mohammed N. Khan ◽  
Tariq Shamim

A thermodynamic model and parametric analysis of a natural gas-fired power plant with carbon dioxide (CO2) capture using multistage chemical looping combustion (CLC) are presented. CLC is an innovative concept and an attractive option to capture CO2 with a significantly lower energy penalty than other carbon-capture technologies. The principal idea behind CLC is to split the combustion process into two separate steps (redox reactions) carried out in two separate reactors: an oxidation reaction and a reduction reaction, by introducing a suitable metal oxide which acts as an oxygen carrier (OC) that circulates between the two reactors. In this study, an Aspen Plus model was developed by employing the conservation of mass and energy for all components of the CLC system. In the analysis, equilibrium-based thermodynamic reactions with no OC deactivation were considered. The model was employed to investigate the effect of various key operating parameters such as air, fuel, and OC mass flow rates, operating pressure, and waste heat recovery on the performance of a natural gas-fired power plant with multistage CLC. The results of these parameters on the plant's thermal and exergetic efficiencies are presented. Based on the lower heating value, the analysis shows a thermal efficiency gain of more than 6 percentage points for CLC-integrated natural gas power plants compared to similar power plants with pre- or post-combustion CO2 capture technologies.


Author(s):  
Hui Hong ◽  
Ying Pan ◽  
Xiaosong Zhang ◽  
Tao Han ◽  
Shuo Peng ◽  
...  

In this paper, a new solar hybrid gas turbine cycle integrating ethanol-fueled chemical-looping combustion (CLC) has been proposed, and the system was investigated with the aid of the Energy-Utilization Diagram (EUD). Chemical-looping combustion consists of two successive reactions: first, ethanol fuel is oxidized by metal oxide (NiO) as an oxygen carrier (reduction of metal oxide); secondly, the reduced metal (Ni) is successively oxidized by combustion air (the oxidation of metal). The reduction of NiO with ethanol requires a relative low-grade thermal energy at 150–200°C. Then concentrated solar thermal energy at approximately 200–300°C can be utilized to provide the process heat for this reaction. The integration of solar thermal energy and CLC could make the exergy efficiency and the net solar-to-electric efficiency of the system more than 54% and 28% at a turbine inlet temperature (TIT) of 1288°C, respectively. At the same time, the variation in the overall thermal efficiency (η) of the system with varying key parameters was analyzed, such as Turbine Inlet Temperature, pressure ratio (π) and the temperature of reduction reactor. Additionally, preliminary experiments on ethanol-fueled chemical-looping combustion are carried out to verify the feasibility of the key process. The promising results obtained here indicate that this novel gas turbine cycle with ethanol-fueled chemical-looping combustion could provide a promising approach of both efficient use of alternative fuel and low-temperature solar thermal and offer a technical probability of combining the chemical-looping combustion with inherent CO2 capture for the alternative fuel.


Energy ◽  
2009 ◽  
Vol 34 (12) ◽  
pp. 2131-2136 ◽  
Author(s):  
Xiaosong Zhang ◽  
Wei Han ◽  
Hui Hong ◽  
Hongguang Jin

Author(s):  
Xueyou Wen ◽  
Yingxin Wei ◽  
Jierong Jin ◽  
Zhen Fu

Proposed in this paper is a novel propulsion system. On the basis of a gas turbine Brayton cycle a Rankine regenerative cycle was set up in parallel, which by utilizing the waste heat of the gas turbine exhaust gas is able to flexibly supply steam for gas turbine steam injection and for aircraft catapults. Thus brought forth is a gas turbine propulsion plant with a dual-purpose steam supply, which can well be suited for use on board an aircraft carrier. The propulsion plant under discussion has the inherent merits of a steam injected gas turbine cycle, but the additional new feature of steam supply for aircraft catapults significantly enhances the advantages of the propulsion plant as a whole. With a medium-sized aircraft carrier being selected as an example a comprehensive comparison has been conducted of four types of propulsion power plants, including a gas turbine propulsion plant with the capability to supply steam for both gas turbine steam injection and aircraft catapults.


2015 ◽  
Vol 5 (2) ◽  
pp. 89
Author(s):  
Munzer S. Y. Ebaid ◽  
Qusai Z. Al-hamdan

<p class="1Body">Several modifications have been made to the simple gas turbine cycle in order to increase its thermal efficiency but within the thermal and mechanical stress constrain, the efficiency still ranges between 38 and 42%. The concept of using combined cycle power or CPP plant would be more attractive in hot countries than the combined heat and power or CHP plant. The current work deals with the performance of different configurations of the gas turbine engine operating as a part of the combined cycle power plant. The results showed that the maximum CPP cycle efficiency would be at a point for which the gas turbine cycle would have neither its maximum efficiency nor its maximum specific work output. It has been shown that supplementary heating or gas turbine reheating would decrease the CPP cycle efficiency; hence, it could only be justified at low gas turbine inlet temperatures. Also it has been shown that although gas turbine intercooling would enhance the performance of the gas turbine cycle, it would have only a slight effect on the CPP cycle performance.</p>


Author(s):  
Esa Utriainen ◽  
Bengt Sundén

The application of recuperators in advanced thermodynamic cycles is growing due to stronger demands of low emissions of pollutants and the necessity of improving the cycle efficiency of power plants to reduce the fuel consumption. This paper covers applications and types of heat exchangers used in gas turbine units. The trends of research and development are brought up and the future need for research and development is discussed. Material aspects are covered to some extent. Attempts to achieve compact heat exchangers for these applications are also discussed. With the increasing pressure ratio in the gas turbine cycle, large pressure differences between the hot and cold sides exist. This has to be accounted for. The applicability of CFD (Computational Fluid Dynamics) is discussed and a CFD–approach is presented for a specific recuperator. This recuperator has narrow wavy ducts with complex cross-sections and the hydraulic diameter is so small that laminar flow prevails. The thermal-hydraulic performance is of major concern.


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