Shadow Edge Lithography for Wafer-Scale Nanofabrication

Author(s):  
John Guofeng Bai ◽  
Jae-Hyun Chung

We propose shadow edge lithography (SEL) as a wafer-scale nanofabrication method. The shadow effect of “line-ofsight” in high-vacuum evaporation is analyzed theoretically to predict the geometric distributions of the fabricated nanoscale gaps. In the experiment, nanoscale gap patterns are created by the shadow of Al edges which are prepatterned using e-beam evaporation and the conventional ultraviolet lithography. Feasibility of the SEL is demonstrated by the fabrication of nanogaps having the width ranging from 15 to 100 nm on 4-inch Si wafers. Furthermore, by using the height differences in the prepatterned Al edges to compensate the geometric distributions of the shadow effect, it is demonstrated that the uniformity tolerance in the nanogap width can be ±1 nm or ±5% across the 4-inch Si wafers at a resolution down to 20 nm. The experimental results agree well with the theoretical prediction considering the virtual source during the e-beam evaporation. Upon the nanogap fabrication, arrays of nanochannels are obtained by reactive ion etching (RIE) using the evaporated Al layers as the etching mask. Our results show that that the evaporated Al layers can be used as the RIE mask to transfer the nanoscale patterns with a high yield and throughput. Thus, the SEL provides a robust method for wafer-scale fabrication especially for sub 50-nm structures.

Author(s):  
Woon-Hong Yeo ◽  
Dong Won Lee ◽  
Kyong-Hoon Lee ◽  
Jae-Hyun Chung

Many upcoming applications, such as nanoelectronic circuitry, single-molecule based chips, nanofluidics, chemical sensors, and fuel cells, require large arrays of nanochannels and nanowires. To commercialize such nanostructured devices, a high resolution and high throughput patterning method is essential. For this purpose, we developed the shadow edge lithography (SEL) as a wafer-scale, high-throughput nanomanufacturing method [1]. In the proposed method, the shadow effect in the high-vacuum evaporation was theoretically analyzed to predict the geometric distribution of the nanoscale patterns [2]. In experiment, nanoscale patterns were created by the shadow of aluminum (Al) edges that were prepatterned using a conventional microfabrication method.


2008 ◽  
Vol 584-586 ◽  
pp. 470-474 ◽  
Author(s):  
Egor Prokofiev ◽  
Dmitriy Gunderov ◽  
Alexandr Lukyanov ◽  
Vladimir Pushin ◽  
Ruslan Valiev

Amorphous-nanocrystalline Ti49.4Ni50.6 alloy in the shape of a disc 20 mm in diameter has been successfully produced using high pressure torsion (HPT). Application of HPT and annealing at temperatures of 300–550°C resulted in formation of a nanocrystalline (NC) structure with the grain size (D) about 20–300 nm. The HPT samples after annealing at Т = 400°C with the D= 20 nm possess high yield stress and high ultimate tensile strength (more than 2000 MPa). There is an area of strain-induced transformation B2-B19’ on the tensile curve of the samples with the grain size D =20 nm. The stress of martensitic transformation (σm) of samples is 450 MPa, which is three times higher than σm in the initial coarse-grained state (σm ≈ 160 MPa). The HPT samples after annealing at Т = 550°C with the D= 300 nm possess high ductility (δ>60 %) and high ultimate tensile strength (about 1000 MPa).


1988 ◽  
Vol 132 ◽  
Author(s):  
R. W. Siegel ◽  
J. A. Eastman

ABSTRACTUltrafine-grained ceramics have been synthesized by the production of ultrafine (2–20 nm) particles, using the gas-condensation method, followed by their in-situ, ultra-high vacuum consolidation at room temperature. These new nanophase ceramics have properties that are significantly improved relative to those of their coarser-grained, conventionally-prepared counterparts. For example, nanophase rutile (TiO2) with an initial mean grain diameter of 12 nm sinters at 400 to 600°C lower temperatures than conventional powders, without the need for compacting or sintering aids. The sintered nanophase rutile exhibits both improved microhardness and fracture characteristics. These property improvements result from the reduced scale of the grains and the increased cleanliness of the particle surfaces and the subsequently-formed grain boundaries. Research completed on the synthesis, characterization, and properties of nanophase ceramics is reviewed and the potential for using the nanophase synthesis method for engineering new and/or improved ceramics and composites is considered.


Carbon ◽  
2014 ◽  
Vol 78 ◽  
pp. 326-338 ◽  
Author(s):  
Hoël Guerin ◽  
Hélène Le Poche ◽  
Roland Pohle ◽  
Laurent Syavoch Bernard ◽  
Elizabeth Buitrago ◽  
...  

2003 ◽  
Vol 789 ◽  
Author(s):  
Sanjay Mathur ◽  
Hao Shen ◽  
Ulf Werner

ABSTRACTSingle crystal Ge nanowires (NWs) were obtained in high yield by gas phase decomposition of germanium di-cyclopentadienylide ([Ge(C5H5)2]), at 325 °C on iron substrates. Highresolution electron microscopy (SEM/TEM) showed Ge NWs to be uniform in terms of diameter (20 nm) and length (> 25 μm). The wire growth is selective and appears to be governed by a Ge-Fe alloy epilayer formed by the reaction between Ge clusters and iron substrate, during the initial stages of the CVD process. The supersaturation of Ge-Fe solid-solution with respect to Ge content induces the spontaneous formation of single crystal germanium nuclei that act as templates for the nanowire growth. X-ray and electron diffraction revealed the NWs to be single crystals of cubic germanium with a preferred growth direction[11–2]. The proposed base-growth model on Fe substrate is supported by TEM, EDX and XPS studies.


2018 ◽  
Vol 10 (39) ◽  
pp. 33457-33463 ◽  
Author(s):  
Kortney Almeida ◽  
Michelle Wurch ◽  
Adane Geremew ◽  
Koichi Yamaguchi ◽  
Thomas A. Empante ◽  
...  

2018 ◽  
Vol 2018 (1) ◽  
pp. 000583-000588 ◽  
Author(s):  
Hui Xu ◽  
Aashish Shah ◽  
Basil Milton ◽  
Ivy Qin

Abstract Wire bonding continues to be the most commonly used interconnection technology due to its low cost, high yield rate, increased flexibility and improved reliability. Among wire bonded packages, the high growth areas include Multi-Chip modules and System in Package (SiP) applications. A type of wire bonding, Stand-Off-Stitch Bond (SSB), is widely used in Multi-chip, die-to-die, SiP and light-emitting diodes (LEDs). The SSB process starts with a flat-topped bump bonding on the substrate or die, followed by the formation of a new ball bond (1st bond). The stitch bond (2nd bond) of that wire is bonded on top of the initial bump. This paper focuses on key SSB process steps, by examining the main challenges and solutions of SSB applications. We demonstrate ultra-fine pitch SSB process capability with 0.6 mil Au wire using newly developed response-based processes for sub-20 nm node wafer technology.


2015 ◽  
Vol 1113 ◽  
pp. 446-452 ◽  
Author(s):  
Nur Shazrynda Md Shahrodin ◽  
Abdul Razak Rahmat ◽  
Agus Arsad

Cassava starch nanocrystals (CSN) has not been reported in open literature, although other starches such as rice, corn, potato and bean were widely used as the main material. Thus, the objective of this research was to investigate the possibility of synthesizing high yield of CSN at different concentration of sulphuric acid (H2SO4). The physical and chemical properties of synthesize CSN was also investigated. Synthesized CSN was prepared by hydrolysing native cassava starch (NCS) with several concentration of H2SO4 (2.8 M, 3.0 M, 3.2 M and 3.4 M). The acid hydrolysis process took five days with continuous stirring speed of 300 to 400 rpm, with constant temperature of 37 °C. The hydrolysed solution of CSN underwent centrifuging process with distilled water until neutral to make sure that no acid residues remain in the CSN solution. The CSN precipitate was dried in an oven over night at 60 °C. The highest yield (1.1 %) produced was from 3.4 M CSN. Morphology test by Transmission Electron Microscopy indicated that the samples have been destructed and degraded to be nanocrystals with a size range of 5 - 20 nm. X-ray Diffraction (XRD) and 13C Nuclear Magnetic Resonance (NMR) were used to indicate the type of crystallinity for both NCS and CSN.


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