Effect of Carbon Nanotube-Phosphinate Ionic Liquid Thin Boundary Layer on the Tribological Behavior of Aluminum Alloy in Steel-on-Aluminum Contact

Author(s):  
Miguel A. Gutierrez ◽  
Michael Gydesen ◽  
Caitlin Marcellus ◽  
Ivan Puchades ◽  
Brian Landi ◽  
...  

In this study, the tribological behavior of the Trihexyl tetradecylphosphonium-bis(2,4,4-trimethylpentyl)phosphinate [THTDP][Phos] ionic liquid with and without single-wall carbon nanotubes (SWCNT) dispersion as a thin boundary layer was intended for investigation. However, the surface heat treatment process was not sufficient to form a thin film on the sample surfaces. Thus, in each test condition, the lubricating agents were used as external (liquid) lubricants. Specifically, [THTDP][Phos] and ([THTDP][Phos]+0.1 wt.% SWCNT) boundary film layers were applied on 6061-T6 aluminum alloy disk samples and tested under sliding contact with 1.5 mm diameter 420C stainless steel balls using a ball-on-flat linearly reciprocating tribometer. A commercially available Mobil Super 10W-40 engine oil (MS10W40) was also tested and used as this investigation’s datum. The tribological behavior of [THTDP][Phos] and ([THTDP][Phos]+SWCNT) boundary film layers was analyzed via wear volume calculations from optical microscopy measurements, as well as by observation of the transient coefficient of friction (COF) obtained through strain gauge measurements made directly from the reciprocating member of the tribometer. Results indicate the potential for reduction of wear volume and coefficient of friction in the IL lubricated steel-on-aluminum sliding contact through (SWCNT) dispersion in the ionic liquid. Wear results are based on measurements obtained using optical microscopy (OM). Results discussed display improved tribological performance for both [THTDP][Phos] and ([THTDP][Phos]+SWCNT) over baseline MS10W40 oil lubricant for both roughness values tested for the steel-on-aluminum contact. No measurable improvements were observed between [THTDP][Phos] and ([THTDP][Phos]+SWCNT) tests.

Friction ◽  
2020 ◽  
Vol 9 (1) ◽  
pp. 169-178
Author(s):  
Hong Guo ◽  
Patricia Iglesias

Abstract In this study, the tribological behavior of an ammonium-based protic ionic liquid (PIL) as an additive in a base mineral oil (MO) is investigated on a steel-steel contact at room temperature and 100 °C. Tri-[bis(2-hydroxyethylammonium)] citrate (DCi) was synthesized in a simple and low-cost way, and the ionic structure of DCi was confirmed by proton nuclear magnetic resonance (1H NMR). The stability measurement of 1 wt% DCi to a MO was investigated, and the lubricating ability and anti-wear properties of DCi as an additive in MO were also examined using a custom-designed reciprocating ball-on-flat tribometer. Optical microscope and profilometry were used to obtain the worn morphology of the steel disks. Scanning electron microscopy (SEM) and energy dispersive X-ray spectroscopy (EDS) were carried out to investigate the wear mechanism and to analyze the surface interactions between the rubbing components. When 1 wt% DCi is added into the base MO, frictional performance is improved at both temperatures studied with a friction reduction of 29.0% and 35.5%, respectively. Moreover, the addition of 1 wt% DCi to MO reduced the wear volume 59.4% compared to the use of MO. An oxygen-richened tribolayer is confirmed by EDS on the disk surface when DCi was used as additive under 100 °C.


2020 ◽  
Vol 62 (12) ◽  
pp. 1243-1250
Author(s):  
Fahri Vatansever ◽  
Alpay Tamer Erturk ◽  
Erol Feyzullahoglu

2018 ◽  
Vol 350 ◽  
pp. 391-400 ◽  
Author(s):  
Xiang Qiu ◽  
Naeem ul Haq Tariq ◽  
Ji-qiang Wang ◽  
Jun-rong Tang ◽  
Lawrence Gyansah ◽  
...  

Wear ◽  
2014 ◽  
Vol 319 (1-2) ◽  
pp. 172-183 ◽  
Author(s):  
Zhen-bing Cai ◽  
Harry M. Meyer ◽  
Cheng Ma ◽  
Miaofang Chi ◽  
Huimin Luo ◽  
...  

Author(s):  
Aswani K Singh ◽  
Varun Sharma

During machining, the cutting fluids play an essential role in cooling and lubrication. In order to reduce the friction forces, the excessive amount of the cutting fluids are generally used. This, in turn, leads to wastage of the cutting fluids which results in a serious impact on the environment, health and cost of production. Therefore, the judicious use of lubricants is the foremost concern in the manufacturing industry. In order to mitigate these drawbacks, various alternatives have been developed in the last decade. In the present paper, ionic liquids have been proved as favourable sustainable alternative additives in the base oil. The effect of alkyl chain length of ionic liquids with base oil on the thermo-physical and tribological characteristics of cutting fluids including viscosity, wettability, anticorrosion behaviour, thermal stability, and coefficient of friction have been analysed. In the present study, pyrrolidinium and hexafluoro-phosphate (PF6) have been used as cation and anion, respectively, with rice bran oil as base oil. The five different ionic liquids have been dispersed in base oil by 1.0 wt%. It has been found that longer alkyl chain length showed the favourable results as compared to the shorter one. Results indicated that ionic liquid based cutting fluid attained ample enhanced thermophysical and tribological properties as compared to the neat rice bran oil. There has been 5.08% and 4.29% improvement in viscosity and thermal conductivity for IL4 + RBO in comparison to neat RBO. In addition, the wettability, coefficient of friction, and wear volume have been reduced by 20.34%, 53.79% and 57.87% correspondingly.


Lubricants ◽  
2018 ◽  
Vol 6 (3) ◽  
pp. 66 ◽  
Author(s):  
Akshar Patel ◽  
Hong Guo ◽  
Patricia Iglesias

Contact friction between moving components leads to severe wear and failure of engineering parts, resulting in large economic losses. The lubricating ability of the protic ionic liquid, tri-[bis(2-hydroxyethylammonium)] citrate (DCi), was studied as a neat lubricant and as an additive in a mineral oil (MO) at various sliding velocities and constant load on an aluminum–steel contact using a pin-on-disk tribometer. Tribological tests were also performed at different concentrations of DCi. When DCi was used as an additive in MO, friction coefficient and wear volume were reduced for each sliding velocity, with a maximum friction and wear reduction of 16% and 40%, respectively, when 2 wt % DCi was added to MO at a sliding velocity of 0.15 m/s. Scanning electron microscopy (SEM) and energy-dispersive X-ray spectroscopy (EDX) were also applied to analyze the wear mechanism of the interface lubricated by MO and DCi as additive.


2016 ◽  
Vol 25 (8) ◽  
pp. 3152-3160 ◽  
Author(s):  
Massimo Lorusso ◽  
Alberta Aversa ◽  
Diego Manfredi ◽  
Flaviana Calignano ◽  
Elisa Paola Ambrosio ◽  
...  

2021 ◽  
pp. 1-17
Author(s):  
Neha Singh ◽  
Sujeet K Sinha

Abstract Liquid absorption and tribological studies of epoxy-based composite with ultra-high molecular weight polyethylene (UHMWPE) and MoS2, sliding against steel were conducted. Composites, as coating and as a bulk, were soaked in water, base oil, ionic liquid and lithium-based grease for different intervals of days or months. Liquid weight% gain was more in polar liquids when compared to non-polar. Coated composite soaked in grease for 10 days showed coefficient of friction of 0.08 with wear-life of more than 1 million cycles and wear rate of 1.7×10−8 mm3/Nm. Bulk polymer composite soaked in grease for 180 days provided the least coefficient of friction of 0.06 and specific wear rate of 2.60×10−7 mm3/Nm.


2019 ◽  
Vol 803 ◽  
pp. 167-171
Author(s):  
Aphinan Phukaoluan ◽  
Anak Khantachawana ◽  
Pongpan Kaewtatip ◽  
Surachai Dechkunakorn

The tribological behavior of Ti49.4Ni50.6, Ti49Ni46Cu5 and Ti50Ni47Co3 (at%) alloy in dry and wet conditions was studied. The alloy was prepared in a Vacuum Arc Re-melting (VAR), homogenized at 800°C for 3600 s and quenched in water. The phase transformation temperatures were measured by differential scanning calorimetry. Before a tribology test, it is necessary to determine surface roughness, because high surface roughness affects friction. The hardness behavior, based on the load over residual indent area, was determined by a Vickers hardness tester. The sliding friction tests were performed using a ball-on-disk tribometer in dry condition at room temperature and wet condition in artificial saliva (pH 5.35) at 37°C (Oral temperature). The results showed that transformation temperature (Af) lowered oral temperature (37°C), this was mainly attributed to the superelastic properties that can be taken into orthodontic applications. The studies showed significant influences in dry condition of coefficient of friction. Caused by the force between the ball and the disk, contact pressure of surface area effect in wear occurred. The debris could not be removed from the surface area tested. TiNiCu and TiNiCo generated significantly lower average coefficient of friction when tested under dry condition, which may have been due to the addition of Cu and Co. Wet condition decreased coefficient of friction more than dry condition, owing to the lubricating effects of artificial saliva.


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