Plasma Decomposition of Carbon Dioxide: Simulations and Experiments

2019 ◽  
Author(s):  
Kamau Wright ◽  
Robert Galvez
Keyword(s):  
Carbon Dioxide ◽  
Co2 Concentration ◽  
Plasma Discharges ◽  
Electrical Parameters ◽  
Plasma System ◽  
Process Gas ◽  
Plasma Decomposition ◽  
Carbon Dioxide Co2 ◽  
Co2 Decomposition ◽  
Over Time

Abstract Simulations and experiments are conducted to model, simulate, test and demonstrate the effect of plasma discharges on decomposition of carbon dioxide (CO2). A pin-to-plane discharge is employed in gas samples containing CO2. A high voltage plasma system is used which was previously shown to be able to decrease CO2 concentration in gas samples. The discharge is modeled and described, including monitoring electrical parameters such as current and voltage. The present study investigated plasma decomposition of carbon dioxide experimentally, and through simulation. A plasma micro-discharge was utilized to better understand plasma-CO2 interactions. Enhancements are suggested to help increase the efficiency and yield of the plasma-CO2 decomposition process. Gas samples are analyzed over time using a CO2 meter.

High Voltage Plasma Reactor for Treatment of Carbon Dioxide and Oxygen Generation

2018 ◽  
Author(s):  
Kamau Wright
Keyword(s):  
Carbon Dioxide ◽  
High Voltage ◽  
Plasma Reactor ◽  
Co2 Concentration ◽  
Sem Analysis ◽  
Plasma Discharges ◽  
Oxygen Generation ◽  
Ftir Spectrometer ◽  
Carbon Dioxide Co2 ◽  
Co2 Decomposition

High voltage plasma-based technologies have the ability to impact multiple fields from medicine to engineering. The goal of the most recent study was to investigate the efficacy of a novel high voltage plasma system to generate oxygen (O2) from carbon dioxide (CO2) through dissociation. The general endothermic plasma-chemical process of CO2 decomposition is presented, with CO2 destruction accompanying production of oxygen (and carbon monoxide) at a mole ratio of 2 to 1. A high voltage plasma reactor was developed for this purpose. SEM analysis was conducted on electrodes used for plasma discharges, to better elucidate characteristics of the plasma. CO2 gas samples were analyzed using an FTIR spectrometer. Baseline scans were taken of CO2 inside the reactor before plasma power was turned on; subsequent scans were taken after 10 min of plasma treatment. Results of FTIR analysis presented here have indicated a 30% decrease in CO2 concentration upon application of the developed plasma reactor. This paper reports on various aspects of the instrumented high voltage plasma reactor; and experimental results which further explore the capability to decrease CO2 concentrations in various environments, while also generating O2.

An Experimental Study of Nonequilibrium Carbon Dioxide/Oil Interactions

SPE Journal ◽  
2018 ◽  
Vol 23 (05) ◽  
pp. 1768-1783 ◽  
Author(s):  
Mahmood Reza Yassin ◽  
Ali Habibi ◽  
Ashkan Zolfaghari ◽  
Sara Eghbali ◽  
Hassan Dehghanpour
Keyword(s):  
Carbon Dioxide ◽  
Experimental Study ◽  
Natural Convection ◽  
Visual Cell ◽  
Bulk Oil ◽  
High Pressure High Temperature ◽  
Light Oil ◽  
Condensing Flows ◽  
Carbon Dioxide Co2 ◽  
Over Time

Summary In this study, we use a custom-designed visual cell to investigate nonequilibrium carbon dioxide (CO2)/oil interactions under high-pressure/high-temperature conditions. We visualize the CO2/oil interface and measure the visual-cell pressure over time. We perform five sets of visualization tests. The first three tests aim at investigating interactions of gaseous (g), liquid (l), and supercritical (sc) CO2 with a Montney (MTN) oil sample. In the fourth test, to visualize the interactions in the bulk oil phase, we replace the opaque MTN oil with a translucent Duvernay (DUV) light oil (LO). Finally, we conduct an N2(sc)/oil test to compare the results with those of CO2(sc)/oil test. We also compare the results of nonequilibrium CO2/oil interactions with those obtained from conventional pressure/volume/temperature (PVT) tests. Results of the first three tests show that oil immediately expands upon injection of CO2 into the visual cell. CO2(sc) leads to the maximum oil expansion followed by CO2(l) and CO2(g). Furthermore, the rate of oil expansion in the CO2(sc)/oil test is higher than that in CO2(l)/oil and CO2(g)/oil tests. We also observe extracting and condensing flows at the CO2(l)/oil and CO2(sc)/oil interfaces. Moreover, we observe density-driven fingers inside the LO phase because of the local increase in the density of LO. The results of PVT tests show that the density of the CO2/oil mixture is higher than that of the CO2-free oil, explaining the density-driven natural convection during CO2(sc) injection into the visual cell. We do not observe either extracting/condensing flows or density-driven mixing for the N2(sc)/oil test, explaining the low expansion of oil in this test. The results suggest that the combination of density-driven natural convection and extracting/condensing flows enhances CO2(sc) dissolution into the oil phase, leading to fast oil expansion after CO2(sc) injection into the visual cell.

scholarly journals Six years of atmospheric CO<sub>2</sub> observations at Mt. Fuji recorded with a battery-powered measurement system

2017 ◽  
Vol 10 (2) ◽  
pp. 667-680 ◽  
Author(s):  
Shohei Nomura ◽  
Hitoshi Mukai ◽  
Yukio Terao ◽  
Toshinobu Machida ◽  
Yukihiro Nojiri
Keyword(s):  
Carbon Dioxide ◽  
Measurement System ◽  
Measurement Data ◽  
Co2 Concentration ◽  
Measurement Unit ◽  
Sources And Sinks ◽  
Charging System ◽  
Carbon Dioxide Co2 ◽  
Stability And Accuracy ◽  
Working Standards

Abstract. We developed a battery-powered carbon dioxide (CO2) measurement system for monitoring at the summit of Mt. Fuji (3776 m a.s.l.), which experiences very low temperatures (below −20 °C) and severe environmental conditions without access to gridded electricity for 10 months (from September to June). Our measurement system used 100 batteries to run the measurement unit during these months. These batteries were charged during the 2-month summer season when gridded electricity was available, using a specially designed automatic battery-charging system. We installed this system in summer 2009 at the Mt. Fuji weather station; observations of atmospheric CO2 concentration were taken through December 2015. Measurements were never interrupted by a lack of battery power except for two cases in which lightning damaged a control board. Thus we obtained CO2 data during about 94 % of the 6-year period. Analytical performances (stability and accuracy) were better than 0.1 ppm, as tested by checking working standards and comparisons with flask sampling.Observational results showed that CO2 mole fractions at Mt. Fuji demonstrated clear seasonal variation. The trend and the variability of the CO2 growth rate observed at Mt. Fuji were very similar to those of the Mauna Loa Observatory (MLO). Seasonally, the concentration at Mt. Fuji was 2–10 ppm lower in summer and 2–12 ppm higher in winter than those at MLO. The lower concentrations at Mt. Fuji in summer are mainly attributed to episodes of air mass transport from Siberia or China, where CO2 is taken up by the terrestrial biosphere. On the other hand, the relatively higher concentrations in winter seem to reflect the high percentage of air masses originating from China or Southeast Asia during this period, which carry increased anthropogenic carbon dioxide. These results show that Mt. Fuji is not very influenced by local sources but rather by the sources and sinks over a very large region.Thus we conclude that, as this system could provide stable measurement data with relatively easy operation for 6 years at Mt. Fuji, it could be a useful monitoring technique for remote background sites elsewhere.

scholarly journals Determination of Dissolved CO2 Concentration in Culture Media: Evaluation of pH Value and Mathematical Data

Processes ◽  
2020 ◽  
Vol 8 (11) ◽  
pp. 1373
Author(s):  
Amir Izzuddin Adnan ◽  
Mei Yin Ong ◽  
Saifuddin Nomanbhay ◽  
Pau Loke Show
Keyword(s):  
Carbon Dioxide ◽  
Ph Value ◽  
Culture Media ◽  
Co2 Concentration ◽  
Co2 Solubility ◽  
Greenhouse Gasses ◽  
Dipotassium Phosphate ◽  
The Difference ◽  
Carbon Dioxide Co2

Carbon dioxide is the most influential gas in greenhouse gasses and its amount in the atmosphere reached 412 µmol/mol in August 2020, which increased rapidly, by 48%, from preindustrial levels. A brand-new chemical industry, namely organic chemistry and catalysis science, must be developed with carbon dioxide (CO2) as the source of carbon. Nowadays, many techniques are available for controlling and removing carbon dioxide in different chemical processes. Since the utilization of CO2 as feedstock for a chemical commodity is of relevance today, this study will focus on how to increase CO2 solubility in culture media used for growing microbes. In this work, the CO2 solubility in a different medium was investigated. Sodium hydroxide (NaOH) and monoethanolamine (MEA) were added to the culture media (3.0 g/L dipotassium phosphate (K2HPO4), 0.2 g/L magnesium chloride (MgCl2), 0.2 g/L calcium chloride (CaCl2), and 1.0 g/L sodium chloride (NaCl)) for growing microbes in order to observe the difference in CO2 solubility. Factors of temperature and pressure were also studied. The determination of CO2 concentration in the solution was measured by gas analyzer. The result obtained from optimization revealed a maximum CO2 concentration of 19.029 mol/L in the culture media with MEA, at a pressure of 136.728 kPa, operating at 20.483 °C.

Correlations of methane and carbon dioxide concentrations from feedlot cattle as a predictor of methane emissions

2016 ◽  
Vol 56 (1) ◽  
pp. 108 ◽  
Author(s):  
Mei Bai ◽  
David W. T. Griffith ◽  
Frances A. Phillips ◽  
Travis Naylor ◽  
Stephanie K. Muir ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Concentration Ratio ◽  
Co2 Concentration ◽  
Feedlot Cattle ◽  
Mitigation Strategies ◽  
Co2 Production ◽  
Ch4 Emissions ◽  
Carbon Dioxide Concentrations ◽  
Carbon Dioxide Co2 ◽  
Animal Diet

Accurate measurements of methane (CH4) emissions from feedlot cattle are required for verifying greenhouse gas (GHG) accounting and mitigation strategies. We investigate a new method for estimating CH4 emissions by examining the correlation between CH4 and carbon dioxide (CO2) concentrations from two beef cattle feedlots in Australia representing southern temperate and northern subtropical locations. Concentrations of CH4 and CO2 were measured at the two feedlots during summer and winter, using open-path Fourier transform infrared spectroscopy. There was a strong correlation for the concentrations above background of CH4 and CO2 with concentration ratios of 0.008 to 0.044 ppm/ppm (R2 >0.90). The CH4/CO2 concentration ratio varied with animal diet and ambient temperature. The CH4/CO2 concentration ratio provides an alternative method to estimate CH4 emissions from feedlots when combined with CO2 production derived from metabolisable energy or heat production.

Predation of freshwater fish in environments with elevated carbon dioxide

2017 ◽  
Vol 68 (9) ◽  
pp. 1585 ◽  
Author(s):  
Stephen R. Midway ◽  
Caleb T. Hasler ◽  
Tyler Wagner ◽  
Cory D. Suski
Keyword(s):  
Carbon Dioxide ◽  
Elevated Co2 ◽  
Prey Capture ◽  
Micropterus Salmoides ◽  
Pimephales Promelas ◽  
Co2 Concentration ◽  
High Pco2 ◽  
Starting Point ◽  
Carbon Dioxide Co2 ◽  
Future Work

Carbon dioxide (CO2) in fresh-water environments is poorly understood, yet in marine environments CO2 can affect fish behaviour, including predator–prey relationships. To examine changes in predator success in elevated CO2, we experimented with predatory Micropterus salmoides and Pimephales promelas prey. We used a two-factor fully crossed experimental design; one factor was 4-day (acclimation) CO2 concentration and the second factor CO2 concentration during 20-min predation experiments. Both factors had three treatment levels, including ambient partial pressure of CO2 (pCO2; 0–1000 μatm), low pCO2 (4000–5000 μatm) and high pCO2 (8000–10000 μatm). Micropterus salmoides was exposed to both factors, whereas P. promelas was not exposed to the acclimation factor. In total, 83 of the 96P. promelas were consumed (n=96 trials) and we saw no discernible effect of CO2 on predator success or time to predation. Failed strikes and time between failed strikes were too infrequent to model. Compared with marine systems, our findings are unique in that we not only saw no changes in prey capture success with increasing CO2, but we also used CO2 treatments that were substantially higher than those in past experiments. Our work demonstrated a pronounced resiliency of freshwater predators to elevated CO2 exposure, and a starting point for future work in this area.

scholarly journals A Fiber-Integrated CRDS Sensor for In-Situ Measurement of Dissolved Carbon Dioxide in Seawater

Sensors ◽  
2021 ◽  
Vol 21 (19) ◽  
pp. 6436
Author(s):  
Mai Hu ◽  
Bing Chen ◽  
Lu Yao ◽  
Chenguang Yang ◽  
Xiang Chen ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Equilibrium Condition ◽  
Co2 Concentration ◽  
Scientific Data ◽  
In Situ Measurement ◽  
Integrated Sensor ◽  
Dissolved Carbon ◽  
Low Efficiency ◽  
Carbon Dioxide Co2

Research on carbon dioxide (CO2) geological and biogeochemical cycles in the ocean is important to support the geoscience study. Continuous in-situ measurement of dissolved CO2 is critically needed. However, the time and spatial resolution are being restricted due to the challenges of very high submarine pressure and quite low efficiency in water-gas separation, which, therefore, are emerging the main barriers to deep sea investigation. We develop a fiber-integrated sensor based on cavity ring-down spectroscopy for in-situ CO2 measurement. Furthermore, a fast concentration retrieval model using exponential fit is proposed at non-equilibrium condition. The in-situ dissolved CO2 measurement achieves 10 times faster than conventional methods, where an equilibrium condition is needed. As a proof of principle, near-coast in-situ CO2 measurement was implemented in Sanya City, Haina, China, obtaining an effective dissolved CO2 concentration of ~950 ppm. The experimental results prove the feasibly for fast dissolved gas measurement, which would benefit the ocean investigation with more detailed scientific data.

scholarly journals Carbon Dioxide Level in Neonatal Incubator: A Comparative Study of Two Baby Air Flow Input Methods in Incubator Chamber

2021 ◽  
Vol 5 (1) ◽  
pp. p65
Author(s):  
R. Vardanjans ◽  
L. Cirule
Keyword(s):  
Carbon Dioxide ◽  
Gas Flow ◽  
Stable Condition ◽  
Co2 Concentration ◽  
Preterm Neonates ◽  
Long Time ◽  
Level Versus ◽  
Infant Incubator ◽  
Co2 Level ◽  
Carbon Dioxide Co2

Preterm neonates often have to spend a long time in incubator which simulates necessary enviromental conditions to maintain patients in stable condition. Authors have found neglected problem with Carbon Dioxide (CO2) concentration in newborn inhaled gas when using “oxygen hood” into infant incubator that has not been studied very closely. Methods in this experiement were carried out as condition monitoring while changing some parameters and positions. Results have shown that CO2 level is letally high in some aspects. Situation is alarming as CO2 level in incubator is not limited by current regulation, as IEC60601-2-19: 2009 +A1:2016. Currently the Incubator manufacturers declare that CO2 maximal concentration should be periodically checked by users, which are hospitals. Some commercially available incubators have the maximum allowed CO2 level 8000 ppm, which is much higher than recommended 2000 ppm CO2 level in indoor working place. There is no limitation of maximal level of CO2 using “oxygen hood”, which are specified in incubator operation manual. This paper goal is to show the correlation of CO2 level versus gas flow into oxygen hood.

scholarly journals EVALUATION OF RTH IN REGIONAL SPATIAL PLAN WITH NDVI IN KENDARI CITY

2021 ◽  
Vol 10 (1) ◽  
pp. 53
Author(s):  
Septianto Aldiansyah
Keyword(s):  
Carbon Dioxide ◽  
Urban Areas ◽  
Minimum Standard ◽  
Descriptive Research ◽  
Current Availability ◽  
Quantitative Descriptive ◽  
Carbon Dioxide Co2 ◽  
Over Time ◽  
Spatial Plan

Kendari City is the capital of Southeast Sulawesi Province with a population of 345,110 people. The number of residents can trigger a narrowing of RTH (RTH) due to meeting the need for land over time. RTH in urban areas ideally is 30% of the total area with 20% public RTH and 10% private RTH. This study aims for RTH based on the comparison of the area of the RTH Regional Spatial Plan (RTRW) and the actual RTH, the population, the ability to produce oxygen (O2) and absorption of carbon dioxide (CO2) in the actual RTH. This research uses quantitative descriptive research in evaluating RTH. The results showed that public RTH in the RTRW still lacked 6.93% so that it was still necessary to review the RTRW to meet these needs. The current RTH is also still less than the minimum standard of RTH in Kendari City of 7.01% in public RTH. If it is accumulated, the current availability of RTH still does not meet the minimum standard of RTH in Kendari City. The availability of oxygen (O2) and absorption of carbon dioxide (CO2) in Kendari City can still meet the needs of residents in Kendari City.

scholarly journals Amine-based carbon dioxide absorption: evaluation of kinetic and mass transfer parameters

2018 ◽  
Vol 12 (4) ◽  
pp. 4088-4097
Author(s):  
S. Ma’mun ◽  
Hallvard F. Svendsen ◽  
I. M. Bendiyasa
Keyword(s):  
Carbon Dioxide ◽  
Mass Transfer ◽  
Atmospheric Pressure ◽  
Co2 Concentration ◽  
Co2 Absorption ◽  
Absorption Process ◽  
Carbon Dioxide Absorption ◽  
Global Emission ◽  
Transfer Parameters ◽  
Carbon Dioxide Co2

Global emission of carbon dioxide (CO2), a major contributor to the climate change, has increased annually and it reached over 37 Gt in 2017. An effort to reduce the emission, therefore, needs to be conducted, e.g. post-combustion capture by use of amine-based absorption. The objective of this study is to evaluate the kinetic and mass transfer parameters in a CO2 absorption process using monoethanolamine (MEA), 2-(methylamino)ethanol (MMEA), and 2-(ethylamino)ethanol (EMEA) as absorbents. The experiments were conducted in a bubble reactor at atmospheric pressure and 40 °C with 10-vol% CO2 flowrate of 5 NL/men. The CO2 concentration leaving the reactor was measured by an IR CO2 analyzer. The results obtained from this experiment were the overall absorption rates consisting of both chemical reaction and mass transfer. Analysis result shows that the reaction between CO2 and amines takes place fast, therefore the mass transfer of CO2 from the gas into the liquid through the gas film would control the overall absorption rate.

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