Preparation and Properties of Nano-Calcium Carbonate Modified PVC Using Ultrasonic Irradiation

Author(s):  
Shengfei Hu ◽  
Wen Chen ◽  
Huaxing Li

PVC/nano-CaCO3 composites were prepared through ultrasonic irradiation. The optimum time of ultrasonic irradiation is 30 min. The fracture toughness of the nanocomposites was investigated by J-integral method based on the mechanical properties and morphology. Compared with corresponding nanocomposites and unfilled PVC, the prepared nanocomposites exhibit outstanding mechanical performances. The mechanical properties of spindly shaped CaCO3 filled PVC are better than these of the cubic nano-CaCO3, which are likely attributed to high aspect ratio of spindly shaped nano-CaCO3. In addition, the mechanical properties of PVC/nano-CaCO3 composites can be improved considerably when the content of nano-CaCO3 is 5–15 phr. Ultrasonic irradiation realizes the excellent dispersion of nanoparticles in the PVC, and offers a new way to deal with the challenges encountered in preparing polymer/nanocomposites materials.

Alloy Digest ◽  
2008 ◽  
Vol 57 (12) ◽  

Abstract Ferrium S53 was developed for use as a structural corrosion resistant steel for aircraft landing gear. S53 has a corrosion resistance equivalent to 440C, strength equivalent to or better than 300M (AMS 6257A) and SAE 4340 (see Mechanical Properties), optimum microstructure features for maximum fatigue resistance, and a surface hardenability equal to or greater than 67 HRC for wear and fatigue. This datasheet is an update to Alloy Digest SS-942 and SS-1003. This datasheet provides information on composition, physical properties, hardness, and tensile properties as well as fracture toughness. It also includes information on corrosion resistance as well as heat treating and machining. Filing Code: SA-589. Producer or source: QuesTek Innovations, LLC.


2011 ◽  
Vol 194-196 ◽  
pp. 1103-1108 ◽  
Author(s):  
Yong Xin Yang ◽  
Jie Lian

In this paper, mechanical performances of 480 specimens are tested and influences of basalt fiber ratio, slenderness, soakage material are studied. Results indicate that mechanical properties of BFRC are better than plain concrete. It can be found that the best mechanical performance may be get when the basalt fiber soaked by water-solubility material and its ratio at 8.4 to 14 kg per square meter as well as slenderness at 600 to 800.


2021 ◽  
Author(s):  
WU XU ◽  
JIANCAN DING

Due to the interlaminar properties of composites are low, delamination is one of the major failure modes. It threatens the safety of composite structure subjected to out-of-plane static and especially impact loadings. High interlaminar fracture toughness is demanded in the society where composite structures are widely used. However, for tough material, large deformation may occur in the determination of the interlaminar fracture toughness when using the double cantilever beam (DCB) test. Therefore, accurate determination of the fracture toughness of tough material and dynamic loading is very challenging under large deformation. J-integral is an important parameter in fracture mechanics. It’s equivalent to energy release rate under monotonic loading and widely used in the determination of interlaminar fracture toughness of composites. In this paper, it is used to determine the fracture toughness for composite DCB under large deformation and wedge-insert double cantilever beam (WDCB) test, which is widely used to determine the dynamic interlaminar fracture toughness. Exact and closed form nonlinear J-integrals are derived for the largely deformed DCB and WDCB. Compared with the alternative data reduction methods for determining interlaminar fracture toughness, the J- integral method is more accurate. In addition, the J-integral method is simple and promising, since it is unnecessary to measure the crack length in the tests.


2009 ◽  
Vol 24 (6) ◽  
pp. 2056-2065 ◽  
Author(s):  
Diletta Sciti ◽  
Laura Silvestroni ◽  
Stefano Guicciardi ◽  
Daniele Dalle Fabbriche ◽  
Alida Bellosi

Fully dense HfC and TaC-based composites containing 15 vol% TaSi2 or MoSi2 were produced by hot pressing at 1750–1900 °C. TaSi2 enhanced the sinterability of the composites and nearly fully dense materials were obtained at lower temperatures than in the case of MoSi2-containing ones. The TaC-based composites performed better than HfC composites at room temperature, showing values of mechanical strength up to 900 MPa and a fracture toughness of 4.7 MPa·m1/2. However, preliminary oxidation tests carried out in air at 1600 °C revealed that HfC-based composites have a superior high temperature stability compared to TaC-based materials.


2013 ◽  
Vol 812 ◽  
pp. 241-245 ◽  
Author(s):  
Fatimah A’thiyah Sabaruddin ◽  
Noorasikin Samat

Polymer nanocomposites containing polypropylene (PP) as the polymer matrix and nanofiller aluminium hydroxide (ATH) as the flame retardant filler were compounded with various loading of maleic anhydride grafted polypropylene, MAPP (0, 1, 2, 3, 5 wt %). All materials were mixed using melt mixing process and were further prepared using an injection moulding machine. The mechanical performances of the samples were characterized using tensile and impact tests. Improvements were observed for the tensile and impact properties of the PP/ATH samples after being loaded with MAPP. MAPP loading of 1 wt % was determined to be the optimum content of coupling agent addition as this loading enabled the best performance of the nanocomposite in tensile and impact tests. Different morphologies of the fracture surfaces for all samples were characterized using FESEM analysis.


2007 ◽  
Vol 353-358 ◽  
pp. 599-602
Author(s):  
Sung Rok Ha ◽  
Kyong Yop Rhee ◽  
H.H. Shin

It is well-known that the mechanical properties of nanocomposites are better than those of conventional composites. One of problems in fabricating nanocomposites is a dispersion of nanoparticles in the composites. In this study, the effect of MMT content on the tensile characteristics of trifunctional silane-treated MMT/epoxy nanocomposite was investigated. It was found that the tensile strength and the elastic modulus increased by over 24% and 83%, respectively, as the content of MMT increases from 2wt% to 10wt%. The improvement of tensile strength and modulus with increasing content of MMT occurs because the reinforcing effect of MMT becomes greater than the deteriorating effect due to the interfacial debonding between MMT and epoxy as the MMT content increases.


2013 ◽  
Vol 592-593 ◽  
pp. 173-176 ◽  
Author(s):  
Egor Moskvichev

In this paper the mechanical heterogeneity of welded joints was studied. The experimental results show that the mechanical properties and fracture toughness vary significantly in zones of welded joint. To estimate the fracture parameter J-integral a numerical finite-element model based on the random variation of yield strength was proposed.


2012 ◽  
Vol 454 ◽  
pp. 122-125
Author(s):  
Yu Zhi Jiang ◽  
Li Li Zhang ◽  
Zhong Yang Zhang

The magnesium oxysulfate whiskers/PP composites were prepared by melt-extrusion with modified whiskers as fillers. The mechanical performances including the tensile strength, elongation at break and elastic modulus were tested by electronic universal testing machine.The effect of surface modifier on the mechanical properties of the composites was studied. In general, the mechanical properties of the composites of the zinc stearate modified whiskers/PP were better than it modified by coupling agent KH550. when the contents of the whiskers modified were 20%, the mechanical properties of the composites got the best. There occurred different organic molecule membranes on the surface of the modified whiskers, which lowered the interfacial energy of whiskers. So modified whiskers had different strengthening with PP matrix.


2012 ◽  
Vol 723 ◽  
pp. 353-357
Author(s):  
Guo Jun Zhang ◽  
Zhi Ping Sun ◽  
Li Yan Zou

The microstructure and mechanical properties of samples were examined, and the relationship of structure and mechanical properties for VC/Fe composite sintered at different holding time were studied. Holding time can influence the mechanical properties, with the holding time rising, when the holding time is 80 min, the hardness is Max, it’s 10.71 GPa, the enhancing range is 37.66%; The relative density changes slower from 60 to 100 min; when the holding time is 60 minutes, fracture toughness and bending strength of material is 16.17 MPa•m 1/2 and 1070 MPa, it’s better than before.


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