Friction-reducing mechanisms of molybdenum dithiocarbamate/zinc dithiophosphate combination: New insights in MoS2 genesis

1999 ◽  
Vol 17 (3) ◽  
pp. 884-890 ◽  
Author(s):  
C. Grossiord ◽  
J.-M. Martin ◽  
Th. Le Mogne ◽  
K. Inoue ◽  
J. Igarashi
2018 ◽  
Vol 70 (5) ◽  
pp. 878-887 ◽  
Author(s):  
Zeqi Jiang ◽  
Jianhua Fang ◽  
Fei Chen ◽  
Boshui Chen ◽  
Kecheng Gu

Purpose This paper aims at understanding tribological properties of lubricating oils doped with zinc dithiophosphate(ZDDP) with and without electromagnetic field impact. Design/methodology/approach The friction and wear properties of the oils formulated with zinc butyloctyl dithiophosphate (T202) or zinc dioctyl dithiophosphate (T203) under electromagnetic field or nonelectromagnetic field were evaluated on a modified four-ball tribotester. The characteristics of the worn surfaces obtained from electromagnetic or nonelectromagnetic field conditions were analyzed by scanning electronic microscopy, energy dispersive spectrometer and X-ray photoelectron spectroscopy. This paper focuses on understanding influence of electromagnetic field on lubrication effect of the ZDDP-formulated oils. Findings The electromagnetic field could effectively facilitate anti-wear and friction-reducing properties of the oils doped with T202 or T203 as compared to those without electromagnetism affection, and the T203-doped oils were more susceptible to the electromagnetic field. The improvement of anti-wear and friction-reducing abilities of the tested oils were mainly attributed to the promoted tribochemical reactions and the modification of the worn surfaces (forming Zn-Fe solid solution) induced by the electromagnetic field. Originality/value This paper has revealed that tribological performances of ZDDP-doped oils could be improved by the electromagnetic field and discussed its lubrication mechanisms. Investigating tribological properties of additives from the viewpoint of electromagnetics is a new attempt, which has significance not only for the choose and designing of additives in electromagnetic condition but also for development of tribological theories and practices.


Friction ◽  
2021 ◽  
Author(s):  
Weiwei Tang ◽  
Xuejun Zhu ◽  
Yufeng Li

AbstractAdvances in nano-lubricant additives are vital to the pursuit of energy efficiency and sustainable development. Carbon dots (CDs) have been widely investigated in the domain of lubricant additives owing to their extraordinary tribological properties, in particular, their friction-reducing and anti-wear properties. Metal-doped CDs are a new type of CDs, and their friction-reducing and anti-wear properties are attracting increasing attention. Therefore, a series of CDs doped with various divalent metal ions have been successfully synthesized via one-pot pyrolysis. The tribological properties of the synthesized CDs as water-based lubricant additives are in the following order: Zn-CDs > Cu-CDs ≫ Mg-CDs > Fe-CDs > U-CDs. Specifically, adding 1.0 wt% of Zn-CDs into water-based lubricant results in 62.5% friction and 81.8% wear reduction. Meanwhile, the load-carrying capacity of the water-based lubricant increases from 120 N to at least 500 N. Zn-CDs as an additive have long service life. Additionally, anion-tuned Zn-CDs fabricated via anion exchange exhibit promise as lubricant additives for poly(ethylene glycol). Based on the results of wear scar surface analyses, it is discovered that tribochemical films, primarily composed of iron oxides, nitrides, metal carbonates, zinc oxides, zinc carbonates, organic compounds, and embedded carbon cores, formed on the rubbing surfaces with a thickness of approximately 270 nm when Zn-CDs are used as additives. This film combined with the “ball-bearing” and third-particle effects of Zn-CDs contributed to excellent lubrication performance.


2015 ◽  
Vol 2015 ◽  
pp. 1-7 ◽  
Author(s):  
Yu Su ◽  
Le Gong ◽  
Dandan Chen

This paper used graphite nanoparticles with the diameter of 35 and 80 nm and LB2000 vegetable based oil to prepare graphite oil-based nanofluids with different volume fractions by two-step method. The tribological properties of graphite nanoparticles as LB2000 vegetable based oil additive were investigated with a pin-on-disk friction and wear tester. Field emission scanning electron microscope (FE-SEM) and energy dispersive spectroscopy (EDS) were used to examine the morphology and the content of some typical elements of wear scar, respectively. Further, the lubrication mechanism of graphite nanoparticles was explored. It was found that graphite nanoparticles as vegetable based oil additive could remarkably improve friction-reducing and antiwear properties of pure oil. With the increase of volume fraction of graphite nanoparticles, the friction coefficient and the wear volume of disk decreased. At the same volume fraction, the smaller particles, the lower friction coefficient and wear volume. The main reason for the improvement in friction-reducing and antiwear properties of vegetable based oil using graphite nanoparticles was that graphite nanoparticles could form a physical deposition film on the friction surfaces.


1988 ◽  
Vol 110 (3) ◽  
pp. 394-401 ◽  
Author(s):  
Y. Tanita ◽  
F. Honda ◽  
K. Nakajima

The behavior of zinc dithiophosphate (ZnDTP) is investigated for the antiwear properties in SiC-steel and Si3N4-steel sliding contact systems under boundary lubrication. Reaction products formed on the steel surfaces under the sliding contact differ in the chemical compositions and the thickness between these couples. These differences are specifically related to the physical properties of mating materials such as heat conductivity and friction coefficient. The reaction products are analyzed by SEM (scanning electron microscope), EPMA (electron probe microanalysis), AES (Auger electron spectroscope), and PAS (photoacoustic spectroscopy), and it is confirmed that iron phosphate for SiC-steel and iron phosphate and zinc sulfide (or some complex compound containing equal amounts of Zn and S in atomic ratio) for Si3N4-steel couple exist on the steel surface, respectively. An examination is conducted on steel-steel couple in comparison with ceramics-steel couples, and the atomic ratio (Zn:P:S) of the constituent elements of the reaction products coincides fairly with that of SiC-steel couple.


2018 ◽  
Vol 33 (03) ◽  
pp. 583-595 ◽  
Author(s):  
Ahmed F. Ibrahim ◽  
Hisham A. Nasr-El-Din ◽  
Ahmed Rabie ◽  
Genyao Lin ◽  
Jian Zhou ◽  
...  

2021 ◽  
Author(s):  
Mikhail Yurievich Golenkin ◽  
Denis Vladimirovich Eliseev ◽  
Alexander Anatolyevich Zemchikhin ◽  
Alexey Alexandrovich Borisenko ◽  
Akhmat Sakhadinovich Atabiyev ◽  
...  

Abstract The paper describes the results of the first multistage hydraulic fracturing operations in Russia on the Caspian Sea shelf in the gas condensate and oil deposits of the Aptian formation of V. Filanovsky field. In addition to the small productive formation depth, long horizontal sections with a complex trajectory and high collapse gradients due to large zenith angles when passing the Albian and Aptian deposits of poorly consolidated sandstones are an additional challenge for choosing a multistage hydraulic fracturing assembly. The above features require the use of modern sand control screens with enhanced frac sleeves. A design was developed which includes frac sleeves and sand control screens that can withstand multiple cycles of hydraulic impact during hydraulic fracturing, as well as many opening/closing cycles. A seawater-based frac fluid system was applied. The frac fleet was located on a pontoon, the coiled tubing – on a platform. For the first time in Russia, a 2-5/8 inch coiled tubing with a complex-type friction reducing system was used to switch coupling/sleeves in conditions of very long horizontal sections, complex trajectories, and high friction coefficients. The minimum distances between the screen's sliding sleeves and frac sleeves did not prevent from performing manipulations in complex environment. For well cleaning, the frac assemblies of reverse rotary-pulse and rotary-directional types were used. At the first stage of the project, the development of an optimal method of well completion was successfully implemented. Due to the close interaction of the operating company, service company, and science & engineering team of the operator, for the first time in Russia the design of downhole equipment with the use of advanced technologies of sand control screens, frac sleeves was presented. This solution has proved its effectiveness – the downhole equipment has retained its operational properties after a long period of well operation and further in the process of hydraulic fracturing. At the second stage of the project, 32 MSHF operations were performed at four wells. To reduce nonproductive time and operational risks, a satellite communication complex was additionally deployed on the pontoon to join the engineering centers of Astrakhan, Moscow, and Houston. After finishing the well development, the design indicators for formation fluid rates were achieved, which proved the effectiveness of the stimulation of the field's target objects – this opens great prospects for further development of low-permeability reservoirs at offshore sites in the Caspian Sea. The successful project implementation and the achievement of the design values of oil flow rates has expanded the possibilities of commercial operation of the low-permeable Aptian formation, complicated by the presence of a gas cap and underlying water. A solution was presented for working in extended horizontal well sections with 2-5/8 inch coiled tubing together with a complex-type mechanical friction reducing system. The economic effect was achieved when solving tasks of manipulating mechanical screen couplings and frac port sleeves without the involvement of downhole tractors. The use of new solutions in the completion assembly made it possible to eliminate additional sand ingress problems.


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