AbstractExtreme Ultraviolet (EUV) lithography is gaining momentum as the patterning technology of choice for the semiconductor nodes with less than 70-nm half-pitch. As such, it must be ready for manufacturing in the 2006-2007 time frame, and it must be extendable to the lower limits of CMOS technology. Successful patterning of 40-nm dense lines in viable EUV photoresists indicates that today's resist materials may have the necessary resolution, but better optics are needed to verify this more rigorously. Although little is understood about the impact of line-edge roughness (LER) on device performance, it is generally assumed that EUV LER must be less than 3 nm 3σ. EUV lines have been printed with LER as low as 4 nm 3σ, but they were printed with unacceptable photospeed. Deliberate attempts to increase the photospeed while maintaining low LER have produced a resist with sizing dose of 1.7 mJ/cm2 and LER of 6.6 nm 3σ. Photospeed is important because EUV photons are difficult to create, and the photoresist must use them efficiently for economically acceptable throughput. Throughput models indicate that patterning doses may need to be 1-2 mJ/cm2, and only 30-40% of these photons will be absorbed, so the resists must be able to accommodate statistical dose fluctuations that are an appreciable fraction of the mean dose. Highly sensitive resists such as these have been produced with good LER. Since all resist materials absorb EUV radiation strongly, the photoresist layer will have to be less than 150 nm thick. Resists this thin pose problems for device manufacturing, largely because they will not have acceptable etch resistance, and this etch resistance will have to be recovered in some other way. Efforts have begun to integrate hard masks with thin resists in real device fabrication. Defect data indicate that defect densities do not increase in resist films less than 100 nm thick, and transistors, via chains, and microprocessors have all been fabricated with these thin-resist/hard-mask integrations.
Dielectric Response Spectroscopy as Means to Investigate Interfacial Effects for Ultra-Thin Film Polymer-Based High NA EUV Lithography