scholarly journals Modern Concepts on Diamond Genesis

2021 ◽  
Vol 59 (11) ◽  
pp. 1038-1051
Author(s):  
F. V. Kaminsky ◽  
S. A. Voropaev
Keyword(s):  
Surface Tension ◽  
Surface Energy ◽  
Physical Properties ◽  
Trace Element ◽  
Thermodynamic Parameters ◽  
Isotope Composition ◽  
Volcanic Rocks ◽  
Metamorphic Rocks ◽  
Diamond Genesis

AbstractThe best-known, most well-studied diamondiferous rocks are kimberlites and lamproites. Diamonds are also found in impactites, metamorphic rocks, ophiolites, and modern volcanic rocks. Diamonds from these rocks differ from kimberlitic diamonds in size, morphology, trace-element and isotope composition, and physical properties. Differences in these characteristics are related to their different mechanisms of origin. In some cases, diamonds can be formed in “metastable” conditions under disequilibrium thermodynamic parameters, supporting the conclusion that diamond is a polygenetic mineral, formed in nature under different physicochemical and geodynamic conditions. According to thermodynamic considerations and calculations, “metastable” crystallization of diamond is mainly controlled by the size of the forming crystallites. The main effectors in decreasing the energetic barrier for nanosized diamonds are surface tension and related surface energy.

Lithium isotopes in kimberlites, lamproites and lamprophyres as tracers of source components and processes related to supercontinent cycles

2021 ◽  
pp. SP513-2021-60
Author(s):  
Lukáš Krmíček ◽  
Tomáš Magna ◽  
Ashutosh Pandey ◽  
N. V. Chalapathi Rao ◽  
Jindřich Kynický
Keyword(s):  
Isotope Composition ◽  
Volcanic Rocks ◽  
Dharwar Craton ◽  
Metamorphic Rocks ◽  
Eastern Dharwar Craton ◽  
Content Type ◽  
Bastar Craton ◽  
Li Isotope ◽  
Supplementary Material ◽  
Orogenic Belts

AbstractOur pilot study reveals potential fingerprints of Li isotopes recorded in the Mesoproterozoic (∼1.4-1.1 Ga) kimberlites, lamproites and lamprophyres from the Eastern Dharwar Craton and Paleocene (62 Ma) orangeite from the Bastar Craton in India. The new data are interpreted in the context of available Li isotope composition of lamproitic to lamprophyric rocks occurring in Variscan (Bohemian Massif) and Alpine-Himalayan (SW Tibet) orogenic belts formed in response to Gondwana-Pangea amalgamation and break-up. As a result of supercontinents development, kimberlites from the Eastern Dharwar Craton and ‘orangeite’ from the Bastar Craton show clear presence of a component with a heavy Li isotope signature (δ7Li up to 9.7‰) similar to an ancient altered oceanic crust, whereas the Eastern Dharwar Craton lamproites (2.3-6.3‰) and lamprophyres (3.3-6.7‰) show Li isotope signatures indicative of a dominant contribution from heterogeneous lithospheric mantle. Variscan lamprophyric to lamproitic rocks and post-collisional mantle-derived (ultra)potassic volcanic rocks from SW Tibet, i.e., rocks from the orogenic belts outside the cratonic areas, are characterized by a clear Li isotope shift towards isotopically lighter component (δ7Li as low as -9.5‰) comparable with the involvement of an evolved continental crust and high-pressure metamorphic rocks in their orogenic mantle source. Such components with isotopically light Li are strikingly missing in the source of cratonic kimberlites, lamproites and lamprophyres.Supplementary material at https://doi.org/10.6084/m9.figshare.c.5495097

The nucleation of cavities at grain boundaries

1987 ◽  
Vol 45 ◽  
pp. 288-291
Author(s):  
P. J. Goodhew
Keyword(s):  
Surface Tension ◽  
Surface Energy ◽  
Grain Boundaries ◽  
Radiation Damage ◽  
Impurity Concentration ◽  
Driving Force ◽  
Nucleation And Growth ◽  
Phase Boundaries ◽  
Cavity Nucleation ◽  
Spherical Bubble

Cavity nucleation and growth at grain and phase boundaries is of concern because it can lead to failure during creep and can lead to embrittlement as a result of radiation damage. Two major types of cavity are usually distinguished: The term bubble is applied to a cavity which contains gas at a pressure which is at least sufficient to support the surface tension (2g/r for a spherical bubble of radius r and surface energy g). The term void is generally applied to any cavity which contains less gas than this, but is not necessarily empty of gas. A void would therefore tend to shrink in the absence of any imposed driving force for growth, whereas a bubble would be stable or would tend to grow. It is widely considered that cavity nucleation always requires the presence of one or more gas atoms. However since it is extremely difficult to prepare experimental materials with a gas impurity concentration lower than their eventual cavity concentration there is little to be gained by debating this point.

TEM/AEM characterization of fine-grained clay minerals in very-low-grade rocks: Evaluation of contamination by empa involving celadonite family minerals

1996 ◽  
Vol 54 ◽  
pp. 694-695
Author(s):  
Gejing Li ◽  
D. R. Peacor ◽  
D. S. Coombs ◽  
Y. Kawachi
Keyword(s):  
Electron Microscopy ◽  
Volcanic Rocks ◽  
Analytical Electron Microscopy ◽  
Metamorphic Rocks ◽  
New Mineral ◽  
Chemical Compositions ◽  
Low Grade ◽  
Fine Grained ◽  
Depth Analysis ◽  
Mineral Aggregates

Recent advances in transmission electron microscopy (TEM) and analytical electron microscopy (AEM) have led to many new insights into the structural and chemical characteristics of very finegrained, optically homogeneous mineral aggregates in sedimentary and very low-grade metamorphic rocks. Chemical compositions obtained by electron microprobe analysis (EMPA) on such materials have been shown by TEM/AEM to result from beam overlap on contaminant phases on a scale below resolution of EMPA, which in turn can lead to errors in interpretation and determination of formation conditions. Here we present an in-depth analysis of the relation between AEM and EMPA data, which leads also to the definition of new mineral phases, and demonstrate the resolution power of AEM relative to EMPA in investigations of very fine-grained mineral aggregates in sedimentary and very low-grade metamorphic rocks.Celadonite, having end-member composition KMgFe3+Si4O10(OH)2, and with minor substitution of Fe2+ for Mg and Al for Fe3+ on octahedral sites, is a fine-grained mica widespread in volcanic rocks and volcaniclastic sediments which have undergone low-temperature alteration in the oceanic crust and in burial metamorphic sequences.

ASSESSING TRACE ELEMENT (DIS)EQUILIBRIUM AND THE APPLICATION OF SINGLE ELEMENT THERMOMETERS IN METAMORPHIC ROCKS

2016 ◽  
Author(s):  
Alicia M. Cruz-Uribe ◽  
◽  
Maureen Feineman ◽  
Thomas Zack ◽  
Dorrit E. Jacob
Keyword(s):  
Trace Element ◽  
Metamorphic Rocks ◽  
Single Element

Petrogenesis of the peralkaline Flowers River Igneous Suite and its significance to the development of the southern Nain Batholith

2021 ◽  
pp. 1-26
Author(s):  
Taylor A. Ducharme ◽  
Christopher R.M. McFarlane ◽  
Deanne van Rooyen ◽  
David Corrigan
Keyword(s):  
Trace Element ◽  
Volcanic Rocks ◽  
Second Phase ◽  
Discrete Events ◽  
Volcanic Event ◽  
Volcanic Succession ◽  
Intrusive Suite ◽  
Tectonic Boundaries ◽  
Host Rocks ◽  
Nain Plutonic Suite

Abstract The Flowers River Igneous Suite of north-central Labrador comprises several discrete peralkaline granite ring intrusions and their coeval volcanic succession. The Flowers River Granite was emplaced into Mesoproterozoic-age anorthosite–mangerite–charnockite–granite (AMCG) -affinity rocks at the southernmost extent of the Nain Plutonic Suite coastal lineament batholith. New U–Pb zircon geochronology is presented to clarify the timing and relationships among the igneous associations exposed in the region. Fayalite-bearing AMCG granitoids in the region record ages of 1290 ± 3 Ma, whereas the Flowers River Granite yields an age of 1281 ± 3 Ma. Volcanism occurred in three discrete events, two of which coincided with emplacement of the AMCG and Flowers River suites, respectively. Shared geochemical affinities suggest that each generation of volcanic rocks was derived from its coeval intrusive suite. The third volcanic event occurred at 1271 ± 3 Ma, and its products bear a broad geochemical resemblance to the second phase of volcanism. The surrounding AMCG-affinity ferrodiorites and fayalite-bearing granitoids display moderately enriched major- and trace-element signatures relative to equivalent lithologies found elsewhere in the Nain Plutonic Suite. Trace-element compositions also support a relationship between the Flowers River Granite and its AMCG-affinity host rocks, most likely via delayed partial melting of residual parental material in the lower crust. Enrichment manifested only in the southernmost part of the Nain Plutonic Suite as a result of its relative proximity to multiple Palaeoproterozoic tectonic boundaries. Repeated exposure to subduction-derived metasomatic fluids created a persistent region of enrichment in the underlying lithospheric mantle that was tapped during later melt generation, producing multiple successive moderately to strongly enriched magmatic episodes.

The Caledonoid faults of northern Lleyn (North Wales)

1970 ◽  
Vol 107 (3) ◽  
pp. 235-247 ◽  
Author(s):  
W. E. Tremlett
Keyword(s):  
Volcanic Rocks ◽  
Strike Slip ◽  
Metamorphic Rocks ◽  
Red Sandstone ◽  
North Wales ◽  
Dextral Strike Slip

SummaryEvidence of substantial dextral strike-slip displacements along the Caledonoid fault-set of northern Lleyn is revealed by the distribution of Pre-Cambrian igneous and metamorphic rocks, Ordovician volcanic rocks and Caledonian ‘early granodioritic’ intrusions. These apparently occurred prior to some smaller sinistral strike-slip movements which left total net dextral displacements of 91/2 km. Both types of movement were completed before the Caledonoid faults were disrupted by NNW sinistral faulting and more intrusions of Lower Old Red Sandstone age were emplaced.

Influence of alteration on physical properties of volcanic rocks

2012 ◽  
Vol 566-567 ◽  
pp. 67-86 ◽  
Author(s):  
Antonio Pola ◽  
Giovanni Crosta ◽  
Nicoletta Fusi ◽  
Valentina Barberini ◽  
Gianluca Norini
Keyword(s):  
Physical Properties ◽  
Volcanic Rocks

Geochemistry and Isotope Composition of Paleoproterozoic Granites and Felsic Volcanics of the Elash Graben: Evidence of the Heterogeneity of the Early Precambrian Crust

2021 ◽  
Vol 62 (10) ◽  
pp. 1175-1187
Author(s):  
A.D. Nozhkin ◽  
O.M. Turkina ◽  
K.A. Savko
Keyword(s):  
Isotope Composition ◽  
Volcanic Rocks ◽  
Rare Metal ◽  
Temporal Association ◽  
Metal Deposit ◽  
Wide Range ◽  
Rare Metal Deposit ◽  
Geochronological Study ◽  
Felsic Volcanic ◽  
Felsic Volcanic Rocks

Abstract —The paper presents results of a petrogeochemical and isotope–geochronological study of the granite–leucogranite association of the Pavlov massif and felsic volcanics from the Elash graben (Biryusa block, southwest of the Siberian craton). A characteristic feature of the granite–leucogranites is their spatial and temporal association with vein aplites and pegmatites of the East Sayan rare-metal province. The U–Pb age of zircon from granites of the Pavlov massif (1852 ± 5 Ma) is close to the age of the pegmatites of the Vishnyakovskoe rare-metal deposit (1838 ± 3 Ma). The predominant biotite porphyritic granites and leucogranites of the Pavlov massif show variable alkali ratios (K2O/Na2O = 1.1–2.3) and ferroan (Fe*) index and a peraluminous composition; they are comparable with S-granites. The studied rhyolites of the Tagul River (SiO2 = 71–76%) show a low ferroan index, a high K2O/Na2O ratio (1.6–4.0), low (La/Yb)n values (4.3–10.5), and a clear Eu minimum (Eu/Eu* = 0.3–0.5); they are similar to highly fractionated I-granites. All coeval late Paleoproterozoic (1.88–1.85 Ga) granites and felsic volcanics of the Elash graben have distinct differences in composition, especially in the ferroan index and HREE contents, owing to variations in the source composition and melting conditions during their formation at postcollisions extension. The wide range of the isotope parameters of granites and felsic volcanic rocks (εNd from +2.0 to –3.7) and zircons (εHf from +3.0 to +0.8, granites of the Toporok massif) indicates the heterogeneity of the crustal basement of the Elash graben, which formed both in the Archean and in the Paleoproterozoic.

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