The role of magma injection and crystal sorting in the formation of early gabbros at the Coldwell Complex, Ontario, Canada

2019 ◽  
Vol 56 (7) ◽  
pp. 715-737 ◽  
Author(s):  
Yong-hua Cao ◽  
David J. Good ◽  
Robert L. Linnen ◽  
Iain M. Samson
Keyword(s):  
Major Element ◽  
Mineral Chemistry ◽  
Ultramafic Rocks ◽  
Chemical Compositions ◽  
Olivine Gabbro ◽  
Additional Observation ◽  
Midcontinent Rift ◽  
Layered Series ◽  
Incompatible Elements

The Layered Series of the Midcontinent Rift related Coldwell Complex comprises thick sections of gabbro, without any known associated ultramafic rocks. It represents a major early intrusive unit of the Coldwell Complex and consists of thick accumulations of olivine gabbro and oxide augite melatroctolite. This study combines petrography, mineral chemistry, and lithogeochemistry to constrain the magma composition and petrogenesis of the Layered Series. The presence of cumulus orthoclase together with the observation that the Layered Series rocks plot in the alkaline field on a total alkali–silica diagram indicate that the Layered Series magma has an alkaline parentage. The stratigraphy of the Layered Series cannot be fully correlated between different areas using lithogeochemistry and mineral chemistry. This together with observed normal and reverse trends for mineral chemical compositions in different areas suggest that the processes related to magma emplacement and crystallization were different in different locations. The whole-rock concentrations of incompatible elements and the compositions of major minerals of the olivine gabbro and oxide augite melatroctolite units are chemically similar. However, major element lithogeochemistry is variable, dominantly due to differences in the abundances of olivine, clinopyroxene, plagioclase, and magnetite. An additional observation is that olivine and clinopyroxene are not in chemical equilibrium. Together, these observations are interpreted to reflect a combination of multiple injections of magma and crystal sorting in an open system.

The Harp dikes and their relationship to the Helikian geological record in central Labrador

1977 ◽  
Vol 14 (12) ◽  
pp. 2683-2696 ◽  
Author(s):  
R. E. Meyers ◽  
R. F. Emslie
Keyword(s):  
Major Element ◽  
Mineral Chemistry ◽  
Olivine Gabbro ◽  
Crustal Extension ◽  
Hypabyssal Intrusions ◽  
Major Element Chemistry ◽  
The World ◽  
Basaltic Magmas ◽  
Basic Magmatism ◽  
Uplift And Erosion

The Harp olivine diabase dikes, of Neohelikian age, form an east-northeast trending swarm that cuts rocks of the Harp Lake Complex in central Labrador. The petrography, and rock and mineral chemistry of the dikes indicate that they are transitional in character between tholeiitic and alkalic compositions. The major element chemistry of the dikes is similar to basaltic magmas from other comparable continental settings and in particular closely resembles basalts and diabase sills of the Neohelikian Seal Lake Group.Correlation of the Seal Lake – Harp dikes magmatism is suggested with two other groups of hypabyssal intrusions of olivine gabbro east and southeast of the Seal Lake synclinorium (Michael gabbros and diabase dikes in the Mealy Mountains complex). All of this basic magmatism may have been related to a Neohelikian zone of continental rifting or incipient rifting. Intrusion and extrusion of basic magma under conditions indicative of crustal extension closely follows, or is associated with, uplift and erosion of anorogenic anorthosite–'granite' complexes in other places in the world and is inferred to be a consequence of a continuing evolving process of mantle–crust interactions; in Labrador, the process began in the Paleohelikian with intrusion of major anorthosite–adamellite complexes.

scholarly journals A 3D study on the amplification of regional haze and particle growth by local emissions

2021 ◽  
Vol 4 (1) ◽  
Author(s):  
Wei Du ◽  
Lubna Dada ◽  
Jian Zhao ◽  
Xueshun Chen ◽  
Kaspar R. Daellenbach ◽  
...  
Keyword(s):  
Atmospheric Stability ◽  
Ground Level ◽  
Particle Growth ◽  
Chemical Compositions ◽  
Size Distributions ◽  
Aerosol Composition ◽  
Regional Haze ◽  
Haze Formation ◽  
Beijing China

AbstractThe role of new particle formation (NPF) events and their contribution to haze formation through subsequent growth in polluted megacities is still controversial. To improve the understanding of the sources, meteorological conditions, and chemistry behind air pollution, we performed simultaneous measurements of aerosol composition and particle number size distributions at ground level and at 260 m in central Beijing, China, during a total of 4 months in 2015–2017. Our measurements show a pronounced decoupling of gas-to-particle conversion between the two heights, leading to different haze processes in terms of particle size distributions and chemical compositions. The development of haze was initiated by the growth of freshly formed particles at both heights, whereas the more severe haze at ground level was connected directly to local primary particles and gaseous precursors leading to higher particle growth rates. The particle growth creates a feedback loop, in which a further development of haze increases the atmospheric stability, which in turn strengthens the persisting apparent decoupling between the two heights and increases the severity of haze at ground level. Moreover, we complemented our field observations with model analyses, which suggest that the growth of NPF-originated particles accounted up to ∼60% of the accumulation mode particles in the Beijing–Tianjin–Hebei area during haze conditions. The results suggest that a reduction in anthropogenic gaseous precursors, suppressing particle growth, is a critical step for alleviating haze although the number concentration of freshly formed particles (3–40 nm) via NPF does not reduce after emission controls.

scholarly journals Geochemical signatures of mineralizing events in the Juomasuo Au–Co deposit, Kuusamo belt, northeastern Finland

2021 ◽  
Author(s):  
Mikael Vasilopoulos ◽  
Ferenc Molnár ◽  
Hugh O’Brien ◽  
Yann Lahaye ◽  
Marie Lefèbvre ◽  
...  
Keyword(s):  
Trace Element ◽  
Sulfur Isotope ◽  
Mineral Chemistry ◽  
Chemical Compositions ◽  
Metasedimentary Rocks ◽  
Metavolcanic Rocks ◽  
Icp Ms ◽  
Stage 1 ◽  
Host Rocks ◽  
Relationship Of

AbstractThe Juomasuo Au–Co deposit, currently classified as an orogenic gold deposit with atypical metal association, is located in the Paleoproterozoic Kuusamo belt in northeastern Finland. The volcano-sedimentary sequence that hosts the deposit was intensely altered, deformed, and metamorphosed to greenschist facies during the 1.93–1.76 Ga Svecofennian orogeny. In this study, we investigate the temporal relationship between Co and Au deposition and the relationship of metal enrichment with protolith composition and alteration mineralogy by utilizing lithogeochemical data and petrographic observations. We also investigate the nature of fluids involved in deposit formation based on sulfide trace element and sulfur isotope LA-ICP-MS data together with tourmaline mineral chemistry and boron isotopes. Classification of original protoliths was made on the basis of geochemically immobile elements; recognized lithologies are metasedimentary rocks, mafic, intermediate-composition, and felsic metavolcanic rocks, and an ultramafic sill. The composition of the host rocks does not control the type or intensity of mineralization. Sulfur isotope values (δ34S − 2.6 to + 7.1‰) and trace element data obtained for pyrite, chalcopyrite, and pyrrhotite indicate that the two geochemically distinct Au–Co and Co ore types formed from fluids of different compositions and origins. A reduced, metamorphic fluid was responsible for deposition of the pyrrhotite-dominant, Co-rich ore, whereas a relatively oxidized fluid deposited the pyrite-dominant Au–Co ore. The main alteration and mineralization stages at Juomasuo are as follows: (1) widespread albitization that predates both types of mineralization; (2) stage 1, Co-rich mineralization associated with chlorite (± biotite ± amphibole) alteration; (3) stage 2, Au–Co mineralization related to sericitization. Crystal-chemical compositions for tourmaline suggest the involvement of evaporite-related fluids in formation of the deposit; boron isotope data also allow for this conclusion. Results of our research indicate that the metal association in the Juomasuo Au–Co deposit was formed by spatially coincident and multiple hydrothermal processes.

scholarly journals Petrogenetic and Compositional Features of Rare Metal Pan-African Post-Collisional Pegmatites of Southwestern Nigeria; A Status Review

2018 ◽  
Vol 7 (2) ◽  
pp. 166-187
Author(s):  
Abiola Oyebamiji ◽  
Adeniyi JohnPaul Adewumi ◽  
Tehseen Zafar ◽  
Adegbola Odebunmi ◽  
Philips Falae ◽  
...  
Keyword(s):  
Mineral Chemistry ◽  
Rare Metal ◽  
Border Zone ◽  
Chemical Compositions ◽  
Molten Material ◽  
Southwestern Nigeria ◽  
Pan African ◽  
Opening And Closing ◽  
High Degree ◽  
Rare Metal Pegmatite

Abstract This research reviews the geology, petrogenesis, compositional trends and geochronology of the rare-metal pegmatite of southwestern Nigeria. The source of these pegmatites is still presently debated which have been explained as either product of highly fractionated molten material or anatexis of the local crust. However, published works of past authors have been compiled to give a detailed understanding of the formation of the mineral deposits. The basement complex of southwestern Nigeria comprises of Precambrian rocks of amphibolite, the hornblende gneiss and the granite gneisses which were formed as a result of the opening and closing of the ensialic basin with significant, extensive subduction during the Pan-African orogeny. The pegmatites in this region have shown internal zoning and a high degree of evolution from the border zone to the core zone during the crystallization and solidification of the felsic granite to pegmatite melt. The rare-metal pegmatites have distinct chemical compositions and mineralogy, containing quartz, biotite, muscovite, microcline, garnet with localized tourmaline, tantalite and columbite. These pegmatites vary significantly by their bulk-rock and mineral chemistry which indicates a more peraluminous attribute and enrichments of lithophile elements of Rb, Cs, Ta and Ba. Previous K/Ar isotopic ages (502.8±13.0 Ma and 514.5±13.2 Ma) suggest that the pegmatites are related to the post-collisional phase of intensive metasomatism. Adopted from previous studies, a five-stage conceptual model of evolution which is widely accepted have been proposed for the origin of the pegmatites.

scholarly journals The role of chlorite dehydration in ultramafic rocks for slab melting and element recycling in subducted crust

2021 ◽  
Author(s):  
Jörg Hermann ◽  
Matthias Lederer ◽  
Shayne Lakey ◽  
Daniela Rubatto
Keyword(s):  
Ultramafic Rocks ◽  
Slab Melting

scholarly journals TephraNZ: a major and trace element reference dataset for prominent Quaternary rhyolitic tephras in New Zealand and implications for correlation

2020 ◽  
Author(s):  
Jenni L. Hopkins ◽  
Janine E. Bidmead ◽  
David J. Lowe ◽  
Richard J. Wysoczanski ◽  
Bradley J. Pillans ◽  
...  
Keyword(s):  
New Zealand ◽  
Trace Element ◽  
Major Element ◽  
Chemical Compositions ◽  
Volcanic Centre ◽  
Reference Dataset ◽  
Future Studies ◽  
Glass Shard ◽  
Tephra Deposits ◽  
Glass Shards

Abstract. Although analyses of tephra-derived glass shards have been undertaken in New Zealand for nearly four decades (pioneered by Paul Froggatt), our study is the first to systematically develop a formal, comprehensive, open access, reference dataset of glass-shard compositions for New Zealand tephras. These data will provide an important reference tool for future studies to identify and correlate tephra deposits and for associated petrological and magma-related studies within New Zealand and beyond. Here we present the foundation dataset for TephraNZ, an open access reference dataset for selected tephra deposits in New Zealand. Prominent, rhyolitic, tephra deposits from the Quaternary were identified, with sample collection targeting original type sites or reference locations where the tephra's identification is unequivocally known based on independent dating or mineralogical techniques. Glass shards were extracted from the tephra deposits and major and trace element geochemical compositions were determined. We discuss in detail the data reduction process used to obtain the results and propose that future studies follow a similar protocol in order to gain comparable data. The dataset contains analyses of twenty-three proximal and twenty-seven distal tephra samples characterising 45 eruptive episodes ranging from Kaharoa (636 ± 12 cal. yrs BP) to the Hikuroa Pumice member (2.0 ± 0.6 Ma) from six or more caldera sources, most from the central Taupō Volcanic Zone. We report 1385 major element analyses obtained by electron microprobe (EMPA), and 590 trace element analyses obtained by laser ablation (LA)-ICP-MS, on individual glass shards. Using PCA, Euclidean similarity coefficients, and geochemical investigation, we show that chemical compositions of glass shards from individual eruptions are commonly distinguished by major elements, especially CaO, TiO2, K2O, FeOt (Na2O+ K2O and SiO2/K2O), but not always. For those tephras with similar glass major-element signatures, some can be distinguished using trace elements (e.g. HFSEs: Zr, Hf, Nb; LILE: Ba, Rb; REE: Eu, Tm, Dy, Y, Tb, Gd, Er, Ho, Yb, Sm), and trace element ratios (e.g. LILE / HFSE: Ba / Th, Ba / Zr, Rb / Zr; HFSE / HREE: Zr / Y, Zr / Yb, Hf / Y; LREE / HREE: La / Yb, Ce / Yb). Geochemistry alone cannot be used to distinguish between glass shards from the following tephra groups: Taupō (Unit Y in the post-Ōruanui eruption sequence of Taupō volcano) and Waimihia (Unit S); Poronui (Unit C) and Karapiti (Unit B); Rotorua and Rerewhakaaitu; and Kawakawa/Ōruanui, Okaia, and Unit L (of the Mangaone subgroup eruption sequence). Other characteristics can be used to separate and distinguish all of these otherwise-similar eruptives except Poronui and Karapiti. Bimodality caused by K2O variability is newly identified in Poihipi and Tahuna tephras. Using glass shard compositions, tephra sourced from Taupō Volcanic Centre (TVC) and Mangakino Volcanic Centre (MgVC) can be separated using bivariate plots of SiO2/K2O vs. Na2O+K2O. Glass shards from tephras derived from Kapenga Volcanic Centre, Rotorua Volcanic Centre, and Whakamaru Volcanic Centre have similar major- and trace-element chemical compositions to those from the MgVC, but can overlap with glass analyses from tephras from Taupō and Okataina volcanic centres. Specific trace elements and trace element ratios have lower variability than the heterogeneous major element and bimodal signatures, making them easier to geochemically fingerprint.

Differential weathering in ultramafic rocks of New Caledonia: The role of infiltration instability

2017 ◽  
Vol 550 ◽  
pp. 268-278 ◽  
Author(s):  
Pierre Genthon ◽  
Jean-Lambert Join ◽  
Julie Jeanpert
Keyword(s):  
New Caledonia ◽  
Ultramafic Rocks

scholarly journals Petrology, mineral chemistry, and geochemistry of Late Triassic Ni–Cu ore-bearing mafic–ultramafic intrusions, Hongqiling, northeastern China: petrogenesis and tectonic implications

2019 ◽  
Vol 56 (2) ◽  
pp. 111-128
Author(s):  
Ai Li ◽  
Jian Wang ◽  
Yue Song
Keyword(s):  
Crustal Contamination ◽  
Parental Magma ◽  
Mineral Chemistry ◽  
Late Triassic ◽  
Sulfide Deposit ◽  
Chemical Compositions ◽  
Tholeiitic Magma ◽  
Average Value ◽  
Central Asian ◽  
History Of

The Hongqiling magmatic Ni–Cu sulfide deposit, situated on the southern margin of the eastern Central Asian Orogenic Belt (CAOB), is composed of over 30 mafic–ultramafic intrusions. These ore-bearing intrusions are composed mainly of harzburgite, lherzolite, websterite, orthopyroxenite, and norite (gabbro). The constituent minerals are olivine, diopside, bronzite, calcic-hornblende, plagioclase, and spinel with orthopyroxene as a dominant mineral in these intrusions. These ore-bearing intrusions are not Alaskan-type complexes. Spinel and clinopyroxene both exhibit different chemical compositions from those in the Alaskan-type complexes. The rocks that make up the intrusions have high contents of MgO (average value = 25.20 wt.%) and low TiO2 (average value = 0.58 wt.%). The high MgO contents of the minerals and the high Mg# (71) of the calculated melt in equilibrium with olivine demonstrate that the parental magma of the Hongqiling mafic–ultramafic intrusions was a high-Mg tholeiitic magma. The Hongqiling ore-bearing mafic–ultramafic intrusions and the calculated “trapped liquids” for the olivine-orthopyroxene cumulate rocks are all enriched in large-ion lithophile elements and depleted in high field strength elements. The Ce/Pb, Ta/La, Th/Yb, and (La/Sm)PM values and the depletion of Nb and Ta suggest that the magma experienced crustal contamination. The Hongqiling ore-bearing intrusions display many similarities with mafic–ultramafic intrusions that formed in a post-collisional extensional environment in the western CAOB (e.g., Huangshanxi). Common features include their whole-rock compositions and mineral chemistry. Combined with the evolutionary history of the eastern segment of the CAOB, we believe that the Late Triassic Hongqiling mafic–ultramafic intrusions formed in a post-collisional extensional environment.

Application of the Vineyard Geologic Identity Concept to Two Marquette-producing Vineyards in the Champlain Valley, Vermont, USA

2021 ◽  
Author(s):  
Jeffrey Munroe
Keyword(s):  
Major Element ◽  
Base Cations ◽  
Nutrient Status ◽  
Exchange Capacity ◽  
Laser Scattering ◽  
Physical Foundation ◽  
Geologic Setting ◽  
Marine Embayment ◽  
Future Work

<p>The concept of “Vineyard Geological Identity” (VGI) was introduced (Ferretti, 2019: <em>Catena</em>) in recognition of the role of geologic setting in contributing to fertility, hydrology, and other important aspects of vineyard soils.  This study applied the VGI concept to two vineyards in the Champlain Valley of Vermont, USA where a burgeoning wine-making industry has been catalyzed by the development of French-American hybrid grape variety capable of surviving cold winters and bringing fruit to ripeness in relatively cool summers.  The vineyards studied here, “LP” and “SV”, both produce the hybrid grape known as “Marquette”, are at a similar elevation (~100 m), have a similar macroclimate (MAT ~7 °C, MAP ~ 850 mm, ~1400 GDD), and were inundated by proglacial Lake Vermont during deglaciation (~15,000 years ago).  Notable differences between the sites are the lithology of the underlying bedrock (Ordovician carbonate at LP, and Cambrian quartzite at SV), and the fact that the SV site was located at the edge of a marine embayment at the Pleistocene/Holocene transition after Lake Vermont drained.  The hypothesis tested was the prediction that despite their broadly similar physical settings and geologic histories, the VGI of the two vineyards would vary as a result of differences in their underlying bedrock and the soil parent materials at these settings.  Samples were collected at depths of 25, 50, 75, and 100 cm from 10 locations within the Marquette block at in each vineyard.  All samples were evaluated for grain size distribution (with the hydrometer method and a laser scattering analyzer), thermogravimetric analysis (from 25 to 1000 °C), pH, nutrient status, base saturation, and cation exchange capacity.  The deepest samples were also analyzed for mineralogy (with XRD) and major element chemistry (with XRF).  Results confirm the tested hypothesis.  Most base cations are significantly more abundant in the samples from the LP site (reflecting the underlying carbonate bedrock), and the LP site is significantly finer grained (reflecting its former deepwater location in Lake Vermont).  Conversely, at the SV vineyard Na is significantly more abundant and samples are significantly coarser, consistent with the former location of this site in the nearshore zone of a marine embayment.  In future work these results could be used as a physical foundation for evaluating the possible role of terroir in controlling aspects of the flavors expressed in Marquette wines from these two vineyards.</p>

Production of SG Grade Pig Iron in Mini Blast Furnace

2013 ◽  
Vol 634-638 ◽  
pp. 3174-3180
Author(s):  
Madan Mohan Mahato ◽  
Mahesh Kumar Agrawal ◽  
Sharda Nand Sinha
Keyword(s):  
Blast Furnace ◽  
Metallurgical Coke ◽  
Chemical Compositions ◽  
Pig Iron ◽  
Hot Metal ◽  
Efficient Operation ◽  
Demand And Supply ◽  
Slag Chemistry ◽  
Capital Intensive

The entire life of a Blast furnace operator is spent to achieve the following aims: • To increase the productivity of Blast Furnace as high as possible. • To decrease the coke rate as low as possible to produce unit ton of hot metal. • To produce the hot metal of superior SG quality with particular reference to Sulphur & Silicon. • To keep the production cost as low as possible. The process indices of Mini Blast Furnace are similar to that of a conventional blast furnace. But, conventional blast furnace is capital intensive, solely dependent on good quality metallurgical coke, the gestation period is longer, and requires elaborate burden preparation. There is huge gap between demand and supply of steel in India. Also, India is dreaming to become developed nation by 2020. In such situations, the role of Mini Blast Furnace becomes very important. The slag chemistry is an important parameter to improve the process indices of MBF. The slag chemistry includes its chemical composition, liquidus temperature, fluidity, Sulphide capacity etc, which has an important bearing on the smooth & efficient operation of the MBF. The main important constituent of SG grade pig iron, particularly, Sulphur & silicon content should be 0.040% maximum and 1.20% to 2.20% maximum respectively. The chemical compositions of SG Grade Pig Iron is C- 3.80-4.20%, Mn – 0.35- 0.80%, Si – 1.20- 2.20%, S - 0.040% maximum and P – 0.15% maximum. The role of slag to produce such a low sulphur & low silicon in Mini Blast Furnace is very important. Therefore, to control Sulphur and silicon in SG Grade Pig Iron in Mini Blast Furnace, the optimisation of Slag Chemistry is an essential step.

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