Examination of the 2002 major warming in the southern hemisphere using ground-based and Odin/SMR assimilated data: stratospheric ozone distributions and tropic/mid-latitude exchange

2007 ◽  
Vol 85 (11) ◽  
pp. 1287-1300 ◽  
Author(s):  
H Bencherif ◽  
L El Amraoui ◽  
N Semane ◽  
S Massart ◽  
D Vidyaranya Charyulu ◽  
...  
Keyword(s):  
Nitrous Oxide ◽  
Southern Hemisphere ◽  
Transport Model ◽  
Stratospheric Ozone ◽  
Three Dimensional ◽  
Polar Vortex ◽  
Low Latitude ◽  
Height Range ◽  
Weather Forecasts ◽  
European Centre

Following an exceptionally active winter, the 2002 Southern Hemisphere (SH) major warming occurred in late September. It was preceded by three minor warming events that occurred in late August and early September, and yielded vortex split and break-down over Antarctica. Ozone (O3 and nitrous oxide (N2O) profiles obtained during that period of time (15 August – 4 October) by the Sub-Millimetre Radiometer (SMR) aboard the Odin satellite are assimilated into MOCAGE (Modélisation Isentrope du transport Mésoéchelle de l'Ozone Stratosphérique par Advection), a global three-dimensional chemistry transport model of Météo-France. The assimilated algorithm is a three-dimensional-FGAT built by the European Centre for Research and Advance Training in Scientific Computation (CERFACS) using the PALM (Projet d'Assimilation par Logiciel Multi-méthode) software. The assimilated O3 and N2O profiles and isentropic distributions are compared to ground-based measurements (LIDAR and balloon-sonde) and to maps of advected potential vorticity (APV). The latter is computed by the MIMOSA (Modélisation Isentrope du transport Mésoéchelle de l'Ozone Stratosphérique par Advection) model, a high-resolution advection transport model, using meteorological fields from the European Centre for Medium-Range Weather Forecasts (ECMWF). It is found that O3 concentrations retrieved by the MOCAGE–PALM assimilation system show a reasonably good agreement in the 20–28 km height range when compared with ground-based profiles. This altitude range corresponds to the intersection between the MOCAGE levels (0–28 km) and SMR O3 retrievals (20–50 km). Moreover, comparison of N2O assimilated fields with MIMOSA APV maps indicates that the dramatic split and subsequent break-down of the polar vortex, as well as the associated mixing of mid- and low-latitude stratospheric air, are well resolved and pictured by MOCAGE–PALM. The present study demonstrates also that the tremendous dynamics and associated polar vortex deformations during the 2002-austral-winter have modified ozone and nitrous oxide distributions not only at the vicinity of the polar vortex, but over topics and subtropics as well. PACS Nos.: 92.60.H–, 92.60.Hd, 92.70.Cp, 92.70.Gt

scholarly journals Analysis of a rapid increase of stratospheric ozone during late austral summer 2008 over Kerguelen (49.4° S, 70.3° E)

2010 ◽  
Vol 10 (7) ◽  
pp. 17727-17751
Author(s):  
H. Bencherif ◽  
L. El Amraoui ◽  
G. Kirgis ◽  
J. Leclair De Bellevue ◽  
A. Hauchecorne ◽  
...  
Keyword(s):  
Potential Vorticity ◽  
Large Scale ◽  
Lower Stratosphere ◽  
Transport Model ◽  
Stratospheric Ozone ◽  
Three Dimensional ◽  
Austral Summer ◽  
Air Masses ◽  
Weather Forecasts ◽  
Global Mapping

Abstract. This paper reports on an increase of ozone event observed over Kerguelen (49.4° S, 70.3° E) in relationship with large-scale isentropic transport. It is evidenced from ground-based observations, together with satellite global observations and assimilated fields. The study is based on the analyses of the first ozonesonde experiment never recorded at the Kerguelen site in the framework of a French campaign called ROCK that took place from April to August 2008. Comparisons and interpretations of the observed event are supported by co-localised SAOZ observations, by global mapping of tracers (O3, N2O and columns of O3) from Aura/MLS and Aura/OMI experiments, and by model simulations of Ertel Potential Vorticity initialised by ECMWF (European Centre for Medium-Range Weather Forecasts) data reanalyses. Satellite and ground-based observational data revealed a consistent increase of ozone in the local stratosphere by mid-April 2008. Additionally, Ozone (O3) and nitrous oxide (N2O) profiles obtained during January–May 2008 by the Microwave Lamb Sounder (MLS) aboard the Aura satellite are assimilated into MOCAGE (MOdèle de Chimie Atmosphérique à Grande Echelle), a global three-dimensional chemistry transport model of Météo-France. The assimilated total O3 values are consistent with SAOZ ground observations (within ±5%), and isentropic distributions of O3 are matching well with maps of advected potential vorticity (APV) derived from the MIMOSA model, a high-resolution advection transport model, and from ECMWF reanalysis. The studied event seems to be related to isentropic transport of air masses that took place simultaneously in the lower- and middle-stratosphere, respectively from the polar region and from tropics to the mid-latitudes. In fact, the studied ozone increase by mid April 2008 results simultaneously: (1) from an equator-ward departure of polar air masses characterised with a high-ozone layer in the lower stratosphere (nearby the 475 K isentropic level), and (2) from a reverse isentropic transport from tropics to mid- and high-latitudes in the upper stratosphere (nearby the 700 K level). The increase of ozone observed over Kerguelen from the 16-April ozonesonde profile is then attributed to a concomitant isentropic transport of ozone in two stratospheric layers: the tropical air moving southward and reaches over Kerguelen in the upper stratosphere, and the polar air passing over the same area but in the lower stratosphere.

scholarly journals An unusual stratospheric ozone decrease in the Southern Hemisphere subtropics linked to isentropic air-mass transport as observed over Irene (25.5° S, 28.1° E) in mid-May 2002

2006 ◽  
Vol 6 (7) ◽  
pp. 1927-1936 ◽  
Author(s):  
N. Semane ◽  
H. Bencherif ◽  
B. Morel ◽  
A. Hauchecorne ◽  
R. D. Diab
Keyword(s):  
Southern Hemisphere ◽  
Total Ozone ◽  
Stratospheric Ozone ◽  
Polar Vortex ◽  
Mean Value ◽  
Ozone Layer ◽  
Weather Forecasts ◽  
Unusual Distribution ◽  
Medium Range ◽  
Middle Stratosphere

Abstract. A prominent ozone minimum of less than 240 Dobson Units (DU) was observed over Irene (25.5° S, 28.1° E), a subtropical site in the Southern Hemisphere, by the Total Ozone Mapping Spectrometer (TOMS) during May 2002 with an extremely low ozone value of less than 219 DU recorded on 12 May, as compared to the climatological mean value of 249 DU for May between 1999 and 2005. In this study, the vertical structure of this ozone minimum is examined using ozonesonde measurements performed over Irene on 15 May 2002, when the total ozone (as given by TOMS) was about 226 DU. It is shown that this ozone minimum is of Antarctic polar origin with a low-ozone layer in the middle stratosphere above 625 K (where the climatological ozone gradient points equatorward), and is of tropical origin with a low-ozone layer in the lower stratosphere between the 400-K and 450-K isentropic levels (where the climatological ozone gradient is reversed). The upper and lower depleted parts of the ozonesonde profile for 15 May are then respectively attributed to equatorward and poleward transport of low-ozone air toward the subtropics in the Southern Hemisphere. The tropical air moving over Irene and the polar one passing over the same area associated with enhanced planetary-wave activity are successfully simulated using the high-resolution advection contour model of Ertel's potential vorticity MIMOSA. The unusual distribution of ozone over Irene during May 2002 in the middle stratosphere is connected to the anomalously pre-conditioned structure of the polar vortex at that time of the year. The winter stratospheric wave driving leading to the ozone minimum is investigated by means of the Eliassen-Palm flux computed from the European Center for Medium-range Weather Forecasts (ECMWF) ERA40 re-analyses.

scholarly journals Energetic particle induced intra-seasonal variability of ozone inside the Antarctic polar vortex observed in satellite data

2015 ◽  
Vol 15 (6) ◽  
pp. 3327-3338 ◽  
Author(s):  
T. Fytterer ◽  
M. G. Mlynczak ◽  
H. Nieder ◽  
K. Pérot ◽  
M. Sinnhuber ◽  
...  
Keyword(s):  
Geomagnetic Activity ◽  
Seasonal Variability ◽  
Transport Model ◽  
Three Dimensional ◽  
Polar Vortex ◽  
Quiet Time ◽  
Significance Level ◽  
Antarctic Polar Vortex ◽  
Ap Index ◽  
The Antarctic

Abstract. Measurements from 2002 to 2011 by three independent satellite instruments, namely MIPAS, SABER, and SMR on board the ENVISAT, TIMED, and Odin satellites are used to investigate the intra-seasonal variability of stratospheric and mesospheric O3 volume mixing ratio (vmr) inside the Antarctic polar vortex due to solar and geomagnetic activity. In this study, we individually analysed the relative O3 vmr variations between maximum and minimum conditions of a number of solar and geomagnetic indices (F10.7 cm solar radio flux, Ap index, ≥ 2 MeV electron flux). The indices are 26-day averages centred at 1 April, 1 May, and 1 June while O3 is based on 26-day running means from 1 April to 1 November at altitudes from 20 to 70 km. During solar quiet time from 2005 to 2010, the composite of all three instruments reveals an apparent negative O3 signal associated to the geomagnetic activity (Ap index) around 1 April, on average reaching amplitudes between −5 and −10% of the respective O3 background. The O3 response exceeds the significance level of 95% and propagates downwards throughout the polar winter from the stratopause down to ~ 25 km. These observed results are in good qualitative agreement with the O3 vmr pattern simulated with a three-dimensional chemistry-transport model, which includes particle impact ionisation.

Record springtime stratospheric ozone depletion at 80°N in 2020

2021 ◽  
Author(s):  
Ramina Alwarda ◽  
Kristof Bognar ◽  
Kimberly Strong ◽  
Martyn Chipperfield ◽  
Sandip Dhomse ◽  
...  
Keyword(s):  
Ozone Depletion ◽  
Transport Model ◽  
Stratospheric Ozone ◽  
Polar Vortex ◽  
The Arctic ◽  
Optical Absorption Spectroscopy ◽  
Chemical Transport Model ◽  
Polar Stratospheric Clouds ◽  
Ozone Loss ◽  
Stratospheric Clouds

<p>The Arctic winter of 2019-2020 was characterized by an unusually persistent polar vortex and temperatures in the lower stratosphere that were consistently below the threshold for the formation of polar stratospheric clouds (PSCs). These conditions led to ozone loss that is comparable to the Antarctic ozone hole. Ground-based measurements from a suite of instruments at the Polar Environment Atmospheric Research Laboratory (PEARL) in Eureka, Canada (80.05°N, 86.42°W) were used to investigate chemical ozone depletion. The vortex was located above Eureka longer than in any previous year in the 20-year dataset and lidar measurements provided evidence of polar stratospheric clouds (PSCs) above Eureka. Additionally, UV-visible zenith-sky Differential Optical Absorption Spectroscopy (DOAS) measurements showed record ozone loss in the 20-year dataset, evidence of denitrification along with the slowest increase of NO<sub>2</sub> during spring, as well as enhanced reactive halogen species (OClO and BrO). Complementary measurements of HCl and ClONO<sub>2</sub> (chlorine reservoir species) from a Fourier transform infrared (FTIR) spectrometer showed unusually low columns that were comparable to 2011, the previous year with significant chemical ozone depletion. Record low values of HNO<sub>3</sub> in the FTIR dataset are in accordance with the evidence of PSCs and a denitrified atmosphere. Estimates of chemical ozone loss were derived using passive ozone from the SLIMCAT offline chemical transport model to account for dynamical contributions to the stratospheric ozone budget.</p>

scholarly journals Analysis of a rapid increase of stratospheric ozone during late austral summer 2008 over Kerguelen (49.4° S, 70.3° E)

2011 ◽  
Vol 11 (1) ◽  
pp. 363-373 ◽  
Author(s):  
H. Bencherif ◽  
L. El Amraoui ◽  
G. Kirgis ◽  
J. Leclair De Bellevue ◽  
A. Hauchecorne ◽  
...  
Keyword(s):  
Potential Vorticity ◽  
Large Scale ◽  
Lower Stratosphere ◽  
Transport Model ◽  
Stratospheric Ozone ◽  
Three Dimensional ◽  
Austral Summer ◽  
Air Masses ◽  
Global Mapping ◽  
The Tropics

Abstract. This paper reports on an increase of ozone event observed over Kerguelen (49.4° S, 70.3° E) in relationship with large-scale isentropic transport. This is evidenced by ground-based observations (co-localised radiosonde and SAOZ experiments) together with satellite global observations (Aura/MLS) assimilated into MOCAGE, a Méteo-France model. The study is based on the analyses of the first ozonesonde experiment never recorded at the Kerguelen site within the framework of a French campaign called ROCK that took place from April to August 2008. Comparisons and interpretations of the observed event are supported by co-localised SAOZ observations, by global mapping of tracers (O3, N2O and columns of O3) from Aura/MLS and Aura/OMI experiments, and by model simulations of Ertel Potential Vorticity initialised by the ECMWF (European Centre for Medium-Range Weather Forecasts) data reanalyses. Satellite and ground-based observational data revealed a consistent increase of ozone in the local stratosphere by mid-April 2008. Additionally, Ozone (O3) and nitrous oxide (N2O) profiles obtained during January–May 2008 using the Microwave Limb Sounder (MLS) aboard the Aura satellite are assimilated into MOCAGE (MOdèle de Chimie Atmosphérique à Grande Echelle), a global three-dimensional chemistry transport model of Météo-France. The assimilated total O3 values are consistent with SAOZ ground observations (within ±5%), and isentropic distributions of O3 match well with maps of advected potential vorticity (APV) derived from the MIMOSA model, a high-resolution advection transport model, and from the ECMWF reanalysis. The event studied seems to be related to the isentropic transport of air masses that took place simultaneously in the lower- and middle-stratosphere, respectively from the polar region and from the tropics to the mid-latitudes. In fact, the ozone increase observed by mid April 2008 resulted simultaneously: (1) from an equator-ward departure of polar air masses characterised with a high-ozone layer in the lower stratosphere (near the 475 K isentropic level), and (2) from a reverse isentropic transport from the tropics to mid- and high-latitudes in the upper stratosphere (nearby the 700 K level). The increase of ozone observed over Kerguelen from the 16-April ozonesonde profile is thus attributed to a concomitant isentropic transport of ozone in two stratospheric layers: the tropical air moving southward and reaching over Kerguelen in the upper stratosphere, and the polar air passing over the same area but in the lower stratosphere.

scholarly journals The use of SMILES data to study ozone loss in the Arctic winter 2009/2010 and comparison with Odin/SMR data using assimilation techniques

2014 ◽  
Vol 14 (23) ◽  
pp. 12855-12869 ◽  
Author(s):  
K. Sagi ◽  
D. Murtagh ◽  
J. Urban ◽  
H. Sagawa ◽  
Y. Kasai
Keyword(s):  
Ozone Depletion ◽  
Transport Model ◽  
Space Station ◽  
Polar Vortex ◽  
The Arctic ◽  
Mixing Ratio ◽  
Weather Forecasts ◽  
Ozone Loss ◽  
Medium Range ◽  
Assimilation Model

Abstract. The Superconducting Submillimeter-Wave Limb-Emission Sounder (SMILES) on board the International Space Station observed ozone in the stratosphere with high precision from October 2009 to April 2010. Although SMILES measurements only cover latitudes from 38° S to 65° N, the combination of data assimilation methods and an isentropic advection model allows us to quantify the ozone depletion in the 2009/2010 Arctic polar winter by making use of the instability of the polar vortex in the northern hemisphere. Ozone data from both SMILES and Odin/SMR (Sub-Millimetre Radiometer) for the winter were assimilated into the Dynamical Isentropic Assimilation Model for OdiN Data (DIAMOND). DIAMOND is an off-line wind-driven transport model on isentropic surfaces. Wind data from the operational analyses of the European Centre for Medium- Range Weather Forecasts (ECMWF) were used to drive the model. In this study, particular attention is paid to the cross isentropic transport of the tracer in order to accurately assess the ozone loss. The assimilated SMILES ozone fields agree well with the limitation of noise induced variability within the SMR fields despite the limited latitude coverage of the SMILES observations. Ozone depletion has been derived by comparing the ozone field acquired by sequential assimilation with a passively transported ozone field initialized on 1 December 2009. Significant ozone loss was found in different periods and altitudes from using both SMILES and SMR data: The initial depletion occurred at the end of January below 550 K with an accumulated loss of 0.6–1.0 ppmv (approximately 20%) by 1 April. The ensuing loss started from the end of February between 575 K and 650 K. Our estimation shows that 0.8–1.3 ppmv (20–25 %) of O3 has been removed at the 600 K isentropic level by 1 April in volume mixing ratio (VMR).

scholarly journals Technical note: LIMS observations of lower stratospheric ozone in the southern polar springtime of 1978

2020 ◽  
Vol 20 (6) ◽  
pp. 3663-3668
Author(s):  
Ellis Remsberg ◽  
V. Lynn Harvey ◽  
Arlin Krueger ◽  
Larry Gordley ◽  
John C. Gille ◽  
...  
Keyword(s):  
Nitric Acid ◽  
Nitrogen Dioxide ◽  
Southern Hemisphere ◽  
Polar Region ◽  
Lower Stratosphere ◽  
Stratospheric Ozone ◽  
Polar Vortex ◽  
Technical Note ◽  
Stratospheric Ozone Layer ◽  
Antarctic Ozone

Abstract. The Nimbus 7 Limb Infrared Monitor of the Stratosphere (LIMS) instrument operated from 25 October 1978 through 28 May 1979. This note focuses on its Version 6 (V6) data and indications of ozone loss in the lower stratosphere of the Southern Hemisphere subpolar region during the last week of October 1978. We provide profiles and maps that show V6 ozone values of only 2 to 3 ppmv at 46 hPa within the edge of the polar vortex near 60∘ S from late October through mid-November 1978. There are also low values of V6 nitric acid (∼3 to 6 ppbv) and nitrogen dioxide (< 1 ppbv) at the same locations, indicating that conditions were suitable for a chemical loss of Antarctic ozone some weeks earlier. These “first light” LIMS observations provide the earliest space-based view of conditions within the lower stratospheric ozone layer of the southern polar region in springtime.

scholarly journals Observations of filamentary structures near the vortex edge in the Arctic winter lower stratosphere

2013 ◽  
Vol 13 (21) ◽  
pp. 10859-10871 ◽  
Author(s):  
C. Kalicinsky ◽  
J.-U. Grooß ◽  
G. Günther ◽  
J. Ungermann ◽  
J. Blank ◽  
...  
Keyword(s):  
Cross Sections ◽  
Transport Model ◽  
Stratospheric Ozone ◽  
Polar Vortex ◽  
Lagrangian Model ◽  
The Arctic ◽  
Small Scale ◽  
Air Mass ◽  
Mixing Ratios ◽  
Passive Tracers

Abstract. The CRISTA-NF (Cryogenic Infrared Spectrometers and Telescope for the Atmosphere – New Frontiers) instrument is an airborne infrared limb sounder operated aboard the Russian research aircraft M55-Geophysica. The instrument successfully participated in a large Arctic aircraft campaign within the RECONCILE (Reconciliation of essential process parameters for an enhanced predictability of Arctic stratospheric ozone loss and its climate interactions) project in Kiruna (Sweden) from January to March 2010. This paper concentrates on the measurements taken during one flight of the campaign, which took place on 2 March in the vicinity of the polar vortex. We present two-dimensional cross-sections of derived volume mixing ratios for the trace gases CFC-11, O3, and ClONO2 with an unprecedented vertical resolution of about 500 to 600 m for a large part of the observed altitude range (≈ 6–19 km) and a dense horizontal sampling along flight direction of ≈ 15 km. The trace gas distributions show several structures, for example a part of the polar vortex and a vortex filament, which can be identified by means of O3–CFC-11 tracer–tracer correlations. The observations made during this flight are interpreted using the chemistry and transport model CLaMS (Chemical Lagrangian Model of the Stratosphere). Comparisons of the observations with the model results are used to assess the performance of the model with respect to advection, mixing, and the chemistry in the polar vortex. These comparisons confirm the capability of CLaMS to reproduce even very small-scale structures in the atmosphere, which partly have a vertical extent of only 1 km. Based on the good agreement between simulation and observation, we use artificial (passive) tracers, which represent different air mass origins (e.g. vortex, tropics), to further analyse the CRISTA-NF observations in terms of the composition of air mass origins. These passive tracers clearly illustrate the observation of filamentary structures that include tropical air masses. A characteristic of the Arctic winter 2009/10 was a sudden stratospheric warming in December that led to a split of the polar vortex. The vortex re-established at the end of December. Our passive tracer simulations suggest that large parts of the re-established vortex consisted to about 45% of high- and mid-latitude air.

A three-dimensional model comparison of PSC processing during the Arctic winters of 1991/1992 and 1992/1993

1994 ◽  
Vol 12 (4) ◽  
pp. 342-354 ◽  
Author(s):  
M. P. Chipperfield
Keyword(s):  
Model Comparison ◽  
Transport Model ◽  
Three Dimensional ◽  
Polar Vortex ◽  
The Arctic ◽  
Three Dimensional Model ◽  
Polar Stratospheric Clouds ◽  
Ozone Loss ◽  
Stratospheric Clouds ◽  
Compare And Contrast

Abstract. A three-dimensional transport model has been used to compare and contrast the extent of processing by polar stratospheric clouds during the northern hemisphere winters of 1991/1992 and 1992/1993. The model has also been used to compare the potential for ozone loss between these two winters. The TOMCAT off-line model is forced using meteorological analyses from the ECMWF. During winter 1992/1993 polar stratospheric clouds (PSCs) in the model persisted into late February/early March, which is much later than in 1991/1992. This persistence of PSCs should have resulted in much more ozone loss in the later winter. Interestingly, however, the extent of PSC processing and ozone loss was greater in January 1992 than January 1993. In January 1992 PSCs occurred at the edge of a distorted polar vortex whilst in January 1993 the PSCs were located at the centre of a much more zonally symmetrical vortex. In March 1993, distortions of the vortex led to the tearing off of vortex air and its mixing into midlatitudes.

scholarly journals Satellite observations of stratospheric hydrogen fluoride and comparisons with SLIMCAT calculations

2015 ◽  
Vol 15 (23) ◽  
pp. 34361-34405 ◽  
Author(s):  
J. J. Harrison ◽  
M. P. Chipperfield ◽  
C. D. Boone ◽  
S. S. Dhomse ◽  
P. F. Bernath ◽  
...  
Keyword(s):  
Atmospheric Chemistry ◽  
Transport Model ◽  
Stratospheric Ozone ◽  
Three Dimensional ◽  
Montreal Protocol ◽  
Chemical Transport Model ◽  
Slowing Down ◽  
Rate Of Increase ◽  
Stratospheric Dynamics ◽  
Chemistry Experiment

Abstract. The vast majority of emissions of fluorine-containing molecules are anthropogenic in nature, e.g. chlorofluorocarbons (CFCs), hydrochlorofluorocarbons (HCFCs), and hydrofluorocarbons (HFCs). Many of these fluorine-containing species deplete stratospheric ozone, and are regulated by the Montreal Protocol. Once in the atmosphere they slowly degrade, ultimately leading to the formation of HF, the dominant reservoir of stratospheric fluorine due to its extreme stability. Monitoring the growth of stratospheric HF is therefore an important marker for the success of the Montreal Protocol. We report the comparison of global distributions and trends of HF measured in the Earth's atmosphere by the satellite remote-sensing instruments ACE-FTS (Atmospheric Chemistry Experiment Fourier Transform Spectrometer), which has been recording atmospheric spectra since 2004, and HALOE (HALogen Occultation Experiment), which recorded atmospheric spectra between 1991 and 2005, with the output of SLIMCAT, a state-of-the-art three-dimensional chemical transport model. In general the agreement between observation and model is good, although the ACE-FTS measurements are biased high by ∼ 10 % relative to HALOE. The observed global HF trends reveal a substantial slowing down in the rate of increase of HF since the 1990s: 4.97 ± 0.12 % year-1 (1991–1997; HALOE), 1.12 ± 0.08 % year-1 (1998–2005; HALOE), and 0.52 ± 0.03 % year-1 (2004–2012; ACE-FTS). In comparison, SLIMCAT calculates trends of 4.01, 1.10, and 0.48 % year-1, respectively, for the same periods; the agreement is very good for all but the earlier of the two HALOE periods. Furthermore, the observations reveal variations in the HF trends with latitude and altitude, for example between 2004 and 2012 HF actually decreased in the Southern Hemisphere below ∼ 35 km. SLIMCAT calculations broadly agree with these observations, most notably between 2004 and 2012. Such variations are attributed to variability in stratospheric dynamics over the observation period.

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