A THEORETICAL EVALUATION OF THE NITROGEN ISOTOPE EFFECT IN THE THERMAL DEAMMONATION OF PHTHALAMIDE

1952 ◽  
Vol 30 (5) ◽  
pp. 443-447 ◽  
Author(s):  
Jacob Bigeleisen
Keyword(s):  
Theoretical Analysis ◽  
Isotope Effect ◽  
Nitrogen Isotope ◽  
Isotopic Substitution ◽  
Theoretical Evaluation ◽  
Theory And Experiment ◽  
Good Agreement

A theoretical analysis is made of the effect of nitrogen isotopic substitution on the rate of deammonation of phthalamide. Good agreement is found between theory and experiment.

Experimental Investigation of Gas-Particle Flow Trajectories and Velocities in an Axial Flow Turbine Stage

1972 ◽  
Author(s):  
W. Tabakoff ◽  
A. Hamed ◽  
M. F. Hussein
Keyword(s):  
Experimental Investigation ◽  
Theoretical Analysis ◽  
Pressure Distribution ◽  
High Speed ◽  
Axial Flow ◽  
Particle Flow ◽  
Blade Surface ◽  
Turbine Stage ◽  
Theory And Experiment ◽  
Good Agreement

This paper describes the results from an investigation of the gas-particle flow trajectories, velocities and pressure distribution in an axial flow turbine stage. A gas-particle flow cascade tunnel and high-speed photographic techniques were used to conduct the experimental investigation. The pressure distribution on the blade surface was measured and compared with the theoretical analysis, the results exhibiting good agreement between the developed theory and experiment.

PHOTOINDUCED NONLINEAR OCTUPOLAR POLARIZATION: TRANSIENT AND PERMANENT REGIMES

1996 ◽  
Vol 05 (04) ◽  
pp. 653-670 ◽  
Author(s):  
CÉLINE FIORINI ◽  
JEAN-MICHEL NUNZI ◽  
FABRICE CHARRA ◽  
IFOR D.W. SAMUEL ◽  
JOSEPH ZYSS
Keyword(s):  
Theoretical Analysis ◽  
Second Harmonic ◽  
Experimental Results ◽  
Polar Field ◽  
Rotational Spectrum ◽  
Dual Frequency ◽  
One Dimensional ◽  
Ethyl Violet ◽  
Disperse Red 1 ◽  
Good Agreement

An original poling method using purely optical means and based on a dual-frequency interference process is presented. We show that the coherent superposition of two beams at fundamental and second-harmonic frequencies results in a polar field with an irreducible rotational spectrum containing both a vector and an octupolar component. This enables the method to be applied even to molecules without a permanent dipole such as octupolar molecules. After a theoretical analysis of the process, we describe different experiments aiming at light-induced noncentrosymmetry performed respectively on one-dimensional Disperse Red 1 and octupolar Ethyl Violet molecules. Macroscopic octupolar patterning of the induced order is demonstrated in both transient and permanent regimes. Experimental results show good agreement with theory.

scholarly journals Nitrogen isotope effects can be used to diagnose N transformations in wastewater anammox systems

2021 ◽  
Vol 11 (1) ◽  
Author(s):  
Paul M. Magyar ◽  
Damian Hausherr ◽  
Robert Niederdorfer ◽  
Nicolas Stöcklin ◽  
Jing Wei ◽  
...  
Keyword(s):  
Isotope Effect ◽  
Isotope Composition ◽  
Isotope Effects ◽  
Nitrogen Isotope ◽  
Anammox Bacteria ◽  
Ammonium Oxidation ◽  
Experimental Conditions ◽  
N Transformations ◽  
Natural Systems ◽  
Inverse Isotope Effect

AbstractAnaerobic ammonium oxidation (anammox) plays an important role in aquatic systems as a sink of bioavailable nitrogen (N), and in engineered processes by removing ammonium from wastewater. The isotope effects anammox imparts in the N isotope signatures (15N/14N) of ammonium, nitrite, and nitrate can be used to estimate its role in environmental settings, to describe physiological and ecological variations in the anammox process, and possibly to optimize anammox-based wastewater treatment. We measured the stable N-isotope composition of ammonium, nitrite, and nitrate in wastewater cultivations of anammox bacteria. We find that the N isotope enrichment factor 15ε for the reduction of nitrite to N2 is consistent across all experimental conditions (13.5‰ ± 3.7‰), suggesting it reflects the composition of the anammox bacteria community. Values of 15ε for the oxidation of nitrite to nitrate (inverse isotope effect, − 16 to − 43‰) and for the reduction of ammonium to N2 (normal isotope effect, 19–32‰) are more variable, and likely controlled by experimental conditions. We argue that the variations in the isotope effects can be tied to the metabolism and physiology of anammox bacteria, and that the broad range of isotope effects observed for anammox introduces complications for analyzing N-isotope mass balances in natural systems.

Flow Characteristics of a Powder Lubricant in a Slider Bearing

2001 ◽  
Author(s):  
Manjunath Pappur ◽  
M. M. Khonsari
Keyword(s):  
Slip Velocity ◽  
Thrust Bearing ◽  
Volume Fraction ◽  
Flow Characteristics ◽  
Slider Bearing ◽  
Systematic Development ◽  
Powder Lubrication ◽  
Insight Into ◽  
Theory And Experiment ◽  
Good Agreement

Abstract This paper deals with a systematic development of theory of powder lubrication with the appropriate formalism based on the fundamentals of fluid mechanics. The theory is capable of predicting flow velocity, fluctuation (pseudo-temperature), powder volume fraction, and slip velocity at the boundaries. An extensive set of parametric simulations covering particle size, surface roughness, volumetric flow, load and speed are performed to gain insight into the performance of a powder lubricated thrust bearing. The results of simulations are compared to the published experimental results. Good agreement between the theory and experiment attests to the capability of the model and its potential for design of powder lubricated bearings.

Morphology of Voltage-Triggered Ordered Wrinkles of a Dielectric Elastomer Sheet

2017 ◽  
Vol 84 (11) ◽  
Author(s):  
Guoyong Mao ◽  
Lei Wu ◽  
Xueya Liang ◽  
Shaoxing Qu
Keyword(s):  
High Voltage ◽  
Optical Sensor ◽  
Material Science ◽  
Dielectric Elastomer ◽  
Theoretical Studies ◽  
Science And Engineering ◽  
Future Design ◽  
Experimental And Theoretical Studies ◽  
Theory And Experiment ◽  
Good Agreement

Wrinkles widely existing in sheets and membranes have attracted a lot of attention in the fields of material science and engineering applications. In this paper, we present a new method to generate ordered (striplike) and steady wrinkles of a constrained dielectric elastomer (DE) sheet coated with soft electrodes on both sides subjected to high voltage. When the voltage reaches a certain value, wrinkles will nucleate and grow. We conduct both experimental and theoretical studies to investigate the wavelength and amplitude of the wrinkle. The results show a good agreement between theory and experiment. Moreover, the amplitude and wavelength of ordered wrinkles can be tuned by varying the prestretch and geometry of the DE sheet, as well as the applying voltage. This study can help future design of DE transducers such as diffraction grating and optical sensor.

Vibration Analysis for Piezoceramic Circular Plates with V-Notches. Part 1: Theory

2014 ◽  
Vol 30 (6) ◽  
pp. 603-609 ◽  
Author(s):  
C.-H. Huang ◽  
Y.-Y. Chen
Keyword(s):  
Theoretical Analysis ◽  
Transverse Vibration ◽  
Stress Singularity ◽  
Trigonometric Polynomials ◽  
Circular Plates ◽  
The Finite Element Method ◽  
Electrical Field ◽  
Ritz’S Method ◽  
Frequency Variations ◽  
Good Agreement

AbstractIn this paper the transverse vibration characteristics of piezoceramic circular plates with V-notches are investigated theoretically through use of the Ritz's method incorporated with the defined equivalent constants. The Ritz's method is employed with two sets of admissible displacement functions, algebraic-trigonometric polynomials and corner functions, to guarantee convergence sufficiently and represent the stress singularity, respectively. Moreover, the equivalent constants derived by comparing the characteristic equations of transverse vibration between isotropic and piezoceramic disks are applied to suspend the electrical field consideration regarding the piezoelectricity. With the aid of theoretical analysis, the non-dimensional frequency parameters of transverse vibration modes for completely free V-notching circular plates are exhibited; in addition, the frequency variations depending on various notch angles and depths are explored. Numerical calculations using the finite element method (FEM) are performed and the results are compared with the theoretical analysis. It is shown that the resonant frequencies predicted by theoretical analysis and calculated by FEM are in good agreement.

Vibrational characteristics of an earth dam

1966 ◽  
Vol 56 (6) ◽  
pp. 1207-1226
Author(s):  
W. O. Keightley
Keyword(s):  
Theoretical Analysis ◽  
Natural Frequencies ◽  
Forced Vibrations ◽  
Earth Dam ◽  
Mode Shapes ◽  
Modal Damping ◽  
Vibrational Characteristics ◽  
Good Agreement ◽  
Lower Frequencies

Abstract An earth dam was excited into vibrations, in the upstream-downstream direction, by four rotating eccentric-mass vibration generators which were operated on the crest. Natural frequencies, mode shapes, and equivalent viscous modal damping constants of the dam were revealed by the forced vibrations. A theoretical analysis of the dam, based on consideration of shearing deformations only, shows moderately good agreement with the behavior which was observed at the lower frequencies.

On an Approximate Method of Calculating Pressures on Non-lifting Head Shapes at Supersonic Speeds

1955 ◽  
Vol 6 (1) ◽  
pp. 31-45
Author(s):  
H. K. Zienkiewicz
Keyword(s):  
Method Of Characteristics ◽  
Order Theory ◽  
Stagnation Pressure ◽  
Slender Body Theory ◽  
Pressure Losses ◽  
The Method Of Characteristics ◽  
Curvature Approximation ◽  
Body Theory ◽  
Theory And Experiment ◽  
Good Agreement

SummarySlender-body theory is used to derive the ogive of curvature approximation for very slender, pointed, convex head shapes at supersonic speeds. Results of application of this approximation, together with the λ-method for circular arc ogives, to a variety of non-slender head shapes show very good agreement with the method of characteristics, van Dyke's second-order theory and experiment. Good agreement with the method of characteristics and with experiment is obtained even in cases when the stagnation pressure losses across the nose shock wave are not negligible.

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