THE FORMATION OF THIN FILMS OF IRON OXIDE
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It is assumed that the free energy of a thin film of iron oxide is a function of its thickness. The effect on the dissociation pressure is calculated and the condition for stability of thickness is stated. A possible method for measuring the free energy change involved in oxide film formation on metal surfaces is presented which is based on measurements of the e.m.f. of the dry cell metal | oxide | oxygen.
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2015 ◽
Vol 25
(17)
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pp. 2564-2572
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2013 ◽
Vol 8
(9)
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pp. 2064-2069
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2017 ◽
Vol 5
(2)
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pp. 252-263
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