THE THEORY OF ULTRASONIC ABSORPTION: RELAXATION OF TWO INTERACTING REACTIONS

1964 ◽  
Vol 42 (5) ◽  
pp. 1174-1185 ◽  
Author(s):  
J. P. Valleau

The purpose of this paper is to extend the theory of ultrasonic absorption in fluids to the case of the relaxations of two interacting reactions. The linear theory of the absorption and dispersion of sound waves is developed in terms of a frequency-dependent viscosity coefficient. This coefficient is then evaluated for the familiar case of a single relaxing reaction and for the more complex case of two reactions interacting in an arbitrary way. The absorption and dispersion of the sound waves are related to familiar physical chemical quantities by explicit formulae, and non-ideality has been taken account of by the use of activity coefficients. Some discussion of the results is presented. The intention of this development is to make possible the extraction of physical chemical data from ultrasonic investigations of systems involving interacting equilibria, and such an application has been made in an accompanying paper.

Proceedings ◽  
2021 ◽  
Vol 52 (1) ◽  
pp. 2
Author(s):  
Noé Anes García ◽  
Antonio Luis Marqués Sierra

In recent years, developments made to reduce the consequences generated using petroleum products have been strengthening; therefore, biofuels have become a requirement in different countries worldwide with the objective of reducing not only the high levels of current pollution, but also mitigating the effects generated by global warming. Despite the advances that have been made in the field of research on Jatropha, it is still necessary to carry out more detailed studies aimed at achieving a better use of it, identifying the influence of its physical–chemical properties in terms of quality levels, as well as determining its behavior when mixed with palm oil to achieve a biodiesel with better yields, whose impact will be reflected mainly in the environmental field, helping to mitigate the production of greenhouse gases that are produced by petroleum products. Although currently the biofuels sector has made important advances in research, it is necessary to deepen the physical–chemical analyses both in the production and storage processes of biodiesel, so that in the future it can be fully fulfilled with the energy requirements that are currently only achieved with fossil fuels, so it is necessary to direct this research toward the development of new products with improved characteristics, especially when exposed to prolonged storage times and low temperatures.


2016 ◽  
Vol 869 ◽  
pp. 112-115 ◽  
Author(s):  
Francisca Pereira de Araújo ◽  
Edson Cavalcanti Silva Filho ◽  
João Sammy Nery de Souza ◽  
Josy Anteveli Osajima ◽  
Marcelo Barbosa Furtini

Soil-cement bricks are good examples of environmentally friendly products. This brick is the combination of soil with compacted cement with no combustion in its production. In this work the physical chemical characteristics of the soil from Piaui for producing this material were investigated. Samples of the soil were collected in three potteries from the county of Bom Jesus and pH analysis were carried out, as well as the rate of organic matter, texture, particle density, limits of liquidity and plasticity rates. The results have shown that the soils have acid tones (pH 5,49 a 6,11), which can be neutralized by adding cement, and organic matter percentages up to 1%. The samples have shown predominantly clay-rich textures with adequate plasticity limits, however, values of liquidity limits and particle density above recommended. Altogether, these soils tend to present viability concerning soil-cement brick production, provided that corrections with additives are made in order to minimize this effect.


1977 ◽  
Vol 32 (1) ◽  
pp. 57-60 ◽  
Author(s):  
H. E. Gunilla Knape ◽  
Lena M. Torell

Abstract Brillouin spectra of molten CSNO3 were investigated for scattering angles between 40 and 140° and in a temperature interval of 420-520 °C. An Ar+ singlemode laser was used for excitation and the total instrumental width was ~265 MHz. The measured frequency shifts and linewidths of the Brillouin components were used to determine velocities and attenuations of thermal sound waves in the frequency range 2.3-7.0 GHz. A dispersion of 4-5% was found between the present hyper­ sonic velocities and reported ultrasonic velocities. A considerable decrease in attenuation with frequency was observed in the investigated frequency range, with the value at high frequency ap­ proaching the classical attenuation. The results are in good agreement with Mountain's theory of a single relaxation time. The relaxation time of the bulk viscosity coefficient was calculated to 1.2×10-10S.


Author(s):  
M. I. Podolsky ◽  
◽  
I. Y. Lilevman ◽  
O. Y. Lilevman ◽  
O. Y. Kedrovsky ◽  
...  

Noise background, as an important factor in the working conditions of agricultural operators, has a direct impact on human health and productivity. This topic is especially relevant for small tractors, which in most cases are not equipped with cabs. One of the main means of reducing the sound pressure on the operator are the mufflers of exhaust gases, which mainly have a labyrinth-absorbing type of action. The paper proposes a fundamental approach to the design of the muffler by the criterion of reflection and scattering of sound waves with the verification of efficiency by computer simulation. The purpose of research: - to improve the working conditions of operators of small tractors that are not equipped with cabs, by reducing the sound pressure level from internal combustion engines; - to improve the noise-absorbing properties of mufflers of exhaust gases of engines with observance of requirements to manufacturability of process of their manufacturing; - to develop a structural scheme of the exhaust gases muffler based on the results of preliminary modeling and analysis of the trajectory of the gas flow in the cavity of its working part. Methods. Determination of the sound pressure level of the engine of a small tractor by mathematical (computer) modeling of the behavior of the exhaust gas flow in the muffler cavity in different frequency ranges. Results. The article analyzes the main sources of noise during the operation of agricultural machinery with internal combustion engines (ICE). On the basis of literature sources and methods, their separate degree of influence on the complex picture of noise pollution of the working space of the operator of a small tractor is established. A comparative analysis of the efficiency of mufflers, created on the generally accepted principles and approaches to the design of such devices. According to the results of previous tests, shortcomings and limitations in the application of design concepts were identified, an additional analysis of external causes and factors was made, and adjustments were made to the method of creating muffler designs. An alternative design approach to the creation of internal combustion engine mufflers of small tractors is proposed and computer modeling of the processes of sound pressure distribution and sound waves in their cavity is performed. Conclusions. 1. A layout diagram of the design of the exhaust muffler, containing a resonator chamber and a shell module, which is made in the form of a three-stage ribbed diffuser of oscillations of the exhaust flow pulses with an additional surface layer of the vibration absorber. The parameters of the exhaust flow of exhaust gases of a typical diesel engine of a small tractor with a capacity of 24 hp are calculated. (pressure - 11652 Pa, acceleration – 90-105 m / s2, frequency - 1950-3300 Hz), which performed computer simulations of the process of gas movement in the muffler cavity of the proposed layout. Optimal design parameters were selected to ensure the maximum possible noise absorption with a body diameter of 150 mm and a length of 600 mm. The calculated sound pressure when working at the crankshaft speed (1700-2000) rpm does not exceed 72 dB. At the same time, the design of the muffler is made in compliance with the requirements for economic feasibility, manufacturability and in accordance with the capabilities of industrial production. A further direction of research is the manufacture of an experimental sample of the muffler and testing for the efficiency of its noise absorption in the conditions of operation of small tractors.


2016 ◽  
Vol 721 ◽  
pp. 154-158
Author(s):  
Edmunds Lodins ◽  
Inga Pudze ◽  
Ineta Rozenstrauha ◽  
Linda Krage

This work focuses on pellets made by Latvian industrial waste (waste cullet glass, sewage sludge, metallurgical slag and alumina scrap metal processing waste and raw mineral materials (limeless clay) to gain high porosity and water sorptiom. Iron sorption using ceramic pellets is explored more detailed. Physical-chemical properties and microstructure were researched to obtain a deeper understanding of how these qualities affect water purification from iron compounds. Three pellets with different properties were made in this paper : B5, A5 and E1. Composition B5 indicates highest iron sorption rate at sintering temperature 1100 °C and shows considerable iron reduction in a solution after one week.


Author(s):  
Iuri Mikelashvili ◽  
Vano Shiukashvili ◽  
Nino Vephkhishvili

Viticulture - winemaking is one of the oldest activities of mankind, which dates back centuries. In Georgia there are such grape varieties and such traditional methods of winemaking that are not found in other countries. For example, Saperavi grape and production of Qvevri (pitcher) wine. Saperavi is an ancient Georgian grape variety on which Georgian winemaking is based today.We have established experimentally the possibility of making high quality rose wine with various characteristics from Saperavi grown in Kakheti region using different wine vessels, such as stainless steel reservoir, oak barrel, traditional Georgian Qvevri (pitcher), under production conditions. The physical, chemical and organoleptic properties of various wines that provide the individuality of the wine have been determined.The main quantities characteristic to rose wine differ from one another, which is obviously due to the vessel in which the wine was made. For example, the wine, fermented and aged in the barrel has the most density because the tannins from the oak barrel increase it; the rose wine, made in the reservoir, has the lowest extract; in the case of Qvevri (pitcher) wine, the mass of dry matter is increased at the expense of the constituent substances of the clay of the pitcher; the wine made in the pitcher has the lowest titratable acidity because the wine acids go into the reaction with the mineral substances of the pitcher clay and the overall acidity decreases; the barrel and Qvevri rose wine has slightly higher volatile acidity. Here the reason for that should also be found in the porosity of the barrel and the pitcher.The various wines produced differ from one another organoleptically as well, which shows the role of the vessel in forming the taste properties of the wine. The different vessels used change all the components of the sensorics.All three wines are interesting in their own way, but the rose Qvevri wine is special for the taste of the traditional Georgian pitcher is best combined with the rose wine made with European technology and gentle processing.


2018 ◽  
Vol 15 (2) ◽  
pp. 41
Author(s):  
Elya Zulfa ◽  
Mufrod Mufrod

ABSTRACTIn previous research, ethanolic extract of pineapple peel (EEPP) has activity as a sunscreen because of the content of flavonoids. EEPP can be formulated in the form of creams and lotions to facilitate use on the skin. This study aims to evaluate the physical chemistry characteristics of EEPP creams and lotions. Creams and lotions were made in 3 formulas based on variations in FI extract concentrations (15.0%), FII (17.5%), FIII (20.0%), base controls and positive controls (preparations on the market). The cream obtained was evaluated for physical chemical characteristics including organoleptic, homogeneity, adhesion and dispersion, viscosity, pH and SPF values which were analyzed descriptively. cream with varying concentrations of green, the distinctive smell of pineapple, homogeneous and in accordance with the pH of the skin. Increasing the concentration of EEPP in the preparation has an effect on increasing viscosity, adhesion but decreasing the dispersion. Whereas the lotion shows greenish color, aromatic odor and semisolid texture and is easily applied. The increase in EEPP in lotion affects the increase in pH, adhesion, but decreasing the dispersion.Keywords: Creams, lotions, sunscreen, pineapple fruit skin


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