Sulfate retention and cation leaching of forest soils in response to acid additions

1991 ◽  
Vol 21 (1) ◽  
pp. 32-41 ◽  
Author(s):  
William J. Fasth ◽  
Mark B. David ◽  
George F. Vance

A vacuum extractor was used to examine the effects of increased SO42− deposition on net S retention and cation leaching in three Maine Spodosols (Berkshire, Dixfield, and Rawsonville series) and an Illinois Alfisol. Columns (leached daily for 30 days with either a simulated throughfall solution containing 80 μequiv. SO42−•L−1 (pH = 4.77) or a simulated throughfall solution plus 200 μequiv. H2SO4•L−1 (pH = 3.66)) were constructed using O horizons over upper B (Bh or Bhs) and lower B (Bhs or BC) horizons for the Spodosols and two depth increments of bulked soil (0–12 and 12–25 cm) for the Alfisol. Leachate concentrations of base cations were dominated by Ca2+ and were generally greater in the Alfisol than in the Spodosol leachates. Declining concentrations of base cations and NH4+ with time led to an increase in Al3+ concentrations and a decrease in pH for some of the Spodosol leachates (e.g., leachate Al3+ increased from 19 μequiv. Al3+ •L−1 (day 2) to 194 μtequiv. Al3+ •L−1 (day 30), and pH decreased from 5.53 to 4.41, respectively, for the Dixfield high-S treatment). Columns that received the high-S treatment retained a greater percentage of the added S than those that received the low-S treatment because of increased SO42− adsorption in the former. High rates of net organic S mineralization were found for all soil types (e.g., 169 μg organic S•g−1 over 30 days for the Rawsonville Bhl horizon, 15% of the total S); no treatment effects were found for the amount of S mineralized. Trends in net S retention across soil type (within the same treatment) reflected increases in soil SO42− from adsorption, as well as decreases in organic S from mineralization. When net S mineralization was removed from leaching losses of S, trends in net S retention closely reflected SO42− adsorption differences (50, 23, 8, and 1% of the added S retained by the Rawsonville, Dixfield, and Berkshire series, and the Alfisol, respectively, for the high-S treatment). Because of the low SO42− adsorption capacity of the Alfisol relative to the Spodosols, organic processes were more important in affecting net S retention for the Alfisol. Inorganic processes of S retention were more important for the three Spodosols studied.

2021 ◽  
Vol 2021 ◽  
pp. 1-7
Author(s):  
Jianhong Liang ◽  
Liuhuan Chen ◽  
Ding Liu ◽  
Chenxu Yi ◽  
Jing Zhu

Phosphorus (P) is one of the key limiting factors for the growth of forests and their net primary productivity in subtropical forest ecosystems. Phosphorus leaching of the forest soil to the catchment and groundwater in karst region is the main source of water eutrophication. Strong P sorption capacity of minerals is generally assumed to be a key driver of P leaching in subtropical ecosystems which varies among different soil types. Here, we estimated P adsorption capacity of the O/A and AB horizon in both limestone soil and red soil of subtropical forests by fitting the Langmuir and Freundlich isotherm to investigate the potential environmental risks of P. The maximum P sorption capacity ( Q m ), P sorption constant ( K L ), P sorption index (PSI), degree of P saturation (DPS), and maximum buffer capacity (MBC) were calculated. The results indicate that Q m of the O/A horizon in both soils were similar. Comparing these two soils, the red soil had a higher K L and MBC in the AB horizon; Q m of limestone soil was larger but K L was lower, indicating that the adsorption capacity of limestone soil was weaker and MBC was lower. There was no significant difference in PSI between the two soils. The DPS values of both soils were below 1.1%, indicating that P saturation is low in both subtropical forest soils due to the lack of marked anthropogenic disturbance. In the O/A horizon, P saturation associated with available P (DPSM3 and DPSOlsen) and that associated with P in the Fe-Al bound state (DPScitrate) were higher in the red soil than in the limestone soil. DPS did not differ significantly in the AB horizon, except for higher DPSM3 and DPScitrate in the red soil. The findings highlight the influence of the soil types on P adsorption. The P adsorption and buffering of red soils were higher than those of limestone soils, indicating a lower risk of P leaching in red subtropical forest soils.


2014 ◽  
Vol 94 (5) ◽  
pp. 621-634 ◽  
Author(s):  
Stephanie Pugliese ◽  
Trevor Jones ◽  
Michael D. Preston ◽  
Paul Hazlett ◽  
Honghi Tran ◽  
...  

Pugliese, S., Jones, T., Preston, M. D., Hazlett, P., Tran, H. and Basiliko, N. 2014. Wood ash as a forest soil amendment: The role of boiler and soil type on soil property response. Can. J. Soil Sci. 94: 621–634. Wood ash is produced in large quantities in Canada as a by-product of the pulp and paper, sawmill, and bioenergy industries and it is anticipated that its disposal in landfills will not be a viable option. An alternative option may be to use it to amend forest soils. Wood ash is a complex mixture and its composition depends on several variables, including the combustion parameters of the boiler in which it is generated. We present an analysis of the amendment of two Canadian forest soils (a Brunisol from the Great Lakes–St. Lawrence and a Luvisol from the Carolinian forest regions of Ontario) with six different wood ashes collected from different biomass boilers through short-term controlled incubations. We show that following an 8-wk incubation period, amendment of the soils with wood ash led to small to moderate increases in soil pH, but had little effect on soil microbial activity and biomass. The concentration of important base cations such as calcium, magnesium and potassium as well as phosphorus generally increased in both soil types following amendment with different ash. This practice can return nutrients lost from forest ecosystems during harvesting; however, effects were found to be boiler-specific. Lastly, we show that four ash types led to small increases in cadmium in either soil; the concentration of all other measured heavy metals was not significantly increased following amendment, and in certain cases decreased, particularly with lead. The only potentially negative aspect encountered was elevated sodium, particularly with ash from one boiler, but unacceptable Na-absorptivity ratios were not exceeded. These results demonstrate that with proper characterization and selection of wood ash type and application rates, amendment of Canadian forest soils with wood ash may benefit forest ecosystems and is unlikely to disrupt the chemical and biological processes in soil environments.


Author(s):  
Magdalena Banach-Szott ◽  
Bozena Debska ◽  
Erika Tobiasova

AbstractMany studies report organic carbon stabilization by clay minerals, but the effects of land use and soil type on the properties of humic acids (HAs) are missing. The aim of the paper is to determine the effects of land use and soil types on the characteristics of HAs, which have a considerable influence on organic matter quality. It was hypothesised that the effect of the land use on HAs properties depends on the particular size distribution. The research was performed in three ecosystems: agricultural, forest, and meadow, located in Slovakia. From each of them, the samples of 4 soil types were taken: Chernozem, Luvisol, Planosol, and Cambisol. The soil samples were assayed for the content of total organic carbon (TOC) and the particle size distribution. HAs were extracted with the Schnitzer method and analysed for the elemental composition, spectrometric parameters in the UV-VIS range, and hydrophilic and hydrophobic properties, and the infrared spectra were produced. The research results have shown that the properties of HAs can be modified by the land use and the scope and that the direction of changes depends on the soil type. The HAs of Chernozem and Luvisol in the agri-ecosystem were identified with a higher “degree of maturity”, as reflected by atomic ratios (H/C, O/C, O/H), absorbance coefficients, and the FT-IR spectra, as compared with the HAs of the meadow and forest ecosystem. However, as for the HAs of Cambisol, a higher “degree of maturity” was demonstrated for the meadow ecosystem, as compared with the HAs of the agri- and forest ecosystem. The present research has clearly identified that the content of clay is the factor determining the HAs properties. Soils with a higher content of the clay fraction contain HAs with a higher “degree of maturity”.


Author(s):  
Pujia Yu ◽  
Hailiang Xu ◽  
Shiwei Liu ◽  
Xinfeng Zhao ◽  
Qingqing Zhang ◽  
...  

During the past 20 years, great landscape changes took place in the northwest of China. Landscape change resulted in soil type transformations. This paper discusses the changes and fractal of soil types in oasis. In order to do it, the soil type maps of Manasi River Basin in 1987 and 2006 were used. 13 types of soil and 2 types of land-use were classified and analyzed in the study area. Results indicated many variations in characteristics. Firstly, all soil types underwent remarkable changes from 1987 to 2006 in the study area: the identified changed area was about 30% or 6506.33 km2. Secondly, in comparison with 1987, in 2006 2/3 of the area's soil types increased, while 1/3 decreased. Rapid expansion of Aquicambids (415.28 km2), and rapid decrease of Petrocambids (797.05 km2) and Aquisalids (415.93 km2) were the noticeable findings. Furthermore, Haplocambids obtained largest gains from other soil types, while Petrocambids lost largest area to other types. Additionally, the fractal relationship objectively existed between the perimeter and area of soil patches. The fractal dimension of Aquisalids, Petrocalcids and Ustifluvents became higher and their shapes became more complex during this period. The stability index was higher in 2006 which indicated that the spatial structure of soil type was more stable than in 1987. These chaotic and occasional changes were largely caused by human activities and natural conditions. Consequently, environmental managers should pay more attention to soil changes in the arid and semiarid region. Santrauka Per pastaruosius 20 metų šiaurės vakarų Kinijoje įvyko didelių kraštovaizdžio pokyčių, lėmusių ir dirvožemio tipų pakitimus. Remiantis 1987–2006 m. Manasi upės baseino dirvožemio žemėlapiais, aptariami dirvožemio tipų pokyčiai ir fraktalai oazėse. Pasirinktoje teritorijoje išskirta ir analizuota 13 dirvožemio tipų ir dvejopa žemėnauda. Nustatyta daug kintamųjų parametrų. Pirma, tirtõs teritorijos visų tipų dirvožemiai nuo 1987 iki 2006 m. žymiai pakito. Nustatytoji pokyčių zona apima apie 30 % teritorijos, arba 6 506,32 km2. Antra, palyginti su 1987 m., 2006 m. 10 dirvožemio tipų teritorija padidėjo, o 5 tipų sumažėjo. Sparčiai padidėjo Aquicambids (415,28 km2), sparčiai sumažėjo Petrocambids (797,05 km2) ir Aquisalids (415,93 km2), pokyčiai buvo žymūs. Iš visų kitų pakitusių dirvožemių tipų Haplocambids plotai padidėjo daugiausia, o labiausiai, palyginti su kitais, sumažėjo Petrocambids plotai. Be to, pastebėta, kad tarp dirvožemio teritorijos plotų ir perimetrų objektyviai egzistuoja fraktalinės sąsajos. Fraktalinės dimensijos Aquisalids, Petrocalcids ir Ustifluvents per minėtą laikotarpį padidėjo, o jų formos tapo sudėtingesnės. Stabilumo indeksas 2006 m. buvo didesnis. Tai rodė, kad erdvinė dirvožemio struktūra mažai pakito, tapo stabilesnė, palyginti nei buvo 1987 m. Šiuos atsitiktinius pokyčius iš esmės lėmė žmogaus veikla ir gamtinės sąlygos. Prieita prie išvados, kad sausojo ar pusiau sauso klimato regionuose kraštotvarkos vykdytojai dirvožemio pokyčiams turėtų skirti daugiau dėmesio.


2013 ◽  
Vol 33 (5) ◽  
pp. 965-975 ◽  
Author(s):  
Aloisio Bianchini ◽  
Pedro H. de M. Borges

The destruction of the cotton crop residues (cotton stalks) is a mandatory procedure in Brazil for prophylactic issues, but is a subject unexplored by the research and there are few studies that deal with this issue. However, this is not encouraged in recent decades, studies aimed at developing and evaluating equipment for this purpose. The present study had the objective to evaluate six methods for mechanical destruction of cotton crop residues. Each method was defined based on the principle of operation of the active parts of the equipment, which were tested in medium texture soil and in a clayey one. The variables used to evaluate the efficiency of the equipment were the regrowth rate, the theoretical field capacity and energy demand. The equipment with convergent concave disks (DCC) and flat cutters discs from manufacturer A (CPS-a) showed the best results in cotton stalks destruction in both soil types. The harrow disc (GPD) was efficient only in clay soil. It was concluded that the equipment with convergent concave disks, among those tested, was the most efficient to destroy cotton stalks, regardless of soil type, and that the harrow disc was not included among the best performers.


1969 ◽  
Vol 30 (3) ◽  
pp. 127-137
Author(s):  
Luis A. Gómez ◽  
José Lería Esmoris ◽  
B. G. Capó

The results obtained in two coffee fertilizer tests performed with the Puerto Rican variety of Coffea arabica on "Catalina Clay" are presented, statistically analyzed, and discussed. Nitrogen and phosphoric acid applications seem to be of greater importance as regards market-coffee production of the above variety in the soil type used, than are the applications of potash, which had no significant effects on the yields. These results are in sharp contrast with the results obtained by McClelland, who found potash applications to be essential and phosphoric acid applications to be not essential for maximum coffee production in Puerto Rico. It should be noted that McClelland's experiments were carried out on other soil types, which were probably not in condition to provide the coffee trees with their potash requirements.


2016 ◽  
Author(s):  
Matheus Henrique Nunes ◽  
Matthew P. Davey ◽  
David Anthony Coomes

Abstract. Understanding the causes of variation in plant functional traits is a central issue in ecology, particularly in the context of global change. Analyses of the drivers of traits variation based on thousands of tree species are starting to unravel patterns of variation at the global scale, but these studies tend to focus on interspecific variation, and the contribution of intraspecific changes remains less well understood. Hyperspectroscopy is a recently developed technology for estimating the traits of fresh leaves. Few studies have evaluated its potential for assessing inter- and intra-specific trait variability in community ecology. Working with 24 leaf traits for European tree species on contrasting soil types, found growing on deep alluvial soils and nearby shallow chalk soils, we ask: (i) What contribution do soil type and species identity make to trait variation? (ii) When traits are clustered into three functional groups (light capture and growth, leaf structure and defence, as well as rock-derived nutrients), are some groups more affected by soil than others? (iii) What traits can be estimated precisely using field spectroscopy? (iv) Can leaf spectra be used to detect inter-soil as well as inter-specific variation in traits? The contribution of species and soil-type effects to variation in traits were evaluated using statistical analyses. Foliar traits were predicted from spectral reflectance using partial least square regression, and so inter- and intra-specific variation. Most leaf traits varied greatly among species. The effects of soil type were generally weak by comparison. Macronutrient concentrations were greater on alluvial than chalk soils while micronutrient concentration showed the opposite trend. However, structural traits, as well as most pigments and phenolic concentrations varied little with soil type. Field spectroscopy provided accurate estimates of species-level trait values, but was less effective at detecting subtle variation of rock-derived nutrients between soil types. Field spectroscopy was a powerful technique for estimating cross-species variation in foliar traits and Si predictions using spectroscopy appear to be promising. However, it was unable to detect subtle within-species variation of traits associated with soil type.


Author(s):  
Songyan Li ◽  
Meng Li ◽  
Guoxi Wang ◽  
Xiaolei Sun ◽  
Beidou Xi ◽  
...  

Abstract Background Exploration of composition and chemical characteristics of soil dissolved organic matter (DOM) is significant to understand its biogeochemical role in terrestrial ecosystems. A total of 43 cropped and 16 natural soils (0–20 cm) under four soil types (cinnamon, chernozem, red and paddy soils) across China were collected to investigate the spectral characteristics of DOM using UV–Vis and 3D-EEM spectroscopy. Results The chernozem soils exhibited the highest aromaticity and humification degree among the four soil types. Ranges of biological index (BIX, 0.53–1.17) and fluorescence index (FI, 1.55–2.10) were found in the investigated DOM, showing joint contribution from allochthonous and autochthonous sources. Higher BIX and FI in the DOM of the paddy and red soils indicated a greater reliance on autochthonous sources for these two soil types. The cropped soils showed no significant differences in chemical characteristics and sources from the natural soils for the cinnamon, chernozem and red soils. UVA (16.2–47.9%) and UVC fulvic-like substances (15.4–40.5%) were the prevailing DOM components, which were highest in the chernozem soils. Additionally, the cropped soils had a higher proportion of humic-like substances than the natural soils in the DOM. Conclusions Both soil type and land-use strongly affected the chemical characteristics of soil DOM, but only soil type had an impact on the DOM composition for the collected soils. These findings may contribute to the prediction of the biochemical behavior of soil DOM under different soil types and land-uses in terrestrial ecosystems.


2015 ◽  
Vol 66 (4) ◽  
pp. 204-213 ◽  
Author(s):  
Cezary Kabała ◽  
Elżbieta Musztyfaga

AbstractSoil with a clay-illuvial subsurface horizon are the most widespread soil type in Poland and significantly differ in morphology and properties developed under variable environmental conditions. Despite the long history of investigations, the rules of classification and cartography of clay-illuvial soils have been permanently discussed and modified. The distinction of clay-illuvial soils into three soil types, introduced to the Polish soil classification in 2011, has been criticized as excessively extended, non-coherent with the other parts and rules of the classification, hard to introduce in soil cartography and poorly correlated with the international soil classifications. One type of clay-illuvial soils (“gleby płowe”) was justified and recommended to reintroduce in soil classification in Poland, as well as 10 soil subtypes listed in a hierarchical order. The subtypes may be combined if the soil has diagnostic features of more than one soil subtypes. Clear rules of soil name generalization (reduction of subtype number for one soil) were suggested for soil cartography on various scales. One of the most important among the distinguished soil sub-types are the “eroded” or “truncated” clay-illuvial soils.


2018 ◽  
Vol 98 (3) ◽  
pp. 500-507
Author(s):  
D.D. Zhu ◽  
L.P. Zhan ◽  
R.H. Cong ◽  
X.K. Li

To understand the chemical behavior of potassium (K) in soil, rhizobox experiments were conducted to study the effects of K uptake by cultivated rice and soil type on K migration and transformation in soils. The aim of this study was to guide reasonable application of K fertilizer in different soil types. The results showed that at the maximum tillering stage, the migration distances of water-soluble K (Sol-K) were 6 and 5 cm, the depletion of exchangeable K (Ex-K) was 7 and 4 cm, and depletion of nonexchangeable K (Nonex-K) was 1 and 5 cm, respectively, in yellow cinnamon soil (YCS) and fluvo-aquic soil (FS). With the growth of rice, the migration distances of Sol-K showed little difference between YCS and FS. Throughout the season, the contributions of Sol-K, Ex-K, and Nonex-K to K uptake in YCS were 12.0%, 40.0%, and 48.0%, respectively, whereas their contributions in FS were 25.7%, 25.8%, and 48.5%, respectively. K uptake by rice was linearly related to the concentration of different forms of K in soils (R2 = 0.687*). In conclusion, soil type significantly affected K mobilization and transformation behavior. This indicated that the location of K fertilizer addition in the root zone should differ with soil type.


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