Investigation of the chemical ordering and thermal properties of the Rh–Ag–Au nanoalloys

Author(s):  
Huseyin Yildirim

In this paper, the melting behaviors of Rh–Ag–Au nanoalloys are investigated with MD simulation. For Rh–Ag–Au nanoalloys, icosahedron structure was considered. The local optimizations of Rh–Ag–Au nanoalloys were carried out with the BH algorithm. The interatomic interactions were modeled with the Gupta potential. The local optimization results of Rh–Ag–Au nanoalloys show that Au and Ag atoms prefer to locate on the surface, and Rh atoms prefer to locate in the inner shells. The bond order parameter result is compatible with the excess energy analysis. It is noted that structures with more Ag–Au bonds are more energetically stable. Caloric curve, heat capacity, Lindemann index, and RMSD methods were used for estimating the melting temperatures of Rh–Ag–Au nanoalloys. According to the simulation results, melting temperatures depend on the composition. Also, it is discovered that nanoalloys are generally melting in two stages. Surface melting of the third shell is occupied by Ag and Au atoms, and then homogeneous melting of the inner shells is occupied by Rh atoms. It is found that the difference between surface melting temperatures and homogeneous melting temperatures in Ag-poor compositions is more significant than that of Ag-rich nanoalloys. In addition, the melting temperatures of the nanoalloys are found to be increased as the size of nanoalloys increases.

2018 ◽  
Vol 11 (1) ◽  
pp. 49-60
Author(s):  
Miftahul Huda

The reality of the difference in applying Islamic law in the context of marriage law legislation in modern Muslim countries is undeniable. Tunisia and Turkey, for example, have practiced Islamic law of liberal nuance. Unlike the case with Saudi Arabia and the United Arab Emirates that still use the application of Islamic law as it is in their fiqh books. In between these two currents many countries are trying to apply the law in their own countries by trying to bridge the urgent new needs and local wisdom. This is widely embraced by modern Muslim countries in general. This paper reviews typologically the heterogeneousness of family law legislation of modern Muslim countries while responding to modernization issues. Typical buildings seen from modern family law reforms can be classified into four types. The first type is progressive, pluralistic and extradoctrinal reform, such as in Turkey and Tunisia. The second type is adaptive, unified and intradoctrinal reform, as in Indonesia, Malaysia, Morocco, Algeria and Pakistan. The third type is adaptive, unified and intradoctrinal reform, represented by Iraq. While the fourth type is progressive, unifiied and extradoctrinal reform, which can be represented by Somalia and Algeria.


SUHUF ◽  
2015 ◽  
Vol 2 (1) ◽  
pp. 53-72
Author(s):  
Ahmad Fathoni
Keyword(s):  

The object of the study of the knowledge of the variety of the Quranic reading  is the  Qur'an itself. The focus is on the difference of the reading and its articulation. The method is based on the riwayat or narration which is originated from the Prophet (Rasulullah saw) and its use is to be one of the instruments to keep the originality of the Qur’an. The validity of the reading the Qur’an is to be judged based on the valid chain  (sanad ¡a¥ī¥)  in accord with the Rasm U£mānÄ« as well as with the  Arabic grammar. Whereas the qualification of its originality is divided into six stages as follow: the first is mutawātir, the second is masyhÅ«r, the third is āhād, the fourth is syaz, the fifth is maudū‘, and the six is mudraj. Of this six catagories, the readings which can be included in the catagory of mutawātir are Qiraat Sab‘ah (the seven readings) and Qiraat ‘Asyrah  (the ten readings). To study this knowledge of reading the Qur’an (ilmu qiraat), one is advised to know about special terms being used such as  qiraat  (readings), riwayat (narration), tarÄ«q (the way), wajh (aspect), mÄ«m jama‘, sukÅ«n mÄ«m jama‘ and many others.


Author(s):  
Bradford Skow

This book aims to answer the following questions: what is the difference between a cause and a background condition? What is it to manifest a disposition? Can dispositions be extrinsic? What is the most basic kind of causation? And, what might a structural explanation be? Each chapter takes up a subset of these questions; the chapters are written to be readable independently. The answers defended rely on three ideas. Two of those ideas use a distinction from the study of lexical aspect, namely the distinction between stative verbs and non-stative verbs. The first idea is that events go with non-stative verbs, in the sense that “If S, then an event occurred in virtue of the fact that S” is true when the main verb in the clause going in for “S” is non-stative. The second is that acting, doing something, goes with non-stative verbs, in the sense that “In Ving X did something” is true iff V is a non-stative verb. The third idea is about levels of explanation: “(A because B) because C” does not entail “A because C.”


Author(s):  
Stephen P. Borgatti ◽  
Martin G. Everett

This chapter presents three different perspectives on centrality. In part, the motivation is definitional: what counts as a centrality measure and what doesn’t? But the primary purpose is to lay out ways that centrality measures are similar and dissimilar and point to appropriate ways of interpreting different measures. The first perspective the chapter considers is the “walk structure participation” perspective. In this perspective, centrality measures indicate the extent and manner in which a node participates in the walk structure of a graph. A typology is presented that distinguishes measures based on dimensions such as (1) what kinds of walks are considered (e.g., geodesics, paths, trails, or unrestricted walks) and (2) whether the number of walks is counted or the length of walks is assessed, or both. The second perspective the chapter presents is the “induced centrality” perspective, which views a node’s centrality as its contribution to a specific graph invariant—typically some measure of the cohesiveness of the network. Induced centralities are computed by calculating the graph invariant, removing the node in question, and recalculating the graph invariant. The difference is the node’s centrality. The third perspective is the “flow outcomes” perspective. Here the chapter views centralities as estimators of node outcomes in some kind of propagation process. Generic node outcomes include how often a bit of something propagating passes through a node and the time until first arrival of something flowing. The latter perspective leads us to consider the merits of developing custom measures for different research settings versus using off-the-shelf measures that were not necessarily designed for the current purpose.


2021 ◽  
Vol 21 (1) ◽  
Author(s):  
Hetti von Hellens ◽  
Leea Keski-Nisula ◽  
Heidi Sahlman

Abstract Background The maternal use of paracetamol during pregnancy has been associated with the development of preeclampsia. This study aims to clarify whether the connection is causal or whether it is due to reverse causation. Methods This study is a continuation of the retrospective case cohort study examining 2,508 pregnant women using a variety of drugs and the development of preeclampsia (1,252 women with preeclampsia and 1,256 controls). For the purposes of this study, more precise data was collected from several hospital databases of the women among this cohort who had reported taking paracetamol during pregnancy (indications, gestational period etc.); this was evaluated in association with the development of preeclampsia. Results 5.5% (100 cases and 37 controls) of all the study population (2,508) had clearly reported paracetamol use. Women with preeclampsia had used significantly more often paracetamol during pregnancy compared to controls (cases 8.0%, controls 2.9%, p < 0.001). The difference was most evident in the third trimester (after the 29th GW) and the use of paracetamol was associated with both mild and severe preeclampsia. Headache and “general pain” were the most common indications for medication among all paracetamol users. Conclusions The use of paracetamol in the third trimester of pregnancy was associated with preeclampsia. This observation indicates that association between paracetamol use and preeclampsia is probably due to reverse causation, i.e. women with preeclampsia experience more headaches due to preeclampsia symptoms since this association was not detected with the use of paracetamol in earlier stages of pregnancy.


2021 ◽  
pp. bmjspcare-2021-002971
Author(s):  
Moshe Y Flugelman

Informing families about the impending or actual death of their relatives is one of the most challenging and complex tasks a physician may face. The following article describes goal setting and provides five roles/recommendations for conducting the encounter with patient families regarding the imminent or actual death of their relatives. Importantly, the encounter should be family-centred, and the physician should be highly attentive to family needs. The following roles should be applied based on family needs and should not be sequential as numbered. The first and basic role is to inform the family at the earliest possible time and as often as possible. The second goal of the physician is to convey to the family that their relative received the needed therapy during his hospitalisation or in the community. The third goal of the physician is to help the family reach acceptance of the death of their relative and leave the hospital having moved beyond anger and bargaining. The fourth goal of the physician during the encounters is to reduce or alleviate guilt by stating that nothing could have changed the course of the disease and that all efforts were made to save the patient. The fifth role of the physician is to try and help the family as a single entity and maintain their unity during this stressful situation. Following these roles/methods will help families in the stressful situation and will create the difference between anger and understanding, rage and compassion, and loss and acceptance.


1945 ◽  
Vol 35 (1-2) ◽  
pp. 58-64 ◽  
Author(s):  
H. H. Scullard

In the settlement of Greece after the Third Macedonian War Roman policy was at times moderate, at times harsh. On occasion the difference might represent only an individual point of view: thus the terms imposed upon Macedonia might seem generous to a Roman who contemplated the grant of ‘freedom’ to the Macedonians, the reduction of taxation and the absence of territorial aggression on Rome's part, while they might equally seem harsh to a Macedonian who felt that his sense of nationhood had been violated by Rome's creation of the four independent Republics. But towards Epirus Roman policy seems to have been marked by two successive stages, the first moderate, the second brutal. It is the purpose of this note to attempt to consider the causes which determined this change and to examine what influence the Epirote Charops exercised upon the measures which turned his country into a playground for Roman brutality and ultimately into an abomination of desolation.


2013 ◽  
Vol 35 (1) ◽  
Author(s):  
Jahel Queralt

AbstractRawls identifies only two arrangements, the liberal socialist regime and the property-owning democracy, as being compatible with justice. Both are market-based economies, suggesting that a just society must include the market. This article questions this idea by looking at three Rawlsian arguments in favour of the market. Two arguments, which link the market to certain basic liberties, are unsound because the market is shown to be nonessential in protecting these liberties. A third argument points at the instrumental value of the market to make the least advantaged as well off as possible. R. is based on an interpretation of the difference principle in which justice requires maximizing the position of the worst off within the most productive economic system. Although commonly accepted, this reading of the principle should be questioned, and thus the third argument is also inconclusive.


De Jure ◽  
2021 ◽  
Vol 12 (1) ◽  
Author(s):  
Daniel Haman ◽  
◽  
◽  

The difference between intent (dolus) and negligence (culpa) was rarely emphasized in codified medieval laws and regulations. When compared to the legal statements related to intent, negligence was mentioned even more rarely. However, there are some laws that distinguished between the two concepts in terms of some specific crimes, such as arson. This paper draws attention to three medieval Slavic legal documents – the Zakon Sudnyj LJudem (ZSLJ), the Vinodol Law and the Statute of Senj. They are compared with reference to regulations regarding arson, with the focus being on arson as a crime committed intentionally or out of negligence. The ZSLJ as the oldest known Slavic law in the world shows some similarities with other medieval Slavic legal codes, especially in the field of criminal law, since most of the ZSLJ’s articles are related to criminal law. On the other hand, the Vinodol Law is the oldest preserved Croatian law and it is among the oldest Slavic codes in the world. It was written in 1288 in the Croatian Glagolitic script and in the Croatian Chakavian dialect. The third document – the Statute of Senj – regulated legal matters in the Croatian littoral town of Senj. It was written in 1388 – exactly a century after the Vinodol Law was proclaimed. When comparing the Vinodol Law and the Statute of Senj with the Zakon Sudnyj LJudem, there are clear differences and similarities, particularly in the field of criminal law. Within the framework of criminal offenses, the act of arson is important for making a distinction between intent and negligence. While the ZSLJ regulates different levels of guilt, the Vinodol Law makes no difference between dolus and culpa. On the other hand, the Statute of Senj strictly refers to negligence as a punishable crime. Even though the ZSLJ is almost half a millennium older than the Statute of Senj and around 400 years older than the Vinodol Law, this paper proves that the ZSLJ defines the guilt and the punishment for arson much better than the other two laws.


Equilibrium ◽  
2013 ◽  
Vol 8 (3) ◽  
pp. 79-101
Author(s):  
Lilianna Jodkowska

The aim of the article is to present new regulations introduced by the Third Book of the Social Code in Germany that concern a reform of the labor market's active instruments gathered under the name "Instumentenreform".  One of the main objectives of the reform is to improve the quality of programs and projects that activate the unemployed, but also to make efforts to include in the labor market groups that have not been activated in such a way so far. One of such groups are the disabled trained and employed in Invalids' Cooperatives.  One of the further, and at the same time new, criteria for all organizations and institutions receiving and applying for funds to realize programs of the labor market and vocational trainings is the introduction and certification of the quality management system. The aim of the paper is to compare the activity of Invalids' Cooperatives in Poland and Germany. This aim will be carried out by analyzing the regulations and as far as possible the data available (the regulations became effective in two stages: in April 2012, and since 01.01.2013 onwards).  The findings of the article have been collected in the form of a description of the situation and forecast for 2013.


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