MODIFICATION OF BaCeO3 PROTONIC CONDUCTORS BY Ag AND Y DOPING
Silver and yttrium dopants influence some physico-chemical properties of BaCeO 3 protonic conduction. Ag -acceptor dopant substituting Ba atom in BaCeO 3 compounds was studied for the first time. Ba 1-x Ag x Ce 1-y Y y O 3-δ (0 ≤ x ≤ 0.1, 0 ≤ y ≤ 0.1) materials were synthesized by solid state reaction and by modified Pechini citric acid method. X-ray diffraction (XRD) and electrical properties measurements including open cell voltage (OCV) of electrochemical cells were used as experimental techniques. Basing on XRD results it was found that all synthesized materials crystallized in orthorhombic Pnma phase with some admixtures of other phases. Metallic Ag , CeO 2 or Y 2 O 3 with different concentrations were detected, depending on the composition, synthesis method and preparation details. DC electrical measurements showed that doping by Ag and Y decreased the total and ionic conductivities of the materials. The modification of charge transport properties was also observed, namely introduction of Ag led to the increase of electronic component of total electrical conductivity, especially at higher temperatures.