Organic geochemistry at varying scales: from kilometres to ångstroms

2018 ◽  
Vol 484 (1) ◽  
pp. 121-137 ◽  
Author(s):  
Clifford C. Walters
Keyword(s):  
Plate Tectonics ◽  
Organic Geochemistry ◽  
Geographical Location ◽  
Analytical Techniques ◽  
Source Rocks ◽  
Force Microscopy ◽  
Petroleum Systems ◽  
Petroleum Geochemistry ◽  
Field Samples ◽  
Single Well

AbstractPetroleum geochemistry has historically relied on the analysis of field samples – source rocks, oils and gases. Data collected for individual samples are considered characteristic of a specific geographical location and geological position that, when aggregated with data from other samples, can be extrapolated to larger scales. These scale-ups may be as small as a few metres, such as a detailed characterization of source rocks penetrated by a single well, to global, such as petroleum systems that now span continents due to plate tectonics. However, a single sample contains a wealth of information at smaller scales. In situ analytical techniques have improved significantly over the last decade, allowing us to examine sedimentary rocks at ever higher spatial (areal and temporal) resolution. Mass spectrometric imaging is an emerging, enabling technology that can be performed at c. 200 µm (matrix-assisted laser desorption) to 50 nm (nanoSIMS) resolution. X-ray microcomputed tomography (µ-CT) is being applied to examine the storage and transport of petroleum in low-permeability shales and carbonates at spatial resolutions as low as c. 8 µm. Pore architecture in shale, both organic and inorganic, can be modelled from small-angle neutron scattering (SANS) data and imaged directly with helium ion microscopy at c. 1 nm resolution. Atomic force microscopy (AFM) can now resolve the molecular structure of individual asphaltene molecules. Information obtained with these techniques is now revealing the fundamental nature of geological organic materials, opening the span of petroleum geochemistry from atoms to continents.

About this title - Application of Analytical Techniques to Petroleum Systems

10.1144/sp484 ◽  
2020 ◽  
Vol 484 (1) ◽  
pp. NP-NP
Author(s):  
Patrick J. Dowey ◽  
Mark Osborne ◽  
Herbert Volk
Keyword(s):  
Oil And Gas ◽  
Organic Geochemistry ◽  
Analytical Techniques ◽  
Petroleum Exploration ◽  
Electricity Production ◽  
Sediment Provenance ◽  
Chemical Production ◽  
Petroleum Systems ◽  
Wide Range ◽  
Analytical Approaches

Cutting-edge techniques have always been utilized in petroleum exploration and production to reduce costs and improve efficiencies. The demand for petroleum in the form of oil and gas is expected to increase for electricity production, transport and chemical production, largely driven by an increase in energy consumption in the developing world. Innovations in analytical methods will continue to play a key role in the industry moving forwards as society shifts towards lower carbon energy systems and more advantaged oil and gas resources are targeted. This volume brings together new analytical approaches and describes how they can be applied to the study of petroleum systems. The papers within this volume cover a wide range of topics and case studies, in the fields of fluid and isotope geochemistry, organic geochemistry, imaging and sediment provenance. The work illustrates how the current, state-of-the-art technology can be effectively utilised to address ongoing challenges in petroleum geoscience.

scholarly journals Application of analytical techniques to petroleum systems: an introduction

2020 ◽  
Vol 484 (1) ◽  
pp. 1-7
Author(s):  
Patrick J. Dowey ◽  
Mark Osborne ◽  
Herbert Volk
Keyword(s):  
Organic Geochemistry ◽  
Isotope Geochemistry ◽  
Analytical Techniques ◽  
Petroleum Exploration ◽  
Sediment Provenance ◽  
Petroleum Systems ◽  
Current State ◽  
Wide Range ◽  
Exploration And Production ◽  
Analytical Approaches

AbstractCutting-edge techniques have always been utilized in petroleum exploration and production to reduce costs and improve efficiencies. Innovations in analytical methods will continue to play a key role in the industry moving forwards, as society shifts towards lower carbon energy systems. This volume brings together new analytical approaches and describes how they can be applied to the study of petroleum systems. The papers within this volume cover a wide range of topics and case studies, in the fields of fluid and isotope geochemistry, organic geochemistry, imaging and sediment provenance. The work illustrates how the current, state-of-the-art technology can be effectively utilized to address ongoing challenges in petroleum geoscience.

scholarly journals Lamination Texture and Its Effects on Reservoir and Geochemical Properties of the Palaeogene Kongdian Formation in the Cangdong Sag, Bohai Bay Basin, China

Minerals ◽  
2021 ◽  
Vol 11 (12) ◽  
pp. 1360
Author(s):  
Mengying Li ◽  
Songtao Wu ◽  
Suyun Hu ◽  
Rukai Zhu ◽  
Siwei Meng ◽  
...  
Keyword(s):  
Vertical Distribution ◽  
Thin Section ◽  
Organic Geochemistry ◽  
Source Rocks ◽  
Diffraction Field ◽  
Bohai Bay ◽  
Geochemical Properties ◽  
Vertical Distributions ◽  
Single Well ◽  
Intercrystalline Pores

The characteristics of laminae are critical to lacustrine shale strata. They are the keys to the quality of source rocks and reservoirs, as well as engineering operations in shale plays. This study uses organic geochemistry, thin section identification, X-ray diffraction, field emission scanning electron microscopy, and other analytical methods, to reveal the detailed lamination texture and vertical distribution of laminae in the second Member of the Kongdian Formation in Cangdong Sag. The principal results are as follows: (1) A classification of laminae is proposed to characterize reservoir and geochemical properties. The five types of laminae are as follows: feldspar-quartz laminae (FQL), clay laminae (CLL), carbonate laminae (CAL), organic matter laminae (OML), and bioclastic laminae (BCL). There are also four significant lamina combinations (with the increasing TOC values): FQL-CLL combination, FQL-CLL-BCL combination, FQL-CLL-OML combination, and FQL-CAL-CLL-OML combination; (2) differences between laminae occur because of the variability in pore types and structures. There appears to be a greater abundance of intercrystalline pores of clay minerals in the FQL, CAL, BCL, and OML, and well-developed organic pores in the CAL and CLL, and the counterparts of intragranular pores of bioclastic material in the BCL. This detailed characterization provides the following comparative quantification of the thin section porosity of laminae in the second Member of the Kongdian Formation can be differentiated: CAL > FQL > OML > BCL > CLL; (3) differentiation between vertical distributions of laminae is carried out in a single well. The FQL and CLL are widely distributed in all the samples, while the BCL is concentrated in the upper part of the second Member of the Kongdian Formation, and CAL is concentrated in the lower part. This detailed classification method, using geochemical analysis and vertical distribution descriptions, offers a detailed understanding of lamination texture and its effects on reservoir and geochemical properties, which will provide a scientific guidance and technical support to better estimate reservoir quality and to identify new sweet spots in the second Member of the Kongdian Formation in the Cangdong Sag.

scholarly journals Extracellular Vesicles Analysis in the COVID-19 Era: Insights on Serum Inactivation Protocols towards Downstream Isolation and Analysis

Cells ◽  
2021 ◽  
Vol 10 (3) ◽  
pp. 544
Author(s):  
Roberto Frigerio ◽  
Angelo Musicò ◽  
Marco Brucale ◽  
Andrea Ridolfi ◽  
Silvia Galbiati ◽  
...  
Keyword(s):  
Extracellular Vesicles ◽  
Analytical Techniques ◽  
Heat Inactivation ◽  
Force Microscopy ◽  
Atomic Force ◽  
Droplet Pcr ◽  
Detergent Treatment ◽  
Routine Procedures ◽  
The Impact ◽  
Mirna Content

Since the outbreak of the COVID-19 crisis, the handling of biological samples from confirmed or suspected SARS-CoV-2-positive individuals demanded the use of inactivation protocols to ensure laboratory operators’ safety. While not standardized, these practices can be roughly divided into two categories, namely heat inactivation and solvent-detergent treatments. These routine procedures should also apply to samples intended for Extracellular Vesicles (EVs) analysis. Assessing the impact of virus-inactivating pre-treatments is therefore of pivotal importance, given the well-known variability introduced by different pre-analytical steps on downstream EVs isolation and analysis. Arguably, shared guidelines on inactivation protocols tailored to best address EVs-specific requirements will be needed among the analytical community, yet deep investigations in this direction have not yet been reported. We here provide insights into SARS-CoV-2 inactivation practices to be adopted prior to serum EVs analysis by comparing solvent/detergent treatment vs. heat inactivation. Our analysis entails the evaluation of EVs recovery and purity along with biochemical, biophysical and biomolecular profiling by means of a set of complementary analytical techniques: Nanoparticle Tracking Analysis, Western Blotting, Atomic Force Microscopy, miRNA content (digital droplet PCR) and tetraspanin assessment by microarrays. Our data suggest an increase in ultracentrifugation (UC) recovery following heat treatment; however, it is accompanied by a marked enrichment in EVs-associated contaminants. On the other hand, solvent/detergent treatment is promising for small EVs (<150 nm range), yet a depletion of larger vesicular entities was detected. This work represents a first step towards the identification of optimal serum inactivation protocols targeted to EVs analysis.

scholarly journals NEW GEOCHEMICAL INSIGHTS INTO CENOZOIC SOURCE ROCKS IN AZERBAIJAN: IMPLICATIONS FOR PETROLEUM SYSTEMS IN THE SOUTH CASPIAN REGION

2021 ◽  
Vol 44 (3) ◽  
pp. 349-384 ◽  
Author(s):  
V. Aghayeva ◽  
R. F. Sachsenhofer ◽  
C.G.C. van Baak ◽  
A. Bechtel ◽  
T. M. Hoyle ◽  
...  
Keyword(s):  
Source Rocks ◽  
Caspian Region ◽  
The South ◽  
Petroleum Systems

scholarly journals The β-oxidation pathway is downregulated during diapause termination in Calanus copepods

2019 ◽  
Vol 9 (1) ◽  
Author(s):  
Elise Skottene ◽  
Ann M. Tarrant ◽  
Anders J. Olsen ◽  
Dag Altin ◽  
Mari-Ann Østensen ◽  
...  
Keyword(s):  
Current Knowledge ◽  
Juvenile Fish ◽  
Sampling Site ◽  
Geographical Location ◽  
Keystone Species ◽  
Calanoid Copepods ◽  
Diapause Termination ◽  
Molecular Events ◽  
High Lipid ◽  
Field Samples

Abstract Calanus copepods are keystone species in marine ecosystems, mainly due to their high lipid content, which is a nutritious food source for e.g. juvenile fish. Accumulated lipids are catabolized to meet energy requirements during dormancy (diapause), which occurs during the last copepodite stage (C5). The current knowledge of lipid degradation pathways during diapause termination is limited. We characterized changes in lipid fullness and generated transcriptional profiles in C5s during termination of diapause and progression towards adulthood. Lipid fullness of C5s declined linearly during developmental progression, but more β-oxidation genes were upregulated in early C5s compared to late C5s and adults. We identified four possible master regulators of energy metabolism, which all were generally upregulated in early C5s, compared to late C5s and adults. We discovered that one of two enzymes in the carnitine shuttle is absent from the calanoid copepod lineage. Based on the geographical location of the sampling site, the field-samples were initially presumed to consist of C. finmarchicus. However, the identification of C. glacialis in some samples underlines the need for performing molecular analyses to reliably identify Calanus species. Our findings contributes to a better understanding of molecular events occurring during diapause and diapause termination in calanoid copepods.

Research for the Upstream Petroleum Sector: The Crown Research Institute Concept

1995 ◽  
Vol 13 (2-3) ◽  
pp. 245-252
Author(s):  
J M Beggs
Keyword(s):  
New Zealand ◽  
Oil And Gas ◽  
Sedimentary Basins ◽  
Source Rocks ◽  
Publicly Funded ◽  
Petroleum Systems ◽  
Oil And Gas Resources ◽  
Petroleum Sector ◽  
Geological Sciences ◽  
Research Institute

New Zealand's scientific institutions have been restructured so as to be more responsive to the needs of the economy. Exploration for and development of oil and gas resources depend heavily on the geological sciences. In New Zealand, these activities are favoured by a comprehensive, open-file database of the results of previous work, and by a historically publicly funded, in-depth knowledge base of the extensive sedimentary basins. This expertise is now only partially funded by government research contracts, and increasingly undertakes contract work in a range of scientific services to the upstream petroleum sector, both in New Zealand and overseas. By aligning government-funded research programmes with the industry's knowledge needs, there is maximum advantage in improving the understanding of the occurrence of oil and gas resources. A Crown Research Institute can serve as an interface between advances in fundamental geological sciences, and the practical needs of the industry. Current publicly funded programmes of the Institute of Geological and Nuclear Sciences include a series of regional basin studies, nearing completion; and multi-disciplinary team studies related to the various elements of the petroleum systems of New Zealand: source rocks and their maturation, migration and entrapment as a function of basin structure and tectonics, and the distribution and configuration of reservoir systems.

Organic geochemistry of Miocene source rocks from the Banat Depression (SE Pannonian Basin, Serbia)

2011 ◽  
Vol 42 (6) ◽  
pp. 655-677 ◽  
Author(s):  
Sanja Mrkić ◽  
Ksenija Stojanović ◽  
Aleksandar Kostić ◽  
Hans Peter Nytoft ◽  
Aleksandra Šajnović
Keyword(s):  
Organic Geochemistry ◽  
Pannonian Basin ◽  
Source Rocks

scholarly journals The Cogollo Group and the oceanic anoxic events 1a and 1b, Maracaibo basin, Venezuela

2015 ◽  
Vol 45 (suppl 1) ◽  
pp. 41-61 ◽  
Author(s):  
José Alejandro Méndez Dot ◽  
José Méndez Baamonde ◽  
Dayana Reyes ◽  
Rommel Whilchy
Keyword(s):  
Source Rock ◽  
Organic Geochemistry ◽  
Sedimentary Facies ◽  
Source Rocks ◽  
Maracaibo Basin ◽  
Pelagic Environment ◽  
Anoxic Events ◽  
Anoxic Environment ◽  
Platform System ◽  
La Luna

ABSTRACTCarbonates of Cogollo Group (Apón, Lisure and Maraca formations) constitute the broader calcareous platform system originated during Aptian and Albian of Cretaceous in north-western South America, Maracaibo Basin, Venezuela. On the shallow shelf, a variety of calcareous sedimentary facies were deposited during marine transgressive and regressive cycles. Some of them developed porosity and constitute important hydrocarbon reservoirs. Due to some major marine transgressions, from early Aptian, the anoxic environment and characteristic facies of a pelagic environment moved from the outer slope and basin to the shallow shelf, during specific time intervals, favouring the sedimentation of organic matter-rich facies, which correspond to the oceanic anoxic events (OAEs) 1a and 1b. The source rock of Machiques Member (Apón Formation) was deposited during early Aptian OAE 1a (~ 120 Ma). The source rock of Piché Member, located at the top of the Apón Formation, was deposited during late Aptian OAE 1b (~ 113 Ma). Finally, La Luna Formation, from Cenomanian, that covers the OAE 2 (~ 93 Ma), represents the most important source rock in the Maracaibo Basin. In this way and based on sedimentological and organic geochemistry results from the determinations performed on 247 samples belonging to six cores in the Maracaibo Basin, we propose these two organic-rich levels, deposited on the shallow shelf of the Cogollo Group, as "effective source rocks", additional to La Luna Formation, with oil migration in relatively small distances to the porosity facies.

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