scholarly journals Hydrodynamic Cavitation-Assisted Synthesis of Nanocalcite

2010 ◽  
Vol 2010 ◽  
pp. 1-8 ◽  
Author(s):  
Shirish H. Sonawane ◽  
Sarang P. Gumfekar ◽  
Kunal H. Kate ◽  
Satish P. Meshram ◽  
Kshitij J. Kunte ◽  
...  

A systematic study was made on the synthesis of nanocalcite using a hydrodynamic cavitation reactor. The effects of various parameters such as diameter and geometry of orifice,CO2flow rate, andCa(OH)2concentration were investigated. It was observed that the orifice diameter and its geometry had significant effect on the carbonation process. The reaction rate was significantly faster than that observed in a conventional carbonation process. The particle size was significantly affected by the reactor geometry. The results showed that an orifice with 5 holes of 1 mm size resulted in the particle size reduction to 37 nm. The experimental investigation reveals that hydrodynamic cavitation may be more energy efficient.

2017 ◽  
Vol 33 (6) ◽  
pp. 927-932
Author(s):  
Julie R Kalivoda ◽  
Cassandra K Jones ◽  
Charles R Stark

Abstract. Particle size reduction is an important component of feed manufacturing that impacts pellet quality, feed flowability, and animal performance. However, reducing particle size too fine often results in reduced flowability of the ground corn and finished feed, which creates potential handling and storage concerns at the feed mill and farm. The objective of this experiment was to determine how fractionation affected flowability of ground corn. Whole corn was received from a single source and ground to achieve 3 target particle sizes, 400, 500, and 600 µm with actual results of 469, 560, and 614 µm. Each target particle size was fractionated into three segments: fine (< 282 µm), medium (> 282 µm and < 630 µm), and coarse (> 630 µm) particles using a vibratory separator (model LS18SP3, SWECO, Florence, Ky.). Within particle size treatment, the percentage of sample obtained for each fraction was: 400 µm: 4.9%, 34.2%, and 60.9% for fine, medium, and coarse, respectively; 500 µm: 1.9%, 31.3%, and 66.9% for fine, medium, and coarse, respectively; and 600 µm: 1.0%, 24.4%, and 74.7% for fine, medium, and coarse, respectively. When the fractions were separated, their particle sizes were: 400 µm: 94, 269, and 744 µm for fine, medium, and coarse, respectively; 500 µm: 96, 253, and 815 µm for fine, medium, and coarse, respectively; and 600 µm: 99, 220, and 898 µm for fine, medium, and coarse, respectively. Fractionated samples were analyzed for multiple flowability characteristics, including: angle of repose, critical orifice diameter, composite flow index (CFI), bulk density, and compressibility. Treatments were arranged in a nested model with three replicates per treatment. Data were analyzed using the GLIMMIX procedure of SAS. When fraction was nested within particle size for each treatment, the fine fraction (< 282 µm) of the 400 µm corn had the poorest CFI (P < 0.05). Whereas the coarse fraction (> 630 µm) of the 600 µm corn had the best CFI. The nutrient content of the fractions was greatest in the medium fraction (> 282 µm and < 630 µm) for crude protein, fat, and acid detergent fiber (ADF). In conclusion, reducing particle size resulted in the ground corn having poorer flowability characteristics, caused predominantly by particles that passed through a 282 µm screen. Based on this data, producers may potentially grind corn to a lower particle size while maintaining flowability if fine particles (< 282 µm) are removed. Keywords: Corn, Flowability, Particle size analysis


Author(s):  
Hao Pang ◽  
Gracious Ngaile

A novel hydrodynamic cavitation–based dispensing process was developed to disperse SiO2 nanoparticles into the base oil, and the effects of process parameters on dispersity and tribological properties of SiO2/oil nanolubricants were studied using the dynamic laser scattering and ring compression tests. With this process, nanolubricants with fine nanoparticles (139–1240 nm) were formulated. A mean particle size reduction of 78% was achieved in 60 min. This process can be scaled up for mass production with relative ease. The formulated SiO2/oil nanolubricants exhibited better tribological performance over that of base oil. Lubrication mechanisms of the SiO2/oil nanolubricant in metal forming were ascertained through analysis of the dispersity of nanolubricants and characterization of dents appearing on the surface of the deforming material. The study revealed the importance of formulating nanolubricants with specific particle size distribution that relate to the surface morphology of the deforming material. In this study, a nanolubricant with particle size of 3.6 μm exhibited better lubrication on ring samples with dent depth of 4.7 μm, implying that most nanoparticles were encapsulated in the dents facilitating hydrostatic lubrication.


1995 ◽  
Vol 117 (4) ◽  
pp. 475-484 ◽  
Author(s):  
A. I. Ansari ◽  
M. Hashish

An experimental investigation was conducted to investigate the influence of abrasive waterjet parameters on the volume removal rate in abrasive waterjet turning. Abrasive mass flow rate, abrasive particle size, waterjet pressure, and orifice diameter were the principal variables that were investigated. Limited tests were also conducted with abrasive mixtures. The results show that the volume removal trends in abrasive waterjet turning are similar to those in linear cutting with abrasive waterjets. Increasing waterjet pressure, orifice diameter, and abrasive flow rate generally resulted in an increase in volume removal rate. However, the volume removal rate levels off either due to volume sweep rate limit or due to the abrasive waterjet limit. The results also suggest a potential for optimizing the abrasive flow rate and abrasive composition. The volume removal rate showed only a weak dependence on the abrasive particle size.


2018 ◽  
Author(s):  
Ping Peng ◽  
Fang-Fang Li ◽  
Xinye Liu ◽  
Jiawen Ren ◽  
jessica stuart ◽  
...  

The rate of ammonia production by the <u>chemical </u>oxidation of iron, N<sub>2</sub>(from air or as pure nitrogen) and water is studied as a function of (1) iron particle size, (2) iron concentration, (3) temperature, (4) pressureand (5) concentration of the alkaline reaction medium. The reaction meduium consists of an aqueous solution of equal molal concentrations of NaOH and KOH (Na<sub>0.5</sub>K<sub>0.5</sub>OH). We had previously reported on the <u>chemical </u>reaction of iron and nitrogen in alkaline medium to ammonia as an intermediate step in the <u>electrochemical </u>synthesis of ammonia by a nano-sized iron oxide electrocatlyst. Here, the intermediate <u>chemical </u>reaction step is exclusively explored. The ammonia production rate increases with temperature (from 20 to 250°C), pressure (from 1 atm to 15 atm of air or N<sub>2</sub>), and exhibits a maximum rate at an electrolyte concentration of 8 molal Na<sub>0,5</sub>K<sub>0,5</sub>OH in a sealed N<sub>2</sub>reactor. 1-3 µm particle size Fe drive the highest observed ammonia production reaction rate. The Fe mass normalized rate of ammonia production increases with decreasing added mass of the Fe reactant reaching a maximum observed rate of 2.2x10<sup>-4</sup>mole of NH<sub>3</sub>h<sup>-1</sup>g<sup>-1</sup>for the reaction of 0.1 g of 1-3 µm Fe in 200°C 8 molal Na<sub>0.5</sub>K<sub>0.5</sub>OH at 15 atm. Under these conditions 5.1 wt% of the iron reacts to form NH<sub>3</sub>via the reaction N<sub>2</sub>+ 2Fe + 3H<sub>2</sub>O ®2NH<sub>3</sub>+ Fe<sub>2</sub>O<sub>3</sub>.


2018 ◽  
Vol 60 (1) ◽  
pp. 42-45
Author(s):  
Tuan Quang Nguyen ◽  
Van Lam Nguyen ◽  
Thai Son Nguyen ◽  
Thi Minh Hue Pham ◽  
◽  
...  

1979 ◽  
Vol 44 (12) ◽  
pp. 3419-3424
Author(s):  
Karel Mocek ◽  
Erich Lippert ◽  
Dušan Husek ◽  
Emerich Erdös

The effect of particle size (0.33-1.0 mm) of the sodium carbonate on the reactivity of the active sodium carbonate prepared therefrom towards the sulfur dioxide was studied in a fixedbed integral reactor at a temperature of 150 °C. The found dependence of the reaction rate on the particle size exhibits an unexpected course; at sizes of about 0.65 mm, a distinct minimum appears. The reaction rate decreases approximately ten times in the first branch of this dependence. The controlling factor of the reactivity of sodium carbonate, however, remains to be the method of preparing the active form.


2021 ◽  
Vol 11 (1) ◽  
Author(s):  
E. S. Prasedya ◽  
A. Frediansyah ◽  
N. W. R. Martyasari ◽  
B. K. Ilhami ◽  
A. S. Abidin ◽  
...  

AbstractSample particle size is an important parameter in the solid–liquid extraction system of natural products for obtaining their bioactive compounds. This study evaluates the effect of sample particle size on the phytochemical composition and antioxidant activity of brown macroalgae Sargassum cristaefolium. The crude ethanol extract was extracted from dried powders of S.cristeafolium with various particle sizes (> 4000 µm, > 250 µm, > 125 µm, > 45 µm, and < 45 µm). The ethanolic extracts of S.cristaefolium were analysed for Total Phenolic Content (TPC), Total Flavonoid Content (TFC), phenolic compound concentration and antioxidant activities. The extract yield and phytochemical composition were more abundant in smaller particle sizes. Furthermore, the TPC (14.19 ± 2.08 mg GAE/g extract to 43.27 ± 2.56 mg GAE/g extract) and TFC (9.6 ± 1.8 mg QE/g extract to 70.27 ± 3.59 mg QE/g extract) values also significantly increased as particle sizes decreased. In addition, phenolic compounds epicatechin (EC), epicatechin gallate (ECG), epigallocatechin (EGC), and Epigallocatechin gallate (EGCG) concentration were frequently increased in samples of smaller particle sizes based on two-way ANOVA and Tukey’s multiple comparison analysis. These results correlate with the significantly stronger antioxidant activity in samples with smaller particle sizes. The smallest particle size (< 45 µm) demonstrated the strongest antioxidant activity based on DPPH, ABTS, hydroxyl assay and FRAP. In addition, ramp function graph evaluates the desired particle size for maximum phytochemical composition and antioxidant activity is 44 µm. In conclusion, current results show the importance of particle size reduction of macroalgae samples to increase the effectivity of its biological activity.


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