scholarly journals Rheological Properties of Polysaccharides from Longan (Dimocarpus longanLour.) Fruit

2015 ◽  
Vol 2015 ◽  
pp. 1-5 ◽  
Author(s):  
Xingxun Liu ◽  
Yongyue Luo ◽  
Chunjie Zha ◽  
Sumei Zhou ◽  
Liya Liu ◽  
...  

Longan polysaccharide (LP) was extracted from longan (Dimocarpus longanLour.) pulp. The composition and rheological properties were determined by chemical analysis and dynamic shear rheometer. The flow behavior and viscoelastic behavior of longan polysaccharide (LP) solution were investigated by steady shear and small amplitude oscillatory shear (SAOS) experiments, respectively. The result shows that the solution is a pseudoplastic flow in a range of shear rate (1–100 s−1). The rheological behavior of LP was influenced by cations such as Na+and Ca2+. With an increase of apparent viscosity,G′andG′′were accompanied by addition of Na+and Ca2+.

2018 ◽  
Vol 61 (3) ◽  
pp. 1113-1120
Author(s):  
Ibrahim Denka Kariyama ◽  
Xiaodong Zhai ◽  
Binxin Wu

Abstract. This literature review was conducted on the physical and rheological properties of animal manure slurries and their applications. The review revealed the importance of these properties in the design of anaerobic treatment plants, pipe systems to transport slurries to treatment and storage units, and other applications and management of raw and treated slurries. The selection of pumping and mixing equipment and their power requirements, the flow behavior, mass, and heat transfer, the quality of mixing, pressure head loss, and other applications of manure slurries are affected by the physical and rheological properties. The review shows that manure slurries generally exhibit non-Newtonian pseudoplastic fluid behavior with a decreasing apparent viscosity as the shear rate increases and that the power law equation can successfully be used to describe the relationship between shear stress and shear rate, especially for low total solids concentrations. Keywords: Animal manure slurries, Apparent viscosity, Non-Newtonian pseudoplastic fluids, Power law equation, Rheological properties.


2021 ◽  
Vol 71 (3) ◽  
pp. 290-297
Author(s):  
Yucheng Peng ◽  
Changlei Xia ◽  
Brian Via

Abstract Interest in cellulose nanocrystal (CNC) recently has been growing significantly. Many applications have been developed for CNC and appropriate procedures to handle the CNC suspensions are critical for these applications. In this study, we explored a method evaluating CNC suspensions based on rheological property characterization. We used a rotational viscometer to characterize CNC suspensions at concentrations of 3, 4, 5, and 6 wt.%. We collected primary readings from the rotational viscometer, including spindle rotation speed and torque, to generate apparent viscosity and shear rate for CNC suspensions. We applied three different methods summarized from the literature to calculate apparent viscosity and real shear rate. We critically analyzed differences among calculation results from the three methods. Shearing thinning behaviors obeyed the power law flow model for all CNC suspensions in the shear rate tested. At different concentrations, consistency and flow behavior indices in the model differed in the measured shear rate range. With the same shear rate, higher concentration CNC suspension had a higher apparent viscosity. The apparent viscosity of the CNC suspension was associated with its weight concentration in a power law relationship. This study indicated that a rotational viscometer can be used as a quality control tool for characterizing the rheological properties of the CNC suspensions. We made recommendations for using appropriate calculation methods to obtain shear rate and apparent viscosity of CNC suspensions from the primary readings of a rotational viscometer under different situations.


2016 ◽  
Vol 19 (0) ◽  
Author(s):  
Pedro Henrique Santos ◽  
Luiza Helena Meller da Silva ◽  
Antônio Manoel da Cruz Rodrigues ◽  
José Antonio Ribeiro de Souza

Summary The aim of this study was to evaluate the rheological behavior of malay apple, a traditional Amazonian fruit with high bioactive properties, at different temperatures and soluble solids concentrations. The experiments were carried out in a Brookfield R/S Plus rheometer with concentric cylinders geometry. Power Law, Herschel-Bulkley, Mizrahi-Berk, and Sisko rheological models were fitted to the experimental data. The malay apple juice (pulp and skin) showed a pseudoplastic behavior for all temperatures and concentrations with flow behavior indexes lower than 1. The temperature effect on the samples’ apparent viscosity was analyzed by the Arrhenius equation. The activation energy increased with a decrease in the soluble solids concentration, showing that the lower the concentration, the greater the temperature influence on the apparent viscosity. The soluble solids effect was described by the exponential equation. The exponential factor increased with the temperature increasing, showing that the higher the temperature, the greater the effect of the soluble solids concentration on samples’ apparent viscosity. Finally, a triparametric mathematical model combining temperature, concentration, and shear rate was proposed aiming to evaluate its effects on the samples’ apparent viscosity and has accurately adjusted to the data with high correlation index R2.


2013 ◽  
Vol 816-817 ◽  
pp. 1274-1277 ◽  
Author(s):  
Kai Kai Guan ◽  
Fang Yi Li ◽  
Gang Li ◽  
Peng Liu ◽  
Jian Feng Li

The rheological behavior of slurry of foam cushion packaging based on fiber and starch was analyzed using digital viscosity meter. Meanwhile the response relationship of viscosity to time, shear rate to shear stress, and viscosity to temperature were also measured. The results showed that the slurry is a kind of non-newtonian fluid with the character of shear thinning. With the increasing of shear rate, apparent viscosity of system keeps in decreasing till the steady state finally. With temperature rising, plastic viscosity and yield strength of slurry will be smaller susceptibly. At last, Casson-Model was chose for the matching of plastic viscosity and yield strength.


Fluids ◽  
2018 ◽  
Vol 3 (4) ◽  
pp. 106 ◽  
Author(s):  
Francisco-José Rubio-Hernández

Rheology of a concrete is mainly controlled by the rheological behavior of its cement paste. This is the main practical reason for the extensive research activity observed during 70 years in this research subfield. In this brief review, some areas of the research on the rheological behavior of fresh cement pastes (mixture method influence, microstructure analysis, mineral additions influence, chemical additives influence, blended cements behavior, viscoelastic behavior, flow models, and flow behavior analysis with alternative methods) are examined.


2019 ◽  
Vol 823 ◽  
pp. 123-127
Author(s):  
Norifumi Miyanaga ◽  
Mitsumi Nihei ◽  
Jun Tomioka

This study describes the influence of flow properties of lithium soap greases on torque of small ball bearings. Three types of greases with different worked penetration were tested in this study. Their rheological properties are revealed by a cone plate type rheometer. Shear stresses under various shear rates are fitted with the Herschel-Bulkley equation. In addition, viscoelastic behaviors of the greases are measured by small amplitude oscillatory shear. The crossover stress that means the shear stress at G’=G” is obtained for the greases. Then, the bearing torque when three types of greases are used as a lubricant is measured. As the results, the grease with higher crossover stress shows the lower bearing torque regardless of that it has larger apparent viscosity. On the other hand, the grease with lower crossover stress shows the higher bearing torque regardless of that it has lower apparent viscosity. These results imply that the channeling state appears in the grease with higher crossover stress while the churning state appears in the grease with lower crossover stress.


2019 ◽  
Vol 33 (05) ◽  
pp. 1950014 ◽  
Author(s):  
A. Bindu Madhavi ◽  
S. Sreehari Sastry

Rheological properties of Cholesteryl n-valerate, Cholesteryl decanoate and Cholesteryl myristate which are esters of cholesterol have been studied. Phase transition temperatures and rheological parameters such as viscosity, elastic modulus G[Formula: see text], loss modulus G[Formula: see text] as functions of temperature, shear rate and time are investigated. In frequency sweep test, a higher transition crossover region has occurred for Cholesteryl myristate, whereas for Cholesteryl n-valerate a frequency-independent plateau prevailed for both the moduli. The occurrence of blue phase in Cholesteryl decanoate during temperature sweep measurements is an indication for the rheological support. The results for steady state have informed that cholesteric esters are having non-Newtonian flow behavior in their respective cholesteric phases. The power-law model has explained well the shear rate dependence of shear stress. A few practical applications of these esters as lubricant additives are discussed, too.


2015 ◽  
Vol 14 (2) ◽  
pp. 31 ◽  
Author(s):  
L. E. Silva ◽  
C. A. C. Santos ◽  
J. E. S. Ribeiro ◽  
C. C. Souza ◽  
A. M. S. Sant’Ana

Rheology attempts to define a relationship between the stress acting on a given material and the resulting deformation and/or flow that takes place. Thus, the knowledge of rheological properties of fluid materials such as vegetable oils generates auxiliary data that can be used in its storage and application. In this context, the aim of this study was to evaluate the rheological behavior of vegetable oils (cotton, canola, sunflower, corn and soybean) at different temperatures, using four rheological models (Ostwald- de-Waelle, Herschel-Bulkley, Newton and Bingham). The rheological properties were determined using a Thermo Haake rheometer with concentric cylinder geometry. Measurements were taken at 30, 45 and 60 °C by controlling the temperature using a thermostatic bath coupled to the equipment. The software Rheowin Pro Job Manager was used for process control and data record. The rheograms were obtained by measuring the values of shear stress varying the shear rate from 100 to 600 s-1 within 250 seconds. For the analysis of the apparent viscosity at different shear rates was applied simple linear regression until 2nd degree with the aid of SAS (SAS/Stat 9.2) program. The apparent viscosity data were submitted to analysis of variance and the averages were compared by Tukey test at 5% of probability. Higher temperatures of the samples were correlated to lower shear stress values, hence lower values for viscosity and consistency index were obtained, since it is known that the density and viscosity are highly sensitive to temperature and that the increase in temperature results in reduction of viscosity, benefiting the fluid flow. The models of Newton and Ostwald-de-Waelle were chosen to evaluate the rheological behavior of the samples, showing a good fit for the rheological data.


Polimery ◽  
2008 ◽  
Vol 53 (07/08) ◽  
pp. 507-512 ◽  
Author(s):  
BERENIKA HAUSNEROVA ◽  
NATALIE HONKOVA ◽  
ANEZKA LENGALOVA ◽  
TAKESHI KITANO ◽  
PETR SAHA

2006 ◽  
Vol 116-117 ◽  
pp. 601-605
Author(s):  
Heng Hua Zhang ◽  
Xian Nian Zhang ◽  
Guang Jie Shao ◽  
Luo Ping Xu ◽  
Yi Tao Yang ◽  
...  

The morphology of semi-solid alloy is one of the key influence factors on the rheological behavior of slurry during die filling and the mechanical properties of formed parts. However, it is difficult to study such effect due to hard controlling of morphology in semi-solid state. In this paper, a self-developed Searle-type viscometer was used to determine the rheological behavior of A356 aluminum alloy in different morphology, which was refined with the salts mixture of K2TiF6 and KBF4. The results indicated that the flow behavior of refined A356 alloy in the semi-solid state possesses obviously thixotropic behavior under isothermal shearing condition with less time to reach steady state and lower steady apparent viscosity as compared to that of the A356 alloy. During continuous cooling at a constant shearing rate, the apparent viscosity of refined A356 slurry in the same solid fraction decreased with the content of Ti. It is shown from quantitative image analysis that the primary α-Al grain in the refined alloy evolves from dendrites to rosettes or sphericitys, and then tends to be rounder and finer in higher Ti content. The mechanism of the influence of morphology on rheological behavior was also discussed in this paper.


Sign in / Sign up

Export Citation Format

Share Document