scholarly journals Development of a New Type of Alkali-Free Liquid Accelerator for Wet Shotcrete in Coal Mine and Its Engineering Application

2015 ◽  
Vol 2015 ◽  
pp. 1-14 ◽  
Author(s):  
Gang Zhou ◽  
Weimin Cheng ◽  
Sen Cao
Keyword(s):  
Compressive Strength ◽  
Raw Materials ◽  
Setting Time ◽  
Engineering Application ◽  
First Grade ◽  
Dust Concentration ◽  
National Standard ◽  
Initial Setting Time ◽  
Initial Setting ◽  
New Type

In order to address issues such as large rebound rate, high dust concentration, and low compressive strength of shotcrete when adding liquid accelerator during wet spraying, the factors influencing the efficiency of liquid accelerator were experimentally analyzed. The single-admixture, combination, and orthogonal tests were conducted on the five fundamental raw materials required to develop the new liquid accelerator. The WT-1 type liquid accelerator, which had better adaptability to different kinds of cement, was developed with the mass concentration ratio of 55% aluminum sulfate octadecahydrate, 4% sodium fluoride, 2.5% triethanolamine, 0.5% polyacrylamide, 5% bentonite, and 33% water. Experimental investigation showed that the initial setting time of the reference cement with 6% mass content of this liquid accelerator was 2 minutes and 15 seconds, and the final setting time was 7 minutes and 5 seconds. The compressive strength after 1 day of curing was 13.6 MPa and the strength ratio after 28 days of curing was 94.8%, which met the first grade product requirements of the China National Standard. Compared with the conventional type liquid accelerator, the proposed type WT-1 accelerator is capable of effectively reducing the rebound rate and dust concentration while significantly increasing the compressive strength of the shotcrete.

scholarly journals Preparation and Performance of a New-Type Alkali-Free Liquid Accelerator for Shotcrete

2017 ◽  
Vol 2017 ◽  
pp. 1-9
Author(s):  
Yanping Sheng ◽  
Bin Xue ◽  
Haibin Li ◽  
Yunyan Qiao ◽  
Huaxin Chen ◽  
...  
Keyword(s):  
Compressive Strength ◽  
Cement Paste ◽  
Cement Mortar ◽  
Retention Rate ◽  
Setting Time ◽  
Test Results ◽  
Initial Setting Time ◽  
Initial Setting ◽  
New Type ◽  
And Performance

A new type of alkali-free liquid accelerator for shotcrete was prepared. Specifically, the setting time and strength and shrinkage performance of two kinds of Portland cement with the accelerator were fully investigated. Moreover, the accelerating mechanism of alkali-free liquid accelerator and the hydration process of the shotcrete with accelerator were explored. Results show that alkali-free liquid accelerator significantly shortened the setting time of cement paste, where the initial setting time of cement paste with 8 wt% of the accelerator was about 3 min and the final setting time was about 7 min. Compressive strength at 1 day of cement mortar with the accelerator could reach 23.4 MPa, which increased by 36.2% compared to the strength of cement mortar without the accelerator, and the retention rate of 28-day compressive strength reached 110%. In addition, the accelerator still shows a good accelerating effect under low temperature conditions. However, the shrinkage rate of the concrete increased with the amount of the accelerator. 5~8% content of accelerator is recommended for shotcrete in practice. XRD and SEM test results showed that the alkali-free liquid accelerator promoted the formation of ettringite crystals due to the increase of Al3+ and SO42- concentration.

scholarly journals Effect of Calcium Nitrate on the Properties of Portland–Limestone Cement-Based Concrete Cured at Low Temperature

Materials ◽  
2021 ◽  
Vol 14 (7) ◽  
pp. 1611
Author(s):  
Gintautas Skripkiūnas ◽  
Asta Kičaitė ◽  
Harald Justnes ◽  
Ina Pundienė
Keyword(s):  
Compressive Strength ◽  
Cement Paste ◽  
Setting Time ◽  
Calcium Nitrate ◽  
Curing Temperature ◽  
Hardened Concrete ◽  
Cement Pastes ◽  
Initial Setting Time ◽  
Initial Setting ◽  
Early Strength

The effect of calcium nitrate (CN) dosages from 0 to 3% (of cement mass) on the properties of fresh cement paste rheology and hardening processes and on the strength of hardened concrete with two types of limestone-blended composite cements (CEM II A-LL 42.5 R and 42.5 N) at different initial (two-day) curing temperatures (−10 °C to +20 °C) is presented. The rheology results showed that a CN dosage up to 1.5% works as a plasticizing admixture, while higher amounts demonstrate the effect of increasing viscosity. At higher CN content, the viscosity growth in normal early strength (N type) cement pastes is much slower than in high early strength (R type) cement pastes. For both cement-type pastes, shortening the initial and final setting times is more effective when using 3% at +5 °C and 0 °C. At these temperatures, the use of 3% CN reduces the initial setting time for high early strength paste by 7.4 and 5.4 times and for normal early strength cement paste by 3.5 and 3.4 times when compared to a CN-free cement paste. The most efficient use of CN is achieved at −5 °C for compressive strength enlargement; a 1% CN dosage ensures the compressive strength of samples at a −5 °C initial curing temperature, with high early strength cement exceeding 3.5 MPa but being less than the required 3.5 MPa in samples with normal early strength cement.

scholarly journals Aplikasi Response Surface Methodology pada Optimasi Penambahan Blast Furnace Slag Terhadap Waktu Pengikatan dan Kuat Tekan Semen

2020 ◽  
Vol 4 (1) ◽  
pp. 61
Author(s):  
Hardjono Hardjono ◽  
Cucuk Evi Lusiani ◽  
Agung Ari Wibowo ◽  
Mochammad Agung Indra Iswara
Keyword(s):  
Compressive Strength ◽  
Response Surface Methodology ◽  
Blast Furnace ◽  
Response Surface ◽  
Blast Furnace Slag ◽  
Setting Time ◽  
Initial Setting Time ◽  
Initial Setting ◽  
Central Composite ◽  
Furnace Slag

Produksi semen setengah jadi (clinker) membutuhkan energi yang tinggi sehingga menggunakan batu bara dalam jumlah besar. Hal ini menyebabkan biaya produksi dari pabrik semen juga tinggi. Kebutuhan energi yang besar untuk menghasilkan clinker tersebut dapat dikurangi dengan menambahan blast furnace slag sebagai campuran pembuatan semen. Campuran clinker dapat menghasilkan produk semen yang memiliki waktu pengikatan dan kuat tekan sesuai SNI. Pengaruh penambahan blast furnace slag sebagai campuran clinker terhadap waktu pengikatan dan kuat tekan semen dapat dioptimalkan dengan response surface methodology (RSM) menggunakan Central Composite Design (CCD). Optimasi dengan menggunakan RSM bertujuan untuk mengetahui kondisi optimum pada penambahan blast furnace slag dan clinker terhadap variabel respon berupa waktu pengikatan awal, waktu pengikatan akhir, dan kuat tekan. Hasil uji ANOVA dan analisis response surface menunjukkan bahwa penambahan blast furnace slag sebagai campuran dalam pembuatan semen memberikan pengaruh yang signifikan terhadap waktu pengikatan awal, waktu pengikatan akhir, dan kuat tekan. Penambahan 5% blast furnace slag dengan 92,5% clinker pada campuran clinker dan gypsum merupakan kondisi optimum yang memberikan pengaruh signifikan terhadap variabel respon.The production of clinker consumes high energy and causes high production cost of cement industry. It can be reduced by adding blast furnace slag as a mixture in cement production. The blast furnace slag - clinker mixture can produce cement with setting time and compressive strength according to SNI. The effect of the addition of blast furnace slag as a clinker mixture to the setting time and compressive strength of cement can be optimized by response surface methodology (RSM) using Central Composite Design (CCD). Optimization by using RSM aims to determine the optimum condition of the blast furnace slag – clinker mixture to the initial setting time, final setting time, and compressive strength. ANOVA test results and response surface analysis show that the addition of blast furnace slag into the cement mixture has a significant influence on the initial setting time, final setting time, and compressive strength. The addition of  5% blast furnace slag with  92.5% clinker in the mixture of clinker and gypsum is the optimum condition which gives a significant effect on the response variable.

scholarly journals Analysis of the Influence of Crystalline Admixtures at Early Age Performance of Cement-Based Mortar by Electrical Resistance Monitoring

Materials ◽  
2021 ◽  
Vol 14 (19) ◽  
pp. 5705
Author(s):  
Rubén Beltrán Cobos ◽  
Fabiano Tavares Pinto ◽  
Mercedes Sánchez Moreno
Keyword(s):  
Compressive Strength ◽  
Thermogravimetric Analysis ◽  
Remote Monitoring ◽  
Electrical Resistance ◽  
Setting Time ◽  
Early Age ◽  
Resistance Monitoring ◽  
Initial Setting Time ◽  
Characterization Techniques ◽  
Initial Setting

Crystalline admixtures are employed for waterproofing concrete. This type of admixtures can affect the early age performance of cement-based mixes. The electrical resistance properties of cement have been related to the initial setting time and to the hydration development. This paper proposes a system for remote monitoring of the initial setting time and the first days of the hardening of cement-based mortars to evaluate the effect of the incorporation of crystalline admixtures. The electrical resistance results have been confirmed by other characterization techniques such as thermogravimetric analysis and compressive strength measurements. From the electrical resistance monitoring it has been observed that the incorporation of crystalline admixtures causes a delay in the initial setting time and hydration processes. The measurements also allow to evaluate the influence of the amount of admixture used; thus, being very useful as a tool to define the optimum admixture dosage to be used.

scholarly journals Preparation of Portland Cement with Gold Ore Tailings

2019 ◽  
Vol 2019 ◽  
pp. 1-9 ◽  
Author(s):  
Qiang Wang ◽  
Geng Yao ◽  
Xiangnan Zhu ◽  
Junxiang Wang ◽  
Peng Wu ◽  
...  
Keyword(s):  
Compressive Strength ◽  
Flexural Strength ◽  
Portland Cement ◽  
Raw Materials ◽  
Setting Time ◽  
Hydration Product ◽  
Difficult Problem ◽  
Initial Setting Time ◽  
Gold Ore ◽  
Curing Age

The disposal of gold ore tailings (GTs) has been a very difficult problem for a long time. Thus, this study explored a new approach to the management of GTs by preparing Portland cement. Physical properties, reaction mechanisms, and hydration product types of cement prepared with GTs (C-GTs) and ordinary Portland cement (C-SS) were compared. X-ray diffraction (XRD), thermogravimetric (TG), and scanning electron microscope energy-dispersive spectroscopy (SEM-EDS) analysis techniques were used to study the mineralogical phases of the clinker and raw materials, hydration product types, and microtopography. The consistency, setting time, flexural strength and compressive strength values of the cement samples (C-GTs and C-SS), and burnability of the raw materials were also studied. The burnability analysis indicated that GTs provided a higher reactivity. The XRD results showed that the clinker phases of the C-GTs were C3S, C2S, C3A, and C4AF. The XRD, TG, and SEM-EDS results showed that the hydration products were flaky calcium hydroxide, rod-shaped ettringite, and granular C-S-H gels. Its compressive strength and flexural strength were, respectively, 30.4 MPa and 6.1 MPa at the curing age of 3 days and 59.1 MPa and 9.8 MPa at the curing age of 28 days, which were slightly higher than those of the C-SS. Furthermore, the results showed that the consistency, initial setting time, and final setting time for the two kinds of cement were similar, which further suggested that GTs could be used to prepare Portland cement.

Study on the Anti-Static Desulphurization Gypsum Fiberboard

2013 ◽  
Vol 772 ◽  
pp. 156-160
Author(s):  
Yan Long Liu ◽  
Chao Fa Tang ◽  
Wen Hao Shen ◽  
Ji Wen Han ◽  
Hong Shuang Du
Keyword(s):  
Raw Materials ◽  
Setting Time ◽  
Market Demand ◽  
Initial Setting Time ◽  
Application Range ◽  
Dry Process ◽  
Biomass Resources ◽  
Initial Setting ◽  
Forestry Industry ◽  
Positive Effect

The fiber of the agriculture and forestry biomass resources and the processing residues is main raw materials as a reinforcing material, the calcinated calcium sulfate hemihydrates by industrial flue gas desulfurization waste is a binder, adding efficient composite retarder to increase the initial setting time of gypsum and meet the production process requirements, adding conductive carbon black to reduce system resistance gypsum fiber to produce and meet the requirements of antistatic products. By semi-dry process, we produced the retardant, waterproof, environmental friendly and anti-static desulfurization gypsum fiberboard. Desulfurization gypsum antistatic fiberboard can meet the market demand for functional products used widely in antistatic floor, antistatic wall panel etc. The production of anti-static desulfhurization gypsum fiberboard expands the application range of desulfhurization gypsum, at the same time, which changes the structure of the forestry industry and has a positive effect on improving the forestry economic operation quality, efficiency and international competitiveness.

Preliminary Study on Reaction of Fresh Concrete with Carbon Dioxide

2018 ◽  
Vol 382 ◽  
pp. 230-234
Author(s):  
Ming Ju Lee ◽  
Ming Gin Lee ◽  
Yung Chih Wang ◽  
Yu Min Su ◽  
Jia Lun Deng
Keyword(s):  
Carbon Dioxide ◽  
Compressive Strength ◽  
Fresh Concrete ◽  
Setting Time ◽  
Cement Matrix ◽  
Cement Ratio ◽  
Water Cement Ratio ◽  
Initial Setting Time ◽  
Initial Setting ◽  
Short Time

In order to let fresh concrete react with carbon dioxide sufficiently, the carbon dioxide was added to mixing concrete. The study used three water cement ratio (0.55, 0.65, 0.75), three CO2 pressures (0.2, 0.4, 0.6 MPa), and two CO2 concentration (50% and 100%) to make concrete samples, and observed the effect of carbon dioxide adsorption in the above parameters. Finally, the compressive strength and carbonation degree of concretes were tested after three curing time (7, 14 and 28 days). The research showed that concrete could be more efficient to absorb carbon dioxide by using this pressure method. The results found that the mixing concrete react with carbon dioxide in a short time, and shorten the initial setting time of concrete. But this method would greatly reduce the workability of concrete after mixing with carbon dioxide and it might be enhanced by water or superplasticizer. The bond of cement matrix might cut down after reacting with carbon dioxide. Based on the above, the compressive strength of concrete which was mixed with carbon dioxide would be impaired. The proposed CO2-mixing method has the capacity to uptake 9.5% carbon dioxide based on water cement ratio and CO2 pressure.

scholarly journals Development of a New Type of Green Switch Air Entraining Agent for Wet-Mix Shotcrete and Its Engineering Application

2016 ◽  
Vol 2016 ◽  
pp. 1-9 ◽  
Author(s):  
Guoming Liu ◽  
Lianjun Chen
Keyword(s):  
Silicone Oil ◽  
Fresh Concrete ◽  
Engineering Application ◽  
First Grade ◽  
National Standard ◽  
Trimethyl Ammonium Chloride ◽  
Mix Proportion ◽  
New Type ◽  
Conventional Type ◽  
Optimal Mixing

Air entraining agent (AEA) can bring a lot of microbubbles into fresh concrete for improving its fluidity; however, high fluidity has adverse effect on the shootability of wet-mix shotcrete. In order to solve the contradictory issue, the paper developed a new type of green switch air entraining agent (GSAE) that can improve both the pumpability and shootability. The single-admixture and combination tests containing foaming ability and surface tension were performed with Deer agitator and automatic tension meter. The new AEA was developed with two constituents A and B. A was prepared withSapindus mukorossi(S-1), dodecyl trimethyl ammonium chloride(1231), and polyacrylamide. B was prepared with lauryl sodium sulfate (K12) and silicone oil. The mass mix proportion was S-1 : 1231 : polyacrylamide : K12 : silicone oil = 1 : 0.33 : 0.2 : 0.33 : 0.47. The application method of GSAE proposed that A was premixed with fresh concrete and then B was added at nozzle. Experimental investigation showed that the optimal mixing amount of GSAE was 0.1%–0.2% relative to cement. All performance measured of wet-mix shotcrete with 0.12% GSAE met the first-grade product requirements of the China National Standard. Compared with the conventional type of AEA, the proposed GSAE is capable of effectively improving pumpability and shootability.

scholarly journals Research on application of high performance alkali-free liquid accelerator in shotcrete support

2020 ◽  
Vol 319 ◽  
pp. 08003
Author(s):  
Luchen Zhang ◽  
Xuena Jia ◽  
Guanjie Yang ◽  
Chaoqun Sun
Keyword(s):  
High Performance ◽  
Setting Time ◽  
Field Tests ◽  
Sprayed Concrete ◽  
Initial Setting Time ◽  
Active Aluminum ◽  
Initial Setting ◽  
New Type ◽  
Research On Application ◽  
Construction Efficiency

At present, sprayed concrete has problems such as low strength, large rebound amount, and high dust concentration. Developed a new type of alkali-free liquid accelerator, which can effectively improve the performance of shotcrete. The alkali-free liquid accelerator is mainly composed of aluminum sulfate, active aluminum hydroxide, alcohol amine, amide, and stabilizer. Through laboratory tests and field tests, when the alkali-free liquid accelerator admixture is 5% to 7%, the initial setting time is within 5 minutes, and the final setting time is within 10 minutes. The strength of shotcrete reaches 12.8MPa in one day, and the compressive strength ratio of 28d is more than 95.3%, and the rebound amount is within 10%. Compared with ordinary alkali-free liquid accelerator and alkaline liquid accelerator, the strength of sprayed concrete mixed with the alkali-free liquid accelerator is greatly improved, which is more conducive to the support of the sprayed layer, reduced rebound and dust, effectively improve the construction environment and increase construction efficiency.

Performances Study and Accelerating Mechanism Analysis of New-Type Alkali-Free Efficient Liquid Setting Accelerator

2014 ◽  
Vol 584-586 ◽  
pp. 1652-1658 ◽  
Author(s):  
Tong Wei Lu ◽  
Fei Xiao ◽  
Lei Guo ◽  
Gui Bo Gao
Keyword(s):  
High Performance ◽  
Setting Time ◽  
Aluminum Silicate ◽  
Mechanism Analysis ◽  
Initial Setting Time ◽  
Final Setting Time ◽  
Calcium Aluminates ◽  
Magnesium Aluminum Silicate ◽  
Initial Setting ◽  
New Type

This paper introduces a new-type alkali-free and chlorine-free high performance liquid accelerated admixture. The accelerated agent is mainly composed of the following components: fluoride magnesium aluminum silicate is main accelerator, alcohol amine polymer is activator, and amide polymer is stabilizer. When dosage of the admixture is greater than 4%, the cement initial setting time is less than 5 min, the final setting time is less than 10 min, and the 28 day compressive strength ratio of mortar is more than 100%. The mechanism is the accelerating of agent on hydration of C3A and C3S. There are large hydration calcium flu silicate (11CaO·4SiO2·CaF2) and hydration calcium aluminates at the later stage of hydration.

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