scholarly journals Effect of Multiwalled Carbon Nanotubes (MWNT) on the Properties of High Impact Polystyrene (HIPS)

2018 ◽  
Vol 2018 ◽  
pp. 1-5 ◽  
Author(s):  
Juan Li

The composites of HIPS/MWNT were prepared by melt blending. The effects of the content of MWNT on the flow, mechanical, and flame retardancy properties of the composites were investigated. The morphologies of fracture surfaces were characterized through scanning electron microscopy (SEM). And the thermal stability of the composites was studied by thermogravimetric analysis. The results show that the flow properties, the impact strength, the elongation at break, and the flame retardancy are improved with the proper addition of MWNT. The morphological behavior indicates the fracture surface of HIPS/MWNT is more roughness than that of HIPS. The addition of MWNT has little influence on the thermal stability of HIPS.

2011 ◽  
Vol 79 ◽  
pp. 282-287 ◽  
Author(s):  
Yi Chen ◽  
Guang Sheng Zeng ◽  
Ping Jiang ◽  
Wei Lu ◽  
Wei Long Huang

EVA was added into PC/PLA blends as a modifier for improving the impact strength of blends, and meanwhile the thermal properties and rheological properties of blends should also be influenced. PC/PLA/EVA blends were prepared by melt blending and the catalyst DBTO was added into the blends in blending process to catalyze the transesterification of PC and EVA for improving the compatibility of blends. The effects of blend composition and transesterification on the thermal and rheological properties of blends were investigated. The results showed that the addition of EVA could improve the crystallinity of PLA in PC/PLA/EVA blends but had little influence on the thermal stability of blends,and the transesterification was beneficial to both the crystallization of PLA and thermal stability of blends. The addition of EVA and the transesterification of PC and EVA increased the apparent viscosity of blends, while the apparent viscosity of blends decreased drastically and the pseudo-plasticity characteristic of blend melts was weakened obviously with increasing PLA content and rising temperature.


2011 ◽  
Vol 410 ◽  
pp. 47-50 ◽  
Author(s):  
Wichuda Chanprapanon ◽  
Nitinat Suppakarn ◽  
Kasama Jarukumjorn

Composites based on polypropylene (PP) and sisal fiber (SF) were prepared by melt blending. Sisal fiber content was 30 phr. Organoclay (OMMT; Cloisite®30B) (1-7 phr) was incorporated into the composites. In addition, maleic anhydride grafted polypropylene (MAPP) was used as a compatibilizer to enhance the interfacial adhesion between PP matrix and sisal fiber and also to improve the dispersion of the organoclay in PP matrix. The addition of OMMT had insignificantly affected mechanical properties of SF/PP composites. However, flame retardancy and thermal stability of SF/PP composites were improved dramatically with the presence of OMMT.


Materials ◽  
2021 ◽  
Vol 14 (7) ◽  
pp. 1805
Author(s):  
Kamila Mizera ◽  
Kamila Sałasińska ◽  
Joanna Ryszkowska ◽  
Maria Kurańska ◽  
Rafał Kozera

Due to the current trends in sustainable development and the reduction in the use of fossil fuels (Green Deal strategy and the circular economy), and thus, the increased interest of the polyurethane industry in polyols derived from renewable sources, it is important to study the impact of these polyols on the flammability of new bioelastomers. The goal of this study was to check the influence of biobased polyols, such as tall oil (TO)-based polyols, soybean oil (SO)-based polyol, and rapeseed oil (RO)-based polyol, on the reduction in the burning and fume emissions of polyurethane and poly(urea)urethane elastomers (EPURs and EPUURs). The thermal stability of these materials was tested using thermogravimetric analysis (TGA). In turn, the flame retardancy and smoke emissions were checked using a cone calorimetry test. The released gases were identified using TGA coupled with Fourier transform infrared (FT-IR) spectroscopy (TGA/FT-IR). Moreover, the morphological and structural characteristics of the char residues were characterized using FT-IR and scanning electron microscopy (SEM) with energy-dispersive spectroscopy (EDS). The obtained data were compared to the results received for elastomers produced with petroleum substrates. The addition of biobased polyols led to a reduction in the burning as a result of the formation of char, especially RO polyol. Moreover, the TO and RO polyols increased the thermal stability of the elastomers.


2013 ◽  
Author(s):  
Jr Morris ◽  
Shardo Robert W. ◽  
Higgins James ◽  
Cook Kim ◽  
Tanner Rhonda ◽  
...  

Cellulose ◽  
2020 ◽  
Vol 27 (17) ◽  
pp. 10473-10487
Author(s):  
Zheng Zhang ◽  
Dezheng Kong ◽  
Heng Sun ◽  
Ling Sun ◽  
Chaohong Dong ◽  
...  

2008 ◽  
Vol 17 (1) ◽  
pp. 096369350801700 ◽  
Author(s):  
Zdeno Špitalský ◽  
Alexander Kromka ◽  
Libor Matějka ◽  
Peter Černoch ◽  
Jana Kovářová ◽  
...  

The epoxy nanocomposites filled with 0.1, 0.5, and 1 wt% nanodiamonds (nanoD) were prepared and their properties were compared with neat epoxy network or epoxy nanocomposite filled with 1 wt% multiwalled carbon nanotubes (MWCNTs). The obtained nanoD-epoxy composites increased significantly thermal stability of prepared nanocomposites in comparison with neat epoxy matrix. The exponential decay of light transmittance with increasing concentration of nanoD in sample was observed. The values of storage modulus G` and glass transition temperature Tg significantly decreased by addition of nanoD to epoxy network. This is caused by inhibition of cross-linking reaction of epoxy- and amino- groups by nanoD.


Polymers ◽  
2019 ◽  
Vol 11 (2) ◽  
pp. 380 ◽  
Author(s):  
Wei Zhao ◽  
Yongxiang Li ◽  
Qiushi Li ◽  
Yiliang Wang ◽  
Gong Wang

The flame retardant modification of epoxy (EP) is of great signification for aerospace, automotive, marine, and energy industries. In this study, a series of EP composites containing different variations of phosphorus-containing polysulfone (with a phosphorus content of approximately 1.25 wt %) were obtained. The obtained EP/polysulfone composites had a high glass transition temperature (Tg) and high flame retardancy. The influence of phosphorus-containing compounds (ArPN2, ArPO2, ArOPN2 and ArOPO2) on the thermal properties and flame retardancy of EP/polysulfone composites was investigated by thermogravimetric analysis (TGA), differential scanning calorimetry (DSC), a UL-94 vertical burning test, and cone calorimeter tests. The phosphorus-containing polysulfone enhanced the thermal stability of EP. The more stable porous char layer, less flammable gases, and a lower apparent activation energy at a high degree of conversion demonstrated the high gas inhibition effect of phosphorus-containing compounds. Moreover, the gas inhibition effect of polysulfone with a P–C bond was more efficient than the polysulfone with a P–O–C bond. The potential for optimizing flame retardancy while maintaining a high Tg is highlighted in this study. The flame-retardant EP/polysulfone composites with high thermal stability broaden the application field of epoxy.


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