scholarly journals Determination of Physicochemical Parameters and Levels of Heavy Metals in Food Waste Water with Environmental Effects

2020 ◽  
Vol 2020 ◽  
pp. 1-9
Author(s):  
Jingxi Ma ◽  
Shuqing Wu ◽  
N. V. Ravi Shekhar ◽  
Supriya Biswas ◽  
Anoop Kumar Sahu

Bioinorganic chemistry is found as a sizzling field in today’s era. It deals with chemistry amongst the heavy metals with natural resources, i.e., air, soil, water, plant byproducts (foods), and environmental essences. The aim of this research is to determine the concentration of heavy metals present in the food waste water sample and to study the environmental effects of metal ion concentration. To conduct the research work, the physicochemical parameters and levels of five heavy metals of food waste water samples were collected from five sampling points of renowned hotels, restaurants, canteens, and confectionaries of a state of India and assessed using the standard analytical procedure. Sampling was carried out from January 2017 up to December 2017. The physicochemical parameters were determined such as pH, temperature, turbidity, conductivity, total dissolved solids, total suspended solids, total alkalinity, biological oxygen demand, chemical oxygen demand, dissolved oxygen, total organic carbon, sulphate, nitrate, and phosphate. The heavy metal concentration was determined by using the UV-spectrophotometer, and the results were compared with the standards prescribed by the WHO, BIS, ICMR, and municipal authorities. The results obtained in the physicochemical analysis revealed that a few parameters were found beyond limits, and the metal ion concentration (iron and zinc) results were found above the permissible limits set by the CPCB (Central Pollution Control Board), ICMR, BIS, and World Health Organization (WHO), most especially, effluent from point P1. It was concluded that all the effluents required further treatment before releasing them into the water body or land to prevent pollution. The obtained results reveal that waste water used for irrigation and farming of nearby areas and water drained from restaurant kitchens were considerably polluted and not suitable for aquatic organisms, irrigation, and agricultural purposes.

2016 ◽  
Vol 6 (12) ◽  
pp. 34-42 ◽  
Author(s):  
Idowu A. Aneyo ◽  
Funmilayo V. Doherty ◽  
Olumide A. Adebesin ◽  
Mariam O. Hammed

Background. Discharged effluents from industry have been responsible for the deterioration of the aquatic environment in many parts of the world, especially in developing countries. Increasing industrialization and urbanization have resulted in the discharge of large amounts of waste into the environment, resulting in high pollution loads. Utilization of microbes such as fungi and bacteria have been used for pollution degradation. Objectives. The aim of this research was to utilize microbial agents such as fungi and bacteria to reduce pollutant loads such as heavy metals in effluent samples. Methods. Three types of effluent (pharmaceutical, textile effluent, and dye) were obtained from Surulere in Lagos Metropolitan Area, Nigeria. Heavy metals analysis was carried out using a flame atomic adsorption spectrophotometer according to standard methods. Samples were cultured for microbes and identified. Bacteria samples were inoculated on nutrient agar and incubated at 37°C for 24 hours. Fungi counts were carried out using potato dextrose agar and incubated at 28°C for 3–5 days. The isolated organisms were identified based on their morphological and biochemical characteristics. Then 100 mL of the effluents was dispensed into 250 mL flasks, and the pH of the medium was adjusted to 7.2 by the addition of either sodium hydroxide or hydrogen chloride and autoclaved at 121°C for 15 minutes. The autoclaved flask was inoculated with 1 mL of bacteria and fungi for 21 days and pH was recorded properly every 48 hours. Results. The results of the physicochemical parameters indicated that conductivity, total suspended solids, total dissolved solids, turbidity, chemical oxygen demand and biochemical oxygen demand for all the three industrial effluents were higher than the World Health Organization (WHO) permissible limits. Heavy metal analysis results show that the effluents had high values for cadmium, above the WHO limit of 0.003 mg/L. Concentrations of zinc ranged from 0.136–1.690 mg/L, and nickel ranged between 0.004–0.037mg/L for the three effluents, within the WHO limit. The identified bacteria were Bacillus subtilis, Klebsiella pneumonia, Salmonella typhi and Bacillus cereus and isolated fungi were Aspergillus flavus and Penicillium chrysogenum. All the physicochemical parameters and heavy metal concentrations were reduced after the biodegradation study in the effluents. Conclusions. The responses observed in the various microbes indicated that the use of microbes for the reduction of environmental pollutants has an advantage over the use of other methods because it is environmentally friendly, low cost, and no new chemicals are introduced into the environment. This method should be encouraged for pollution reduction to bring about ecosystem sustainability advocated for Ghana.


Author(s):  
Waqar Ahmad ◽  
Arif Zubair ◽  
Haq Nawaz Abbasi ◽  
Muhammad Imran Nasir

This study was conducted to investigate the water quality of the Indus river, Sindh, Pakistan. A total of 41 locations were selected along the Indus river and its tributaries for the collection of surface water samples. Twenty-one physico-chemical parameters and heavy metals were analyzed and the data were interpreted through different statistical techniques. In the current study, eleven parameters including iron, copper, zinc, electrical conductivity (EC), total dissolved solids (TDS), pH, potassium, sodium, nitrate, sulfate, and chloride with an average value 0.13 mg/L, 0.04 mg/L, 0.16 mg/L, 733 µS/L, 211.2 mg/L, 7.6, 8.9 mg/L, 107.4 mg/L, 8.01 mg/L, 102 mg/L, 140 mg/L respectively and were within permissible limits set by the World Health Organization (WHO) for drinking water. Whereas, average values of cadmium, mercury, lead, total alkalinity (TA), chemical oxygen demand (COD), total hardness (TH) and turbidity were found 0.004 mg/L, 0.007 mg/L, 0.02 mg/L, 920 mg/L, 103 mg/L, 262 mg/L and 186.2 NTU respectively, higher than permissible limits. Pearson correlation matrix and cluster analysis were used to understand similarities and differences between variables. The variation in the correlation of different parameters shows the complexity of the water quality.    


2020 ◽  
Vol 6 (2) ◽  
pp. 23-28
Author(s):  
O. A. F Wokoma ◽  
◽  
O. S Edori ◽  

Wastewater samples were collected from an oil industry at the point of discharge for a period of two years, from January 2018 – December 2019. The wastewater samples were analyzed for different physicochemical parameters such as temperature, turbidity, total dissolved solids (TDS), total suspended solids (TSS), conductivity, pH, alkalinity, salinity, total hydrocarbon content (THC), biochemical oxygen demand (BOD) and chemical oxygen demand (COD) to examine their conformity to fulfill requirements as recommended by World Health Organization (WHO), Federal Ministry of Environment (FME) and Drinking Water Association (DWA). The results indicated that all the parameters in the discharged wastewater were within acceptable limits of the regulatory bodies. The field data showed that the investigated firm conformed to the law by carrying out proper procedures before discharging the effluents into the public drain and river. Therefore, the release of wastewater from the industry doesn't constitute a danger to the environment as well as aquatic organisms. Keywords: Physicochemical parameter, wastewater discharge, oil industry, environment, contaminants


2020 ◽  
Vol 24 (3) ◽  
pp. 511-517
Author(s):  
O.B. Ovonramwen

Physicochemical analyses of surface and groundwater samples from eleven different locations in Ugbomro and Iteregbi, Delta State, Nigeria were sampled and analyzed for physicochemical parameters according to standard methods for the examination of water and wastewater. The following  mean and standard deviation were obtained from the groundwater of the communities: temp (oC) 22.46 ± 0.50 and 23.23 ± 0.99, pH 6.63 ± 0.68 and6.69 ± 0.24, dissolved oxygen (DO) (mg/L) 5.91 ± 0.46 and 5.73 ± 0.46, chemical oxygen demand (COD) (mg/L) 4.24 ± 0.01 and 4.43 ± 0.10, biochemical oxygen demand (BOD) (mg/L) 3.51 ± 0.38 and 3.84 ± 0.21, Turbidity (NTU) 1.22 ± 1.07 and 3.56 ± 0.77, electrical conductivity (EC) (μs/cm) 748.9 ± 215.79 and 786.67 ± 226.77, color (TCU) 1.22 ± 2.12 and 6.11 ± 2.11, total alkalinity (TA) (mg/L) 6.22 ± 7.38 and 14.11 ± 11.19, HCO3- (mg/L) 6.22 ± 7.38 and 14.11 ± 11.19, NO3 - (mg/L) 1.13 ± 0.62 and 2.89 ± 1.25, total solids (TS) (mg/L) 489.09 ± 180.17 and 664.95 ± 373.37, total suspended solids (TSS) (mg/L) 32.25 ± 24.29 and 123.86 ± 82.79, total dissolved solids (TDS) (mg/L) 456.78 ± 163.73 and 542.20 ± 450.66, Cl- (mg/L) 21.20 ± 3.20 and 20.10 ± 3.89, total hardness (TH) (mg/L) 26.67 ± 22.83 and 46.78 ± 36.17, Na (mg/L) 1.26 ± 0.06 and 1.16 ± 0.04, K (mg/L) 0.04 ± 0.01 and 0.06 ± 0.03, Mg (mg/L) 4.32 ± 3.23 and 6.96 ± 5.49, Ca (mg/L) 8.68 ± 9.35 and 18.12 ± 13.71 respectively. The results obtained were subjected to statistical analysis and compared with the standard set by the Standards Organization of Nigeria (SON) and the World Health Organization (WHO) for water samples. Some of the parameters did not meet the standards, hence the need for treatment. The present physio-chemical analyses of surface and groundwater quality of the two neighboring university areas, Ugbomro and Iteregbi, were done to assess the environmental status of  the environment before socio-economic impacts. Keywords: physicochemical, surface water, groundwater, water quality


2020 ◽  
Vol 32 (4) ◽  
pp. 827-834
Author(s):  
Muhammad Towhid Moula ◽  
Ranjit K. Nath ◽  
Mh. Mosfeka Chowdhury ◽  
Md. Abu Bakar Siddique

Halda is an important river of Bangladesh, is now polluted in different ways through industrial, agricultural, domestic and sewage disposal. Increased anthropogenic activities have increased the potential pollution of the river and excessive pollutants may be toxic to humans and aquatic fauna. Presence of heavy metals in the river water causes perilous impact on the aquatic organisms. Hence, regular monitoring of pollution levels in the river is indispensable. In this study, we discuss about physico-chemical assessments of water quality parameters viz. pH, dissolve oxygen (DO), biochemical oxygen demand (BOD), chemical oxygen demand (COD), total solid (TS), total suspended solid (TSS), total dissolved substance (TDS), total alkalinity, turbidity, salinity, electrical conductivity (EC), hardness, chloride and heavy metals in the water of Halda river during rainy and winter seasons, at different points; sources of pollutants in water and their effects given starting from the early research until the current research.


1992 ◽  
Vol 26 (9-11) ◽  
pp. 2309-2312 ◽  
Author(s):  
J. S. D'Avila ◽  
C. M. Matos ◽  
M. R. Cavalcanti

The processes used to remove heavy metals from inorganic wastewater have in general low efficiency. The use of activated peat obtained by using a process similar to a cation exchange reaction increases the removal efficiency up to five times when compared with peat “in natura”. The main objective of this work is to show the fundamental mathematical model, governed by diffusion process and the algorithms utilized to design the batch and the continuous feed stirred tank reactors or in some cases a fixed bed reactor. The principal dimensions of these equipments are obtained from the knowledge of the activated peat's cation exchange capacity used in the process, and the main chemical characteristics of the heavy metal ion contained in the wastewater. Besides, two important parameters are also included: the ion concentration and the efficiency of the process obtained from laboratory kinetics experiments. For example Pb+2 is removed l:rom a wastewater at a concentration of 50g/m3 in five minutes or less, with an efficiency of 98%.


2016 ◽  
Vol 74 (7) ◽  
pp. 1644-1657 ◽  
Author(s):  
Mona El-Sayed ◽  
Gh. Eshaq ◽  
A. E. ElMetwally

In our study, Mg–Al–Zn mingled oxides were prepared by the co-precipitation method. The structure, composition, morphology and thermal stability of the synthesized Mg–Al–Zn mingled oxides were analyzed by powder X-ray diffraction, Fourier transform infrared spectrometry, N2 physisorption, scanning electron microscopy, differential scanning calorimetry and thermogravimetry. Batch experiments were performed to study the adsorption behavior of cobalt(II) and nickel(II) as a function of pH, contact time, initial metal ion concentration, and adsorbent dose. The maximum adsorption capacity of Mg–Al–Zn mingled oxides for cobalt and nickel metal ions was 116.7 mg g−1, and 70.4 mg g−1, respectively. The experimental data were analyzed using pseudo-first- and pseudo-second-order kinetic models in linear and nonlinear regression analysis. The kinetic studies showed that the adsorption process could be described by the pseudo-second-order kinetic model. Experimental equilibrium data were well represented by Langmuir and Freundlich isotherm models. Also, the maximum monolayer capacity, qmax, obtained was 113.8 mg g−1, and 79.4 mg g−1 for Co(II), and Ni(II), respectively. Our results showed that Mg–Al–Zn mingled oxides can be used as an efficient adsorbent material for removal of heavy metals from industrial wastewater samples.


2021 ◽  
Vol 5 (2) ◽  
pp. 112-116
Author(s):  
F., F. Akinola ◽  
M., O. Lasisi ◽  
B., S. Awe

Groundwater pollution has increased as a result of poor waste disposal practices in developing countries. The purpose of this study was to determine the levels of physicochemical parameters and heavy metal concentrations in order to investigate the impact of dumpsites on groundwater and soil quality in Erinfun community. Four (4) water samples were collected hand dug well and four (4) soil samples designated Ss1 to Ss4 were collected at distances of 10, 20, 30 and 40 m, respectively, away from the waste dumpsite. Physicochemical parameters and traces such as odour, colour, taste and temperature, as well as Biochemical Oxygen Demand, Chemical Oxygen Demand, Dissolve Oxygen, Total Dissolve Solid, pH, and chloride were measured in collected water samples. Collected soil samples were also analyzed for heavy metals such as Magnesium, Zinc, Iron, Chromium, and Lead. All the physical parameters of the water samples analysed were found not to be within the acceptable limit of World Health Organization and Nigerian Standard of Drinking Water Quality standards. The chemical constituents tested were within the acceptable limit of World Health Organization and Nigerian Standard of Drinking Water Quality except for the Biochemical Oxygen Demand, Chemical Oxygen Demand and Dissolve Oxygen of water samples 1 and 2, respectively. The concentration of trace metals in water sample test were within health limit except for Magnesium and Iron which has the highest concentrations in water sample 1 at 10 m away from dumpsite (61.00 mg/l and 0.46 mg/l). Consequently, open dumpsites are discouraged, and constructed standard landfills with appropriate monitoring guidelines are recommended.


Molekul ◽  
2008 ◽  
Vol 3 (1) ◽  
pp. 40 ◽  
Author(s):  
Kapti Riyani ◽  
Tien Setyaningtyas ◽  
Roy Andreas

Study about the use of active charcoal rice straws (AAJP) was done in order to decrease heavy metal ion on textile waste water by using photocatalyst AAJP/TiO2. Rice straws were gained from the Banyumas Regency and samples textile waste water from one of textile industry in Pemalang. This study was begun by the making of active charcoal from the rice straws, and then the modification of photocatalyst AAJP/TiO2 was done with the comparison 1:99, 2:98, 3:97, 4:96, 5:95. The test of heavy metal ion photoreduction was done with some parameters such as weight comparison (1:99, 2:98, 3:97, 4:96, 5:95), pH effect (2, 5, 7, 9, 13) and the effect of ray source (sun light and the UV lamp). Analysis of photocatalyst material used SEM and heavy metal ion concentration used AAS. Results show that optimum photocatalyst activity in weight comparison AAJP300oC / TiO2 (1:99) with decrease concentration was 65.02% for heavy metal ion, mean while AAJP700oC / TiO2 (3:97) with decreased concentration of heavy metal ion is 94.50%. Optimal process for heavy metal ion reduction occur at pH 2 with decreased concentration of heavy metal ion for AAJP300oC / TiO2 (1:99) is 99.87% and for AAJP700oC /TiO2 (3:97) is 100%. The source of UV lamp was good for heavy metal ion photoreduction (AAJP300oC/TiO2(1:99) was 99.87% and AAJP700oC/TiO2 (3:97) was 100%)


2020 ◽  
Vol 32 (4) ◽  
pp. 876-880
Author(s):  
Maninder Singh ◽  
D. P. Tiwari ◽  
Mamta Bhagat

The indiscriminate discharge of heavy metals into water and soil from anthropogenic practices is becoming prominent threat to the environment. Heavy metals like chromium, cadmium, lead, arsenic, nickel etc. are heavily toxic and carcinogenic in nature. This study emphasizes the adequacy of activated water chest nut (Trapa natans) peel powder as a new adsorbent material for removal of chromium(VI) metal ions. Adsorption experiments were performed in batch process. Various process parameters like contact time, temperature, solution pH, dose of adsorbent, metal ion concentration etc. were optimized. The physico-chemical properties of adsorbent material were characterized by FTIR and XRD. The morphology, topology of adsorbent surface was characterized by scanning electron microscopy (SEM) and Brunauer, Emmett and Teller (BET) which revealed a highly porous structure and available specific surface area. The adsorption capacity (maximum) was counted as 59.17 mg/g and specific surface area was found 23.467 m2/g at a pH 7. The adsorption process for Cr(VI) ions was in a good agreement with Langmuir isotherm. The process also followed pseudo second order kinetics. The obtained result shows that activated water chest nut (Trapa natans) peel powder (AWCPP) can be a hopeful low-cost and eco-friendly bio-adsorbent for removal of Cr(VI) metal ions and also better adsorbent than other various reported adsorbents.


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