scholarly journals Effect of Graphene Oxide-Boron Nitride-Based Dual Fillers on Mechanical Behavior of Epoxy/Glass Fiber Composites

2021 ◽  
Vol 2021 ◽  
pp. 1-10
Author(s):  
V. Kavimani ◽  
P. M. Gopal ◽  
B. Stalin ◽  
Alagar Karthick ◽  
S. Arivukkarasan ◽  
...  

Graphene and its derivatives have excellent properties such as high surface area, thermal, and mechanical strength, and this fact made the researchers promote them as the possible filler material for fiber-matrix composite. The current research deals with validation on the effect of graphene oxide boron nitride filler over mechanical and thermal stability of epoxy glass fiber polymer matrix composite. The objective of this experimental investigation is to develop glass fiber reinforced polymer composites with hybrid filler addition. The matrix material selected is epoxy resin, whereas the glass fiber is selected as reinforcement, while boron nitride and graphene oxide are chosen as fillers. Compression moulding methodology is followed to develop the composites with the constant percentage of fiber loading, graphene oxide filler, and varying boron nitride content from 0 to 3 wt.% at an equal interval of 1 wt.%. The developed composite is analyzed for mechanical properties, and the fractured surface is analyzed through the scanning electron microscope. The addition of hybrid fillers enhances the fiber-matrix bonding strength and improves the thermal and mechanical properties up to a specific limit. Thermal gravimetric analysis was conducted to understand the thermal behavior of composite. The results revealed that the addition of filler improved the thermal stability of the composites.

Nanomaterials ◽  
2018 ◽  
Vol 9 (1) ◽  
pp. 15 ◽  
Author(s):  
Yongsheng Zhang ◽  
Jun Ma ◽  
Yao Bai ◽  
Youwei Wen ◽  
Na Zhao ◽  
...  

Petroleum depletion and climate change have inspired research on bio-based polymers and CO2 capture. Tung-oil-based polyols were applied to partially replace polyether-type polyols from petroleum for sustainable polyurethane. Tung-oil-based polyurethane (TBPU), was prepared via a two-step polycondensation, that is, bulk prepolymerization and chain extension reaction. The graphene oxide (GO) was prepared via Hummer’s method. Then, TBPU was composited with the GO at different ratios to form a TBPU/GO hybrid film. The GO/TBPU films were characterized by fourier transform infrared spectroscopy (FTIR), differential scanning calorimeter (DSC), thermal gravimetric analysis (TGA) and scanning electron microscope (SEM), followed by the measurement of mechanical properties and gas permeability. The results showed that the addition of tung-oil-based polyols enhanced the glass transition temperature and thermal stability of TBPU. The mechanical properties of the hybrid film were significantly improved, and the tensile strength and elongation at break were twice as high as those of the bulk TBPU film. When the GO content was higher than 2.0%, a brittle fracture appeared in the cross section of hybrid film. The increase of GO content in hybrid films improved the selectivity of CO2/N2 separation. When the GO content was higher than 0.35%, the resulting GO agglomeration constrained the gas separation and permeation properties.


2014 ◽  
Vol 6 (2) ◽  
pp. 1122-1134 ◽  
Author(s):  
Mokhtar Hemdan Abd El-Salam

Due to the light weight, high specific strength and non hazardous nature of bamboo fiber, it is preferred over synthetic fibers in composite materials for a wide range of applications such as automotive industry and including household sectors. As was noticed, little attention has been given to the effect of bamboo powder on the mechanical properties of rubber composites. Hence, an attempt has been made in this paper to the study the effect of loading and particle size of bamboo powder on the mechanical properties of EPDM composites. Thermo-gravimetric analysis (TGA) was carried out to study the thermal stability of composites. Results indicated that the thermal stability of EPDM was further improved with increasing in bamboo loading and decreasing in particle size. The stress- strain curves of the composites were studied and fitted according toOgden’s model. Mechanical parameters for the studied composites were improved with increasing bamboo loading. Besides, properties such as rupture stress, and internal friction were found to be maximum for composites containing certain content of bamboo powder, depending upon its particle size. Moreover, composites containing the smallest particle size of powder, at all levels of bamboo loading, showed mechanical properties superior to all other composites. From the dynamic mechanical measurements, the dynamic modulus, internal friction, and thermal diffusivity were calculated. The observed variations were explained in view of the role played by both the loading level and the particle size of bamboo powder. These findings were supported by scanning electron microscopy (SEM) micrographs.


Nanomaterials ◽  
2018 ◽  
Vol 8 (11) ◽  
pp. 940 ◽  
Author(s):  
Mualla Öner ◽  
Gülnur Kızıl ◽  
Gülşah Keskin ◽  
Celine Pochat-Bohatier ◽  
Mikhael Bechelany

The thermal and mechanical properties of poly(3-hydroxybutyrate-co-3-hydroxyvalerate, PHBV) composites filled with boron nitride (BN) particles with two different sizes and shapes were studied by scanning electron microscopy (SEM), differential scanning calorimetry (DSC), X-ray diffraction (XRD), Fourier Transform Infrared Spectroscopy (FTIR), thermal gravimetric analysis (TGA) and mechanical testing. The biocomposites were produced by melt extrusion of PHBV with untreated BN and surface-treated BN particles. Thermogravimetric analysis (TGA) showed that the thermal stability of the composites was higher than that of neat PHBV while the effect of the different shapes and sizes of the particles on the thermal stability was insignificant. DSC analysis showed that the crystallinity of the PHBV was not affected significantly by the change in filler concentration and the type of the BN nanoparticle but decreasing of the crystallinity of PHBV/BN composites was observed at higher loadings. BN particles treated with silane coupling agent yielded nanocomposites characterized by good mechanical performance. The results demonstrate that mechanical properties of the composites were found to increase more for the silanized flake type BN (OSFBN) compared to silanized hexagonal disk type BN (OSBN). The highest Young’s modulus was obtained for the nanocomposite sample containing 1 wt.% OSFBN, for which increase of Young’s modulus up to 19% was observed in comparison to the neat PHBV. The Halpin–Tsai and Hui–Shia models were used to evaluate the effect of reinforcement by BN particles on the elastic modulus of the composites. Micromechanical models for initial composite stiffness showed good correlation with experimental values.


2010 ◽  
Vol 139-141 ◽  
pp. 129-132
Author(s):  
Dong Fang Li ◽  
Li Li ◽  
Jian Zhang Li

Wood plastic composite (WPC) is very useful new material in the modern society. Improving the interfacial bond strength between wood and plastic is the foundation of improving the properties of WPC. Ethylene vinyl acetate (EVA) was used as the coupling agent of WPC in this study. Thermo-gravimetric analysis (TGA) was employed to study the thermal stability of wood flour modified by EVA. The modulus of rupture (MOR), the modulus of elasticity (MOE), and the tensile strength of WPC were investigated to understand the effects of the vinyl acetate (VA) content and the melt index of EVA on WPC. The results show that EVA could improve the thermal stability of wood flour and the mechanical properties of WPC. The mechanical properties of WPC are increasing with VA content raise and melt index reducing.


2021 ◽  
Author(s):  
Joong Tark Han ◽  
Joon Young Cho ◽  
Jeong Hoon Kim

The thermal stability of solution-exfoliated graphene oxide (GO) in air is one of the most important physical properties influencing its potential applications. To date, majority of the GO prepared by...


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