scholarly journals Comparison Study of Manometric Respirometric Test and Common Chemical Methods in the Determination ofBOD7in a Pulp and Paper Mill's Wastewaters

Author(s):  
Katri Roppola ◽  
Toivo Kuokkanen ◽  
Hannu Nurmesniemi ◽  
Jaakko Rämö ◽  
Risto Pöykiö ◽  
...  

The biological oxygen demand (BOD) test is widely used in many wastewater treatment plants. The conventional BOD tests are usually time-consuming and the results are often out of date for process control purposes. The aim of this research was to compare the manometric respirometric test with common chemical methods in the determination of BOD of wastewater from a pulp and paper mills as well as to evaluate theBOD7values of both wastewaters from the short-term respirometric measurements. The results showed that there were differences in theBOD7values of paper mill samples measured by conventional and respirometric methods. The main cause was found to be the dilution solution used in the conventional BOD tests. Using the same mineral solution in the respirometric measurements diminished the difference remarkably. Evaluation of theBOD7value after two or three days incubation was proved to work very well and the estimated results were close to measured values (deviations 1%–12%).

2007 ◽  
Vol 2007 ◽  
pp. 1-4 ◽  
Author(s):  
Katri Roppola ◽  
Toivo Kuokkanen ◽  
Jaakko Rämö ◽  
Hanna Prokkola ◽  
Eeva Heiska

The aim of this research was to study the suitability of a manometric respirometric test (OECD 301F) for the determination of biological oxygen demand (BOD) in domestic wastewater. This was done by comparing four different BOD tests (a manometric respirometric test, oxygen sensor determination, iodometric titration, and UV absorption measurement) and by evaluating the BOD7value after a short-term measurement applying the manometric respirometric test. Measurements were done in three dif-ferent laboratories. The respirometric test was performed well on municipal sewage, and the precision of results was good. There were minor deviations between BOD7values as determined by the different methods, but the deviations were not essentially big enough to have a practical impact. Evaluation of the BOD7value after two or three days' incubation by the respirometric method was shown to work well; average deviations between measured and evaluated values after three days' incubation were 5–18%. Hence, the manometric respirometric test proved to be a rapid and suitable tool for process control purposes.


2018 ◽  
Vol 10 (1) ◽  
pp. 367-374 ◽  
Author(s):  
Sangeeta Madan ◽  
Preeti Sachan ◽  
Utkarsh Singh

At present, a large amount of water required for paper production and various chemicals has been identified in effluents, which is produced at different steps of paper making in paper mills. The pulp and paper industry is typically related to pollution difficulties related to high biological oxygen demand (BOD), chemical oxygen demand (COD), colour, suspended solids, lignin and chlorinated compounds. Several studies have been made on eliminate these difficulties of pulp and paper effluents, the problem still continues. Although the physical and chemical methods are on the track of treatment, they are not on par with biological treatment because of cost ineffectiveness and residual effects. The biological treatment is known to be effective in reducing the organic load and toxic effects of paper mill effluents. Some microorganisms including bacteria and fungi have been involved in degrading the chemicals present in pulp and paper mill effluent. This article is an overview of the attempts made by several researchers worldwide to use biotechnological methods for degradation of the toxic compounds present in pulp and paper mill effluents by using fungi, bacteria, algae and enzymes. The current study clearly shows that application of native dominant bacterial and fungal isolates may be used forthe treatment of large pulp and paper mills effluents.


2014 ◽  
Vol 33 (1) ◽  
Author(s):  
Konstantin Bogolitsyn ◽  
Maria Gusakova ◽  
Nina Samsonova ◽  
Natalia Selivanova ◽  
Alexsandra Pochtovalova

AbstractThe first part of this investigation studied complex nature of chemical oxygen demand (COD ) parameter on local and overall effluents, which were obtained from two pulp and paper mills, located in the Northwest region of Russia. Contribution of individual compounds and fractions of matters having different chemical nature to COD for these effluents was established. The second part of this study shows that, qualitative and quantitative characteristics of priority pollutants and their contribution to COD for different pulp and paper mills are not the same, though these mills use similar technologies and produce similar products.


2012 ◽  
Vol 2012 ◽  
pp. 1-7 ◽  
Author(s):  
Virendra Kumar ◽  
Purnima Dhall ◽  
Rita Kumar ◽  
Yogendra Prakash Singh ◽  
Anil Kumar

Small-scale agro-based pulp and paper mills are characterized as highly polluting industries. These mills use Kraft pulping process for paper manufacturing due to which toxic lignified chemicals are released into the environment. Lack of infrastructure, technical manpower, and research and development facilities restricts these mills to recover these chemicals. Therefore, the chemical oxygen demand (COD) of the emanating stream is quite high. For solving the above problem, four bacteria were isolated from the premises of agro-based pulp and paper mill which were identified as species ofPseudomonas, Bacillus, Pannonibacter, andOchrobacterum. These bacteria were found capable of reducing COD up to 85%–86.5% in case of back water and 65-66% in case of back water : black liquor (60 : 40), respectively, after acclimatization under optimized conditions (pH 6.8, temperature 35°C, and shaking 200 rpm) when the wastewater was supplemented with nitrogen and phosphorus as trace elements.


2012 ◽  
Vol 10 (1) ◽  
pp. 127-136 ◽  
Author(s):  
Marjana Simonič ◽  
Doroteja Vnučec

AbstractA study using coagulation-flocculation and ultrafiltration (UF)methods for pulp and paper mills’ wastewater (WW)was carried out. The reduction efficiencies of turbidity and chemical oxygen demand (COD), the removal efficiency of total suspended solids (TSS) and absorbance at 254 nm were the main evaluating parameters. Using coagulation-flocculation, the efficiencies of alum and polyaluminum chloride (PACl)were studied, when used alone and when coupled with flocculant aids. During the coagulation-flocculation process, use of a single coagulant, the coagulant dosage, and the pH, play an important role in determining the coagulation efficiency. At the optimum PACl dosage of 840 mg L−1 and optimum pH of 9.0, turbidity reduction was found to be 94.5%. A combination of inorganic coagulant and flocculant, or polymer was applied, in which PACl was used coupled with the polyelectrolytes Organopol WPB20 and WPB40. PACl coupled with Organopol WPB20 by optimal pH 9 gave a 98.3% reduction of turbidity, 91.9% removal of TSS, and a 60.2% reduction in COD. Ultrafiltration trials were carried out on a pilot scale. A tubular module was used with ceramic membrane. This membrane is a multi-channel membrane with an active surface layer made of Al2O3 and ZrO2. Within the acidic range, the turbidity and TSS were removed at above 99%.


2018 ◽  
Vol 10 (2) ◽  
pp. 695-704 ◽  
Author(s):  
Shaveta Kakkar ◽  
Anju Malik ◽  
Sanjeev Gupta

In the present review, the suitability of adsorption process using low cost adsorbent for the treatment of pulp and paper mill effluent has been discussed. It is clear that adsorption processes are appropriate for the removal of recalcitrant compounds such as surfactants and pesticides, among others biodegradable or non-biodegradable compound present in pulp and paper mills effluents. The importance of the  adsorption is to improvement of the  removal of various physico- chemical (biological oxygen demand (BOD), chemical oxygen demand (COD), colour, suspended solids, lignin), heavy metals (Cu, Cr, Fe, Zn, Ni and Mn etc) organochlorine compounds, all recalcitrant pollutant, reduce toxicity, enhance colour removal by using different cost effective adsorbents. The effective use of the different adsorbents developed from different adsorbent media such as activated carbon, agriculture by product and industrial wastes and sludge as adsorbents  for the removal of different pollutants from the various processes and operations of pulp and paper mill as potential alternatives to different treatment process and received widespread attention. Adsorption necessity is a novel treatment option to improve the efficiency of removal within the discharge limits of wastewaters into the receiving bodies without causing any damage of the environment. However, still there is a need to find out the practical usefulness of such low cost adsorbent at industrial scale with the special reference to metals.


Cerâmica ◽  
2018 ◽  
Vol 64 (371) ◽  
pp. 311-317 ◽  
Author(s):  
L. Simão ◽  
N. J. Lóh ◽  
D. Hotza ◽  
F. Raupp-Pereira ◽  
J. A. Labrincha ◽  
...  

Abstract Industrial wastes from pulp and paper mills are potentially useful materials to use as alternative materials in clinker production. In this study, eco-friendly clinkers were obtained using only waste as feedstock. Eco-friendly clinker with different C3S and C2S contents were produced and hydrated for 7 days at 40 °C, or for 28 and 90 days at room temperature. The potentialities of these waste and the products obtained were revealed through chemical (XRF), thermal (DTA/TG) and surface area (BET) analysis. For comparison, a common ordinary Portland cement (OPC) was tested. As expected, the hydration rate of formulations presenting higher C3S content was higher, generating higher amounts of Ca(OH)2. Furthermore, the amount of Portlandite formed was lower when compared to OPC.


RSC Advances ◽  
2017 ◽  
Vol 7 (16) ◽  
pp. 9754-9763 ◽  
Author(s):  
Bholu Ram Yadav ◽  
Anurag Garg

The present study reports the performance of catalytic wet oxidation (CWO) for the treatment of simulated pulping effluents (with chemical oxygen demand (COD) = 15 000 and 17 000 mg L−1) from large and small scale pulp and paper mills, respectively.


1990 ◽  
Vol 22 (5) ◽  
pp. 189-194 ◽  
Author(s):  
V. V. Cibulić

The results of investigations into the effects of wastewaters from pulp and paper production on the River Sava are presented in this paper. Two situations were studied, i.e., when the treatment plant was in operation and when it was not working. The results of the investigations indicated that the wastewaters had significant effects on the Sava. Chemical oxygen demand (COD) and biochemical oxygen demand (BOD) were increased and some toxic substances were present at high concentrations, e.g., phenols, oils and grease, dyestuff, etc. The negative influence of the wastewaters was greater during the summer, at low water levels in the Sava. The Sava is a tributary of the River Danube, into which the pollution from this river finally flows. Regardless of the water flow rates, toxic substances are constantly accumulating, and, as a result, even such large systems as the Danube and the Sava are becoming more and more polluted.


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