Experimental Study of Interaction of Laser Radiation with Silver Nanoparticles in SiO2 Matrix

2006 ◽  
Vol 6 (3) ◽  
pp. 748-755 ◽  
Author(s):  
M. Sendova ◽  
M. Sendova-Vassileva ◽  
J. C. Pivin ◽  
H. Hofmeister ◽  
K. Coffey ◽  
...  
Keyword(s):  
Silver Nanoparticles ◽  
Photoelectron Spectroscopy ◽  
Chemical Characterization ◽  
Laser Wavelength ◽  
Sio2 Matrix ◽  
Transmission Electron Microscopy Micrographs ◽  
X Ray ◽  
Force Microscopy ◽  
Atomic Force ◽  
Transmission Electron

Thin films of silica containing silver nanoparticles were deposited by magnetron co-sputtering followed by thermal annealing in air or Ar + 2% H2. Laser fragmentation of the particles was carried out at two different wavelengths. The films were characterized by UV-VIS absorption spectroscopy and plasmon resonance numerical modeling based on the Mie theory, together with Rutherford backscattering elemental analysis, X-ray photoelectron spectroscopy chemical characterization, combined with statistical analysis of the transmission electron microscopy micrographs, and surface topography study by atomic force microscopy. It is demonstrated that the fragmentation is a result of a thermal process and its mechanism does not depend on the laser wavelength as long as the laser light is absorbed by the silver particles. Laser treatment with moderate fluences does not alter the precipitated metal content while fragmenting the particles. TEM study indicates that laser assisted silver particle modification can serve as a method for narrowing the particle size distribution.

Curcumin delivery by modified biosourced carbon-based nanoparticles

Nanomedicine ◽  
2022 ◽  
Author(s):  
Hossein Danafar ◽  
Marziyeh Salehiabar ◽  
Murat Barsbay ◽  
Hossein Rahimi ◽  
Mohammadreza Ghaffarlou ◽  
...  
Keyword(s):  
Photoelectron Spectroscopy ◽  
Free System ◽  
X Ray ◽  
Force Microscopy ◽  
Atomic Force ◽  
Transmission Electron ◽  
Good Biocompatibility ◽  
Drug Free ◽  
Mcf 7 ◽  
Carbon Based

Aim: To prepare a novel hybrid system for the controlled release and delivery of curcumin (CUR). Methods: A method for the ultrasound-assisted fabrication of protein-modified nanosized graphene oxide-like carbon-based nanoparticles (CBNPs) was developed. After being modified with bovine serum albumin (BSA), CUR was loaded onto the synthesized hybrid (labeled CBNPs@BSA–CUR). The structure and properties of the synthesized nanoparticles were elucidated using transmission electron microscopy (TEM), atomic force microscopy (AFM), ultraviolet-visible spectroscopy (UV-Vis), Fourier-transform infrared spectroscopy (FTIR) and x-ray photoelectron spectroscopy (XPS) methods. Results: CBNPs@BSA–CUR showed pH sensitivity and were calculated as controlled CUR release behavior. The drug-free system exhibited good biocompatibility and was nontoxic. However, CBNPs@BSA–CUR showed acceptable antiproliferative ability against MCF-7 breast cancer cells. Conclusion: CBNPs@BSA–CUR could be considered a highly promising nontoxic nanocarrier for the delivery of CUR with good biosafety.

Electroless Synthesis of 1.4 nm Pd and Pt Nanoparticles on Self-Assembled Rosette Nanotubes

2011 ◽  
Vol 1301 ◽  
Author(s):  
Rahul Chhabra ◽  
Hicham Fenniri
Keyword(s):  
Electron Microscopy ◽  
Photoelectron Spectroscopy ◽  
Pt Nanoparticles ◽  
Hierarchical Organization ◽  
X Ray ◽  
Force Microscopy ◽  
Rosette Nanotubes ◽  
Atomic Force ◽  
Transmission Electron ◽  
Self Assembled

ABSTRACTElectroless synthesis and hierarchical organization of 1.4 nm Pd and Pt nanoparticles (NPs) on self-assembled Rosette Nanotubes (RNTs) is described. The nucleated NPs are nearly monodisperse and reveal supramolecular organizations guided by RNT templates. Interestingly, the narrow size distribution is attributable to unique templating behavior of RNTs. The resulting metal NP-RNT composites were characterized by Atomic Force Microscopy (AFM), Scanning Electron Microscopy (SEM) and Transmission Electron Microscopy (TEM). X-ray Photoelectron Spectroscopy (XPS) was also performed to confirm the nature and composition of RNT-templated NPs.

Carbon nanotubes and metalloporphyrins and metallophthalocyanines-based materials for electroanalysis

2012 ◽  
Vol 16 (07n08) ◽  
pp. 713-740 ◽  
Author(s):  
José H. Zagal ◽  
Sophie Griveau ◽  
Mireya Santander-Nelli ◽  
Silvia Gutierrez Granados ◽  
Fethi Bedioui
Keyword(s):  
Electron Microscopy ◽  
Carbon Nanotubes ◽  
Hybrid Materials ◽  
Photoelectron Spectroscopy ◽  
State Of The Art ◽  
X Ray ◽  
Force Microscopy ◽  
Atomic Force ◽  
Transmission Electron ◽  
Walled Carbon Nanotubes

We discuss here the state of the art on hybrid materials made from single (SWCNT) or multi (MWCNT) walled carbon nanotubes and MN4complexes such as metalloporphyrins and metallophthalocyanines. The hybrid materials have been characterized by several methods such as cyclic voltammetry (CV), scanning electron microscopy (SEM), transmission electron microscopy (TEM), X-ray photoelectron spectroscopy (XPS), atomic force microscopy (AFM) and scanning electrochemical microscropy (SECM). The materials are employed for electrocatalysis of reactions such as oxygen and hydrogen peroxide reduction, nitric oxide oxidation, oxidation of thiols and other pollutants.

scholarly journals Ultrashort Pulsed Laser Ablation of Magnesium Diboride: Plasma Characterization and Thin Films Deposition

2015 ◽  
Vol 2015 ◽  
pp. 1-9 ◽  
Author(s):  
Angela De Bonis ◽  
Agostino Galasso ◽  
Antonio Santagata ◽  
Roberto Teghil
Keyword(s):  
Electron Microscopy ◽  
Photoelectron Spectroscopy ◽  
Optical Emission ◽  
Silicon Substrates ◽  
X Ray Diffraction ◽  
Laser Target ◽  
X Ray ◽  
Force Microscopy ◽  
Atomic Force ◽  
Transmission Electron

A MgB2target has been ablated by Nd:glass laser with a pulse duration of 250 fs. The plasma produced by the laser-target interaction, showing two temporal separated emissions, has been characterized by time and space resolved optical emission spectroscopy and ICCD fast imaging. The films, deposited on silicon substrates and formed by the coalescence of particles with nanometric size, have been analyzed by scanning electron microscopy, atomic force microscopy, X-ray photoelectron spectroscopy, micro-Raman spectroscopy, and X-ray diffraction. The first steps of the films growth have been studied by Transmission Electron Microscopy. The films deposition has been studied by varying the substrate temperature from 25 to 500°C and the best results have been obtained at room temperature.

scholarly journals Facile Synthesis of Highly Conductive Vanadium-Doped NiO Film for Transparent Conductive Oxide

2020 ◽  
Vol 10 (16) ◽  
pp. 5415
Author(s):  
Ashique Kotta ◽  
Hyung Kee Seo
Keyword(s):  
Electron Microscopy ◽  
Nickel Oxide ◽  
Photoelectron Spectroscopy ◽  
Transparent Conductive Oxide ◽  
X Ray ◽  
Force Microscopy ◽  
Atomic Force ◽  
Transmission Electron ◽  
Conductive Oxide ◽  
P Type

Metal-oxide-based electrodes play a crucial role in various transparent conductive oxide (TCO) applications. Among the p-type materials, nickel oxide is a promising electrically conductive material due to its good stability, large bandgap, and deep valence band. Here, we display pristine and 3 at.%V-doped NiO synthesized by the solvothermal decomposition method. The properties of both the pristine and 3 at.%V:NiO nanoparticles were characterized by field emission scanning electron microscopy (FESEM), transmission electron microscopy (TEM), X-ray diffractometry (XRD), Raman spectroscopy, ultraviolet–visible spectroscopy (UV–vis), and X-ray photoelectron spectroscopy (XPS). The film properties were characterized by atomic force microscopy (AFM) and a source meter. Our results suggest that incorporation of vanadium into the NiO lattice significantly improves both electrical conductivity and hole extraction. Also, 3 at.%V:NiO exhibits a lower crystalline size when compared to pristine nickel oxide, which maintains the reduction of surface roughness. These results indicate that vanadium is an excellent dopant for NiO.

scholarly journals Nanoengineering of Gold Nanoparticles: Green Synthesis, Characterization, and Applications

Crystals ◽  
2019 ◽  
Vol 9 (12) ◽  
pp. 612 ◽  
Author(s):  
Nancy Tepale ◽  
Víctor V. A. Fernández-Escamilla ◽  
Clara Carreon-Alvarez ◽  
Valeria J. González-Coronel ◽  
Adan Luna-Flores ◽  
...  
Keyword(s):  
Gold Nanoparticles ◽  
Green Synthesis ◽  
Photoelectron Spectroscopy ◽  
X Ray Diffraction ◽  
Fundamental Study ◽  
X Ray ◽  
Force Microscopy ◽  
X Ray Scattering ◽  
Atomic Force ◽  
Transmission Electron

The fundamental aspects of the manufacturing of gold nanoparticles (AuNPs) are discussed in this review. In particular, attention is devoted to the development of a simple and versatile method for the preparation of these nanoparticles. Eco-friendly synthetic routes, such as wet chemistry and biosynthesis with the aid of polymers, are of particular interest. Polymers can act as reducing and/or capping agents, or as soft templates leading to hybrid nanomaterials. This methodology allows control of the synthesis and stability of nanomaterials with novel properties. Thus, this review focus on a fundamental study of AuNPs properties and different techniques to characterize them, e.g., Transmission Electron Microscopy (TEM), Atomic Force Microscopy (AFM), UV-Visible spectroscopy, Dynamic Light Scattering (DLS), X-Ray Diffraction (XRD), X-Ray Photoelectron Spectroscopy, Small-angle X-Ray Scattering (SAXS), and rheology. Recently, AuNPs obtained by “green” synthesis have been applied in catalysis, in medicine, and as antibacterials, sensors, among others.

scholarly journals Photo-Irradiated Biosynthesis of Silver Nanoparticles Using Edible MushroomPleurotus floridaand Their Antibacterial Activity Studies

2011 ◽  
Vol 2011 ◽  
pp. 1-7 ◽  
Author(s):  
Ravishankar Bhat ◽  
Raghunandan Deshpande ◽  
Sharanabasava V. Ganachari ◽  
Do Sung Huh ◽  
A. Venkataraman
Keyword(s):  
Electron Microscopy ◽  
Silver Nanoparticles ◽  
X Ray Diffraction ◽  
Spectroscopy Analysis ◽  
X Ray ◽  
Force Microscopy ◽  
Atomic Force ◽  
Transmission Electron ◽  
Synthetic Procedure ◽  
Uv Visible

This is a report on photo-irradiated extracellular synthesis of silver nanoparticles using the aqueous extract of edible oyster mushroom (Pleurotus florida) as a reducing agent. The appearance, size, and shape of the silver nanoparticles are understood by UV-visible spectroscopy, field emission scanning electron microscopy, transmission electron microscopy, and atomic force microscopy. The X-ray diffraction studies, energy dispersive X-ray analysis indicate that particles are crystalline in nature. Fourier transform infrared spectroscopy analysis revealed that the nanoparticles are covered with biomoieties on their surface. As can be seen from our studies, the biofunctionalized silver nanoparticles thus produced have shown admirable antimicrobial effects, and the synthetic procedure involved is eco-friendly and simple, and hence high range production of the same can be considered for using them in many pharmaceutical applications.

Redox and Electrocatalytic Activity of Ni Ion-Implanted Ti

2004 ◽  
Vol 19 (4) ◽  
pp. 1249-1256 ◽  
Author(s):  
M.T. Pham ◽  
M.F. Maitz ◽  
H. Reuther ◽  
E. Richter ◽  
W. Matz ◽  
...  
Keyword(s):  
Photoelectron Spectroscopy ◽  
Surface Film ◽  
Bulk Alloy ◽  
X Ray ◽  
Force Microscopy ◽  
Atomic Force ◽  
Transmission Electron ◽  
Oxidation Of Glucose ◽  
Redox Conversion ◽  
Ion Implanted

Ni-Ti surface alloy was prepared by ion-implanting Ni into Ti. The surface film was amorphous having a Ni surface content of 10–40 at.%. The material was compared with a Ni-Ti bulk alloy (44.08:55.9) regarding their redox and electrocatalytic behavior in NaOH by cyclic voltammetry. The surface was characterized by x-ray photoelectron spectroscopy, x-ray and electron diffraction, transmission electron microscopy, and atomic force microscopy. The ion-implanted material revealed an enhanced activity toward the redox conversion of Ni(OH)2 ↔ NiOOH and the anodic oxidation of glucose. The effect is discussed considering the enhanced generation of active Ni surface sites from amorphous Ni and the stabilization of higher valence Ni by Ti.

scholarly journals Graphene Oxide/Ferrocene-Containing Polymer/Gold Nanoparticle Triple Nanocomposite

Nanomaterials ◽  
2019 ◽  
Vol 9 (2) ◽  
pp. 310 ◽  
Author(s):  
Wenhao Qian ◽  
Tao Song ◽  
Mao Ye ◽  
Haiyan Zhang ◽  
Chun Feng ◽  
...  
Keyword(s):  
Photoelectron Spectroscopy ◽  
Colloidal Stability ◽  
Average Diameter ◽  
X Ray Diffraction ◽  
X Ray ◽  
Force Microscopy ◽  
Atomic Force ◽  
Transmission Electron ◽  
Methacrylate Monomer ◽  
Multifunctional Nanocomposites

A facile strategy to prepare GO-based nanocomposites with both gold nanoparticles (AuNPs) and ferrocene (Fc) moieties was developed. The surface of GO was modified with PFcMAss homopolymer by surface-initiated atom transfer radical polymerization of a new methacrylate monomer of 2-((2-(methacryloyloxy)ethyl)disulfanyl)ethyl ferrocene-carboxylate (FcMAss), consisting of disulfide as an anchoring group for stabilizing AuNPs and Fc group as an additional functionality. AuNPs with an average diameter of about 4.1 nm were formed in situ on the surface of PFcMAss-decorated GO (GO-PFcMAss) via Brust-Schiffrin method to give GO-PFcMAss-AuNPs multifunctional nanocomposites bearing GO, AuNPs and Fc groups. The obtained nanocomposites were characterized by X-ray photoelectron spectroscopy (XPS), X-ray diffraction (XRD), transmission electron microscopy (TEM) and atomic force microscopy (AFM). Since disulfide-containing polymers, rather than the commonly used thiol-containing compounds, were employed as ligands to stabilize AuNPs, much more stabilizing groups were attached onto the surface of GO, and thus more AuNPs were able to be introduced onto the surface of GO. Besides, polymeric chains on the surface of GO endowed GO-PFcMAss-AuNPs nanocomposites with excellent colloidal stability, and the usage of a disulfide group provides possibility to efficiently incorporate additional functionalities by easily modifying structure of disulfide-based monomer.

Formation of Si Nanocrystals in Thin SiO2 Films for Memory Device Applications

2010 ◽  
Vol 644 ◽  
pp. 101-104 ◽  
Author(s):  
Mario Curiel ◽  
Ivan Petrov ◽  
Nicola Nedev ◽  
Diana Nesheva ◽  
Mauro R. Sardela ◽  
...  
Keyword(s):  
Memory Device ◽  
X Ray Diffraction ◽  
Sio2 Matrix ◽  
Furnace Annealing ◽  
X Ray ◽  
Force Microscopy ◽  
Atomic Force ◽  
Transmission Electron ◽  
Si Nanocrystals ◽  
Device Applications

X-ray Diffraction and Reflectivity, Transmission Electron Microscopy and Atomic Force Microscopy were applied to study the effect of thermal annealing on the properties of thin SiOx films (~ 15 nm) prepared by thermal evaporation of SiO in vacuum. It has been shown that furnace annealing at 1000 oC causes phase separation and formation of uniformly distributed Si nanocrystals into a SiO2 matrix. Clockwise hysteresis has been observed in the C-V curves measured and explained by assuming charging and discharging of the NCs with carriers, which tunnel from the Si substrate.

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