Microstructural and Electrical Characteristics of Preferential Growth Direction Controlled CuCrO2 Thin Films

2013 ◽  
Vol 8 (6) ◽  
pp. 579-583 ◽  
Author(s):  
Se-Yun Kim ◽  
Kwang-Min Jo ◽  
Joon-Hyung Lee ◽  
Jeong-Joo Kim ◽  
Young-Woo Heo
2016 ◽  
Vol 869 ◽  
pp. 1001-1006
Author(s):  
Claudia Ferreira da Silva ◽  
André Lima e Silva ◽  
Francisco Xavier Nobre ◽  
Edson Cavalcanti Silva Filho ◽  
Luiz de Sousa Santos Jr. ◽  
...  

Two-dimensional microstructures of molybdenum trioxide (MoO3) were synthesized by heptamolybdate tetrahydrate ammonium acidification, followed by calcination. A solution of the precursor compound heptamolybdate tetrahydrate ammonium acidified to pH 3,5 using glacial acetic acid followed by hydrothermal treatment for 150, 180 and 200 °C for 1, 6 and 12 hours. Then, the intermediate was calcined at 300 °C for varying time 6 and 12h to obtain MoO3. X-ray diffraction revealed that the crystals grew with crystalline structure corresponding to the orthorhombic phase of MoO3 (a-MoO3) as major phase, with a preferential growth direction along the planes (0K0). Raman spectroscopy and IR confirmed the formation of the characteristic modes of molybdenum trioxide for stage found. With Scanning Electron Microscopy (SEM) was possible to observe the formation of nanoplates.


2010 ◽  
Vol 24 (06n07) ◽  
pp. 757-761 ◽  
Author(s):  
R. STIUFIUC ◽  
F. TODERAS ◽  
M. IOSIN ◽  
G. STIUFIUC

In this letter we report on successful preparation and characterization of anisotropic gold nanocrystals bio-synthesized by reduction of aqueous chloroaurate ions in pelargonium plant extract. The nanocrystals have been characterized by means of Transmission Electron Microscopy (TEM), UV-VIS absorption spectroscopy and tapping mode atomic force microscopy (TM-AFM). Using these investigation techniques, the successful formation of anisotropic single nanocrystals with the preferential growth direction along the gold (111) plane has been confirmed. The high detail phase images could give us an explanation concerning the growth mechanism of the nanocrystals.


2004 ◽  
Vol 832 ◽  
Author(s):  
V. Sharma ◽  
B. V. Kamenev ◽  
L. Tsybeskov ◽  
T. I. Kamins

ABSTRACTIn this paper, we report Raman Scattering (RS) and photoluminescence (PL) measurements of Ge nanowires (NWs) grown via vapor-liquid-solid (VLS) using chemical vapor deposition silicon substrates consisting of (100) and (111) crystallographic orientations. Ge NWs grown are ∼40 nm in diameter, approximately a micrometer in length, and a sharp narrow Raman peak at ∼300 cm−1 indicates single crystal quality. An absence of SiGe peak in the Raman spectra indicates that SiGe interdiffusion is insignificant for the NW volume. Low temperature PL-intensity-dependence spectra indicate that the observed emission originates at the Ge NW – Si substrate interface, where SiGe intermixing has been detected. This interface is formed differently for (111) and (100) oriented Si substrates due to the <111> preferential growth direction of Ge NWs.


2011 ◽  
Vol 704-705 ◽  
pp. 343-347
Author(s):  
Long Sun Chao ◽  
Yu Ru Chen ◽  
Fang Chun Wang

In this paper, an experiment model for the directional solidification of Lead/Tin alloy is built and the effects of different-shape seeds on the microstructures on the solidification microstructure are investigated. In a casting process, the temperature and concentration fields will affect the microstructures of materials and this influence is the key point of improving their mechanical and physical properties. It is not easy to control the morphology of solidifying microstructures. The scheme of directional solidification can make the microstructures grow along a fixed direction and it is also the base of single-crystal growth. In the experiment, a poly-grain seed with the same initial concentration of the solidifying casting is used to induce the columnar growth at the bottom portion of the casting, which could avoid the equiaxed growth due to the high undercooling or cooling rate there. In the experimental analysis, we studied the influences of different geometry seeds on the constrained growth, the preferential growth direction of dendrite, the grain size, the temperature gradient, the growth rate, the primary arm spacing and the secondary arm spacing. From the microstructure observation, the adding seed casting reduced the chill-affected and extended the directional solidification zone. This is expected to have the better or more complete structure of directional solidification. Keywords: Directional Solidification, Seed, Heat Transfer and Microstructure


2018 ◽  
Vol 54 (53) ◽  
pp. 7358-7361 ◽  
Author(s):  
Daniel Wurmbrand ◽  
Jörg Wolfram Anselm Fischer ◽  
Rose Rosenberg ◽  
Klaus Boldt

Semiconductor nanorods nucleate via a fibrillar intermediate that is able to template its own preferential growth direction.


2021 ◽  
Vol 11 (1) ◽  
Author(s):  
Inti Zumeta-Dubé ◽  
José Manuel García Rangel ◽  
Jorge Roque ◽  
Issis Claudette Romero-Ibarra ◽  
Mario Fidel García Sánchez

AbstractThe strong facet-dependent performance of glass-supported CeO2 thin films in different applications (catalysis, smart windows, etc.) has been the target of diverse fundamental and technological approaches. However, the design of accurate, cost-effective and scalable methods with the potential for large-area coverage that produce highly textured glass-supported CeO2 thin films remains a technological challenge. In the present work, it is demonstrated that under proper tuning conditions, the ultrasonic spray pyrolysis technique enables one to obtain glass-supported polycrystalline CeO2 films with noticeable texture along both the (100) and (111) directions, as well as with randomly oriented crystallites (no texture). The influence of flow rates, solution molarity, and substrate temperature on the texture and morphological characteristics, as well as optical absorption and Raman response of the deposited films, is evaluated. The obtained results are discussed on the basis of the combined dependence of the CeO2-exposed surfaces on the thermodynamic stability of the corresponding facets and the reaction kinetics, which modulate the crystallite growth direction.


2021 ◽  
pp. 149706
Author(s):  
Yumin Sim ◽  
Jinbae Kim ◽  
Seo Hyoung Chang ◽  
Chel-Jong Choi ◽  
Maeng-Je Seong
Keyword(s):  

1994 ◽  
Vol 361 ◽  
Author(s):  
Chang Jung Kim ◽  
Dae Sung Yoon ◽  
Joon Sung Lee ◽  
Chaun Gi Choi ◽  
Won Jong Lee ◽  
...  

ABSTRACTThe (100), (111) and randomly oriented PZT thin films were fabricated on Pt/Ti/Coming 7059 glass using sol-gel method. The thin films having different orientation were fabricated by different drying conditions for pyrolysis. The preferred orientations of the PZT thin films were observed using XRD, rocking curves, and pole figures. The microstructures were investigated using SEM. The hysteresis loops and capacitance-voltage characteristics of the films were investigated using a standardized ferroelectric test system. The dielectric constant and current-voltage characteristics of the films were investigated using an impedance analyzer and pA meter, respectively. The films oriented in a particular direction showed superior electrical characteristics to the randomly oriented films.


2010 ◽  
Vol 518 (16) ◽  
pp. 4615-4618 ◽  
Author(s):  
Petronela Prepelita ◽  
R. Medianu ◽  
F. Garoi ◽  
N. Stefan ◽  
Felicia Iacomi

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