The anchored location of CdS on SiC via organosilane for effective heterogeneous interface design in photocatalysis

2019 ◽  
Vol 9 (8) ◽  
pp. 906-913
Author(s):  
Yuan Peng ◽  
Jingjing Yang ◽  
Taiping Xie ◽  
Zhenyu Li ◽  
Wenbing Shi
Keyword(s):  
Interface Design ◽  
Carrier Lifetime ◽  
The Other ◽  
Periodic Lattice ◽  
Electron Hole ◽  
Lattice Distribution ◽  
New Approach ◽  
Uniform Interface ◽  
Charge Carrier Lifetime ◽  
Hole Recombination

This work demonstrates a new approach to construct a heterogeneous junction by means of the periodic lattice distribution of semiconductor atoms. The organosilane was applied as an anchored coupling agent to connect the semiconductors at both ends, one of which connects SiC and the other connects CdS, and the SiC/M/CdS heterogeneous junction was established. The photocatalytic hydrogen evolution ability of this heterojunction was three times as much as the traditional SiC/CdS composite under visible light. Meanwhile, the uniform interface distribution, prolonged charge-carrier lifetime and minor electron–hole recombination were achieved. The results provide new insights into interface design and offer an indepth understanding with respect to organic–inorganic heterojunction configuration in photocatalysis.

Suppressing photoexcited electron–hole recombination in MoSe2/WSe2 lateral heterostructures via interface-coupled state engineering: a time-domain ab initio study

2020 ◽  
Vol 8 (39) ◽  
pp. 20621-20628
Author(s):  
Zhaobo Zhou ◽  
Yehui Zhang ◽  
Xiwen Zhang ◽  
Xianghong Niu ◽  
Guangfen Wu ◽  
...  
Keyword(s):  
Time Domain ◽  
Carrier Lifetime ◽  
Vital Role ◽  
Two Dimensional ◽  
Ab Initio Study ◽  
Electron Hole ◽  
Photoexcited Electron ◽  
Photoexcited Carrier ◽  
Hole Recombination ◽  
Lateral Heterostructure

Interface-coupled states play a vital role in photoexcited carrier lifetime of two-dimensional lateral heterostructure-based photovoltaic and photoelectric devices.

scholarly journals Structural rigidity accelerates quantum decoherence and extends carrier lifetime in porphyrin nanoballs: a time domain atomistic simulation

2020 ◽  
Vol 2 (4) ◽  
pp. 1502-1511
Author(s):  
Ritabrata Sarkar ◽  
Md Habib ◽  
Moumita Kar ◽  
Anup Pramanik ◽  
Sougata Pal ◽  
...  
Keyword(s):  
Time Domain ◽  
Atomistic Simulation ◽  
Quantum Coherence ◽  
Carrier Lifetime ◽  
Quantum Decoherence ◽  
Phonon Coupling ◽  
Electron Hole ◽  
Structural Rigidity ◽  
Electron Phonon Coupling ◽  
Hole Recombination

Structural rigidity assists to weaken the NA electron–phonon coupling, shorten the quantum coherence and thus suppress the dynamics of electron–hole recombination.

A New Approach to the Demonstration of Oxidase-Localization Using Tannic Acid Or Catechin

1973 ◽  
Vol 31 ◽  
pp. 698-699
Author(s):  
V. Mizuhira ◽  
Y. Futaesaku
Keyword(s):  
Cross Section ◽  
Tannic Acid ◽  
Elastic Fiber ◽  
The Other ◽  
New Approach ◽  
Tissue Block ◽  
Active Reaction ◽  
The Cross

Previously we reported that tannic acid is a very effective fixative for proteins including polypeptides. Especially, in the cross section of microtubules, thirteen submits in A-tubule and eleven in B-tubule could be observed very clearly. An elastic fiber could be demonstrated very clearly, as an electron opaque, homogeneous fiber. However, tannic acid did not penetrate into the deep portion of the tissue-block. So we tried Catechin. This shows almost the same chemical natures as that of proteins, as tannic acid. Moreover, we thought that catechin should have two active-reaction sites, one is phenol,and the other is catechole. Catechole site should react with osmium, to make Os- black. Phenol-site should react with peroxidase existing perhydroxide.

Optically Detected Magnetic Resonance and Double Beam Photoluminescence of CdS/HgS/CdS Nanoparticles

1998 ◽  
Vol 536 ◽  
Author(s):  
H. Porteanu ◽  
A. Glozman ◽  
E. Lifshitz ◽  
A. Eychmüller ◽  
H. Weller
Keyword(s):  
Optical Properties ◽  
Magnetic Resonance ◽  
Cds Nanoparticles ◽  
Electron Hole ◽  
Cladding Layer ◽  
Double Beam ◽  
Optically Detected Magnetic Resonance ◽  
Optically Detected ◽  
Cladding Layers ◽  
Hole Recombination

AbstractCdS/HgS/CdS nanoparticles consist of a CdS core, epitaxially covered by one or two monolayers of HgS and additional cladding layers of CdS. The present paper describes our efforts to identify the influence of CdS/HgS/CdS interfaces on the localization of the photogenerated carriers deduced from the magneto-optical properties of the materials. These were investigated by the utilization of optically detected magnetic resonance (ODMR) and double-beam photoluminescence spectroscopy. A photoluminescence (PL) spectrum of the studied material, consists of a dominant exciton located at the HgS layer, and additional non-excitonic band, presumably corresponding to the recombination of trapped carriers at the interface. The latter band can be attenuated using an additional red excitation. The ODMR measurements show the existence of two kinds of electron-hole recombination. These electron-hole pairs maybe trapped either at a twin packing of a CdS/HgS interface, or at an edge dislocation of an epitaxial HgS or a CdS cladding layer.

MAPPING CONTEMPORARY ISLAMIC JURISPRUDENCE OF MUḤAMMAD SAʻĪD AL-‘ASHMĀWĪ AND MUḤAMMAD SHAḤRŪR

2018 ◽  
Vol 1 (1) ◽  
pp. 32
Author(s):  
Yusroh Yusroh ◽  
Mohd. Zaki Abd. Rahman
Keyword(s):  
The Other ◽  
Russian Philosophy ◽  
New Approach ◽  
Marriage And Divorce ◽  
Other Hand ◽  
Islamic Jurisprudence

Muḥammad Saʻīd Al-‘Ashmāwī and Muḥammad Shaḥrūr are well known as contemporary Muslim thinkers. This article tries to map their contemporary ideas on Islamic jurisprudence. The main data of this research taken mainly from the works both of Al-‘Ashmāwī and Shaḥrūr. In particular, the paper tries to analyze Al-‘Ashmāwī‘s ideas on sharia, politics, hijab, marriage and divorce. On the other hand, the ideas of Shahrour on al-Qur'an, Sunnah and Fiqh, the theory of borders, pluralism, the commandment, inheritance, hijab, marriage, divorce, dowry, politics, and imamate are also critizised. After analyzing their lives and their ideas on Islamic jurisprudence, the paper found that their social, educational and practical backgrounds have affected their intellectual formations and ideas. Ashmawi is encouraged by diligence and enlightenment and is believed to be enlightened. Shahrour, however, takes a new approach in order to create the ḥudūd theory as a new way. As well as their intellectual background, Ashmawi has a good queen in Arabic, English and French as well as religion, Sharia, jurisprudence and theology. Shahrour is a good queen in Arabic, English, Russian, philosophy, philology and historical language.

A NEW APPROACH TO THE STUDY OF COORDINATIVE CONSTRUCTIONS

2019 ◽  
pp. 175-187
Author(s):  
Anna Varnayeva
Keyword(s):  
Characteristic Property ◽  
Mathematical Concept ◽  
The Other ◽  
New Approach ◽  
Logical Aspect ◽  
First Case

Coordinative constructions are traditionally opposed to subordinative constructions. However, this opposition comes down to denial of dependence in coordinative constructions. Thereby the parity of these two constructions does not come to light: subordinative construction can be described without coordinative one. This situation is not improved by detection of a coordinative triangle in all coordinative constructions. The article shows a new approach in the study of coordinative constructions: a coordinative construction is a system; there are not only specific relations – a coordinative triangle, – but also specific elements. Novelty of the study consists in the address to extralinguistic facts, viz. a mathematical concept of a set and its elements. There are a lot of similarities between them. A set in mathematics includes generalizing elements and the composed row in coordinative constructions; in the first case the set is not partitioned, in the second case it is partitioned. In mathematics equivalent components in coordinative constructions correspond to the set elements. A characteristic property in mathematics is homogeneity in coordinative constructions and etc. It is firstly demonstrated, that coordinative and subordinative constructions are correlative and the study of one construction is impossible without the study of the other one. Their parity is shown in coordinative constructions with elements of one set, in subordinative ones with elements of different sets. Cf.: roses and tulips –red roses. In the coordinatiму construction elements of one set are called: «flowers »; in the subordinative construction there are elements of different sets: «flowers » and «colors». It should be noted that the mathematical concept of a set relates to so called logical aspect in linguistics or thinking about reality.

Pre-Industrial Experience in Solar Photocatalytic Mineralization of Real Wastewaters. Application to Pesticide Container Recycling

1999 ◽  
Vol 40 (4-5) ◽  
pp. 123-130 ◽  
Author(s):  
S. Malato ◽  
J. Blanco ◽  
C. Richter ◽  
B. Milow ◽  
M. I. Maldonado
Keyword(s):  
Organic Contaminants ◽  
Toxic Waste ◽  
Experimental Plant ◽  
Electron Hole ◽  
Particulate Suspensions ◽  
Photocatalytic System ◽  
Commercial Pesticide ◽  
Pesticide Container ◽  
By Products ◽  
Hole Recombination

Particulate suspensions of TiO2 irradiated with natural solar tight in a large experimental plant catalyse the oxidation of organic contaminants. The problem in using TiO2 as a photocatalyst is electron/hole recombination. One strategy for inhibiting e−/h+ recombination is to add other (irreversible) electron acceptors to the reaction. In many highly toxic waste waters where degradation of organic pollutants is the major concern, the addition of an inorganic anion to enhance the organic degradation rate may be justified. For better results, these additives should fulfil the following criteria: dissociate into harmless by-products and lead to the formation of ·OH or other oxidising agents. In this paper, we attempt to demonstrate the optimum conditions for the treatment of commercial pesticide rinsates found in the wastewater produced by a pesticide container recycling plant. The experiments were performed in one of the pilot plants of the largest solar photocatalytic system in Europe, the Detoxification Plants of the Plataforma Solar de Almería (PSA), in Spain. After testing ten different commercial pesticides, results show that peroxydisulphate enhances the photocatalytic miniralization of all of them. This study is part of an extensive project focused on the design of a solar photocatalytic plant for decontamination of agricultural rinsates in Almería (Spain).

scholarly journals Integrated Double-Sided Random Microlens Array Used for Laser Beam Homogenization

Micromachines ◽  
2021 ◽  
Vol 12 (6) ◽  
pp. 673
Author(s):  
Wei Yuan ◽  
Cheng Xu ◽  
Li Xue ◽  
Hui Pang ◽  
Axiu Cao ◽  
...  
Keyword(s):  
Laser Beam ◽  
Microlens Array ◽  
Energy Utilization ◽  
Utilization Rate ◽  
Periodic Lattice ◽  
Lattice Distribution ◽  
Speckle Field ◽  
High Laser ◽  
Alignment Problem ◽  
In Series

Double microlens arrays (MLAs) in series can be used to divide and superpose laser beam so as to achieve a homogenized spot. However, for laser beam homogenization with high coherence, the periodic lattice distribution in the homogenized spot will be generated due to the periodicity of the traditional MLA, which greatly reduces the uniformity of the homogenized spot. To solve this problem, a monolithic and highly integrated double-sided random microlens array (D-rMLA) is proposed for the purpose of achieving laser beam homogenization. The periodicity of the MLA is disturbed by the closely arranged microlens structures with random apertures. And the random speckle field is achieved to improve the uniformity of the homogenized spot by the superposition of the divided sub-beams. In addition, the double-sided exposure technique is proposed to prepare the rMLA on both sides of the same substrate with high precision alignment to form an integrated D-rMLA structure, which avoids the strict alignment problem in the installation process of traditional discrete MLAs. Then the laser beam homogenization experiments have been carried out by using the prepared D-rMLA structure. The laser beam homogenized spots of different wavelengths have been tested, including the wavelengths of 650 nm (R), 532 nm (G), and 405 nm (B). The experimental results show that the uniformity of the RGB homogenized spots is about 91%, 89%, and 90%. And the energy utilization rate is about 89%, 87%, 86%, respectively. Hence, the prepared structure has high laser beam homogenization ability and energy utilization rate, which is suitable for wide wavelength regime.

Stress Testing to Assess Recovery from Extreme Events

2021 ◽  
Vol 0 (0) ◽  
Author(s):  
M. John Plodinec
Keyword(s):  
Climate Change ◽  
United States ◽  
Financial Institutions ◽  
Extreme Events ◽  
Stress Testing ◽  
The United States ◽  
The Other ◽  
New Approach ◽  
Rapid Spread ◽  
Potential Benefits

Abstract Over the last decade, communities have become increasingly aware of the risks they face. They are threatened by natural disasters, which may be exacerbated by climate change and the movement of land masses. Growing globalization has made a pandemic due to the rapid spread of highly infectious diseases ever more likely. Societal discord breeds its own threats, not the least of which is the spread of radical ideologies giving rise to terrorism. The accelerating rate of technological change has bred its own social and economic risks. This widening spectrum of risk poses a difficult question to every community – how resilient will the community be to the extreme events it faces. In this paper, we present a new approach to answering that question. It is based on the stress testing of financial institutions required by regulators in the United States and elsewhere. It generalizes stress testing by expanding the concept of “capital” beyond finance to include the other “capitals” (e.g., human, social) possessed by a community. Through use of this approach, communities can determine which investments of its capitals are most likely to improve its resilience. We provide an example of using the approach, and discuss its potential benefits.

Closed Sets of Boolean Terms in Relational Databases

1991 ◽  
Vol 14 (3) ◽  
pp. 367-385
Author(s):  
Andrzej Jankowski ◽  
Zbigniew Michalewicz
Keyword(s):  
Computational Complexity ◽  
Incomplete Information ◽  
Relational Databases ◽  
The Other ◽  
New Approach ◽  
Closed Sets ◽  
Null Value ◽  
Algebraic Operations

A number of approaches have been taken to represent compound, structured values in relational databases. We review a few such approaches and discuss a new approach, in which every set is represented as a Boolean term. We show that this approach generalizes the other approaches, leading to more flexible representation. Boolean term representation seems to be appropriate in handling incomplete information: this approach generalizes some other approaches (e.g. null value mark, null variables, etc). We consider definitions of algebraic operations on such sets, like join, union, selection, etc. Moreover, we introduce a measure of computational complexity of these operations.

Sign in / Sign up

Export Citation Format

Share Document