Charge transport mechanism in dodecylbenzenesulfonic acid doped polyaniline/carbon black composites

2021 ◽  
pp. 096739112110403
Author(s):  
Ariba Bibi ◽  
Abdul Shakoor
Keyword(s):  
Carbon Black ◽  
Charge Transport ◽  
In Situ Polymerization ◽  
Three Dimensional ◽  
Aqueous Dispersion ◽  
Ammonium Persulfate ◽  
Sem Analysis ◽  
Dc Conductivity ◽  
Dodecylbenzenesulfonic Acid ◽  
Doped Polyaniline

Dodecylbenzenesulfonic acid (DBSA) doped polyaniline and carbon black (CB) composites (PANI-DBSA/CB) were synthesized by in-situ polymerization of aniline in the aqueous dispersion of carbon black (CB) in the presence of ammonium persulfate (APS) as an oxidant. Various composite samples with varying amounts of CB (1 wt% and 2 wt%) were synthesized and were characterized by using X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), and scanning electron microscopy (SEM). XRD studies confirmed the formation of the well-organized and semi-crystalline structure of the composites. SEM analysis revealed the increase in grain size and the granular structure of the synthesized composites. DC conductivity was measured in the temperature range from 300 K to 393 K using two probe methods. An increase in DC conductivity was found on the inclusion of carbon black at all temperatures and the most probable model of charge transport was found to be three-dimensional variable range hopping (3D-VRH). As the concentration of CB in the composites increased, activation energy was found to be decreased. The density of states, hopping length, and hopping energy were calculated, respectively, and were found to be influenced by CB incorporation.

Properties of Polyaniline with the Doping of Different Acid

2012 ◽  
Vol 502 ◽  
pp. 31-35 ◽  
Author(s):  
Xiao Hua Wang
Keyword(s):  
Thermal Stability ◽  
Reaction Time ◽  
Reaction Temperature ◽  
Acid Content ◽  
In Situ Polymerization ◽  
Ammonium Persulfate ◽  
Dodecylbenzenesulfonic Acid ◽  
Thermal Stability Of

Polyaniline(PANI) with the doping of hydrochloride(HC1), aminosulfonic acid (NH2SO3H) or dodecylbenzenesulfonic acid(DBSA) was prepared by in-situ polymerization. Effects of acid content, reaction time, oxidant ammonium persulfate (APS) dosage and reaction temperature on the conductivity of PANI were studied. The resistance and thermal stability of them were compared. Results show that the largest conductivity of HC1-PANI is 1.98 s.cm-1 among them in case the C(HC1)=0.5mol/L, reaction time is 6.0h, n(APS/aniline)=1.0; The conductivity of NH2SO3H-PANI is 0.2s.cm-1 in case the C(NH2SO3H)=1.0mol/L, reaction time is 6.0h, n(APS/aniline)=2.0; The conductivity of DBSA-PANI is 0.98s.cm-1 in case the C(DBSA)=1.0 mol/L, reaction time is 8.0h, n(APS/aniline) = 2.0. The the least resistance of HC1-PANI is 10Ω, and that of NH2SO3H- PANI is the largest of 120Ω. The order of their thermal stability is DBSA-PANI > NH2SO3H-PANI > HC1-PANI before 350°C, that of their thermal stability is inverse when it reaches 350°C.

scholarly journals Synthesis and Characterization of Polypyrrole (PPy) by In-situ Polymerization Technique

2020 ◽  
Vol 6 (2) ◽  
pp. 686-688
Author(s):  
Phalak Mrunalini ◽  
Rajendra Waghulade ◽  
Yogesh Toda
Keyword(s):  
In Situ Polymerization ◽  
Ammonium Persulfate ◽  
Sem Analysis ◽  
X Ray Diffraction ◽  
X Ray ◽  
Nano Powder ◽  
Infra Red ◽  
Granular Morphology

This work reports synthesize of polypyrrole nano powder by chemical in-situ polymerization of pyrrole in aqueous solution and ammonium persulfate solution which acts as oxidant. It is characterized by X-ray diffraction (XRD), Fourier infra-red spectroscopy (FTIR) and scanning electron microscopy (SEM). The XRD spectrum reveals that the materials are amorphous in nature. FTIR analysis confirms that all peaks are the main characteristic of PPy. SEM analysis showed that the powder has a uniform granular morphology and the size varies from ∼500 nm to 1 μm. The micrograph of polypyrrole reveals the presence of globular particles. The formed particles are irregular in nature. The results show that the fibers are chemically formed as spherical nanostructures.

Mechanical Property and Conductivity of Polyaniline-Poly(Vinyl Alcohol)Composite Films

2012 ◽  
Vol 502 ◽  
pp. 297-301
Author(s):  
Xiao Hua Wang
Keyword(s):  
Tensile Strength ◽  
Reaction Time ◽  
Composite Film ◽  
In Situ Polymerization ◽  
Composite Films ◽  
Ammonium Persulfate ◽  
Poly Vinyl Alcohol ◽  
Dodecylbenzenesulfonic Acid ◽  
Drying Temperature

The polyaniline(PANI)-poly(vinyl alcoho1)(PVA) composite films with the doping of hydrochloride (HCl), dodecylbenzenesulfonic acid (DBSA) or aminosulfonic acid (NH2SO3H ) were prepared by in-situ polymerization. Effects of PVA content, HC1 content, oxidant ammonium persulfate(APS)dosage, reaction time and film drying temperature on tensile strength of the HCl-PANI-PVA composite film were studied. The conductivity of PANI-PVA composite film with the doping of HCl is the highest of 13.2S.cm-1 among them. The tensile strength of the film is improved greatly due to effective mixture of PANI and PVA. The tensile strength of the composite film substantially depended upon the mass fraction of PVA. The tensile strength of the HC1-PANI-PVA composite film reaches the maximum of 60.8 MPa, in case the PVA content is 40%, the C(HC1)=1.0 mol/L，reaction time is 4.0 h, the n(APS/An)=1.0, and film drying temperature is 80°C.

The Study of Acid Doped Polyaniline Anticorrosive Coatings

2011 ◽  
Vol 399-401 ◽  
pp. 2013-2017
Author(s):  
Hong Yin Xu ◽  
Li Li
Keyword(s):  
Salicylic Acid ◽  
Electron Microscope ◽  
Ammonium Persulfate ◽  
Sem Analysis ◽  
Temperature Reaction ◽  
Main Research ◽  
Anticorrosive Coatings ◽  
Doped Polyaniline ◽  
Salicylic Acid Concentration ◽  
Scanning Electron

This topic in the reaction temperature, reaction time for 5 °C for 7 hours, aniline and ammonium persulfate mole ratio of 1:1 conditions, main research on synthesis of concentration of reactant polyaniline performance, yield, the influence of electric conductivity. By ir, conductivity meter, scanning electron microscope (sem) analysis of samples, and the results show that when the yankees salicylic acid concentration sulfonylureas 0.15-0.25 mol/L, ammonium persulfate concentration 0.1-0.2 mol/L got when the production rate is higher, anticorrosive performance is good polyaniline coatings.

Synthesis and Characterization of PANI/Ferric Chloride Composite for Fabrication of Electrodes in Supercapacitor

2013 ◽  
Vol 768 ◽  
pp. 334-337 ◽  
Author(s):  
Deebankarthikeyan Sivalingam ◽  
Hemalatha Elangovan ◽  
Manikandan Subramanian ◽  
Senthil Kumar Kandasamy ◽  
Murugesan Govindasamy
Keyword(s):  
Ferric Chloride ◽  
In Situ Polymerization ◽  
Ammonium Persulfate ◽  
Supercapacitor Application ◽  
Vis Spectroscopy ◽  
Doped Polyaniline ◽  
Polymerization Method ◽  
Hcl Medium

The main objective of this work is to synthesize polyaniline/ferric chloride composite and to measure the conductivity of the as prepared composite. And also, to analyze the ability of using Ferric Chloride doped polyaniline as an electrode material for the fabrication of supercapacitor application. By in-situ polymerization method, polyaniline in pure form and doped form with the ferric chloride were synthesized using ammonium persulfate as initiator in HCl medium. Polyaniline nanoparticles and its composite are characterized by UV-Vis spectroscopy, FTIR, XRD and Conductivity meter.

In-Situ Formation and Coating of Cordierite Whiskers on Cordierite Based Honeycomb Support

2006 ◽  
Vol 317-318 ◽  
pp. 701-704
Author(s):  
Daniel Doni Jayaseelan ◽  
Shunkichi Ueno ◽  
Hideki Kita ◽  
Naoki Kondo ◽  
Tatsuki Ohji
Keyword(s):  
Three Dimensional ◽  
Sem Analysis ◽  
In Situ Method ◽  
Dimensional Network ◽  
In Situ Formation ◽  
Cordierite Honeycomb ◽  
Complete Formation ◽  
Aqueous Slurry

In this work, cordierite whiskers were successfully coated on cordierite honeycomb support by in-situ method. Whisker coating was performed on walls of the pore channels of cordierite support from aqueous slurry. Sintering was carried out at 1300 °C for 4 hours. XRD measurements revealed a complete formation of cordierite phase, no traces of other phases were identified. A well adherence of coating on the support was identified from the microstructure. SEM analysis also revealed the formation of three-dimensional network of cordierite whiskers with open pores between them on the cordierite support.

Structure-Property Relationship of Dodecylbenzenesulfonic Acid Doped Polyaniline

2013 ◽  
Vol 721 ◽  
pp. 199-205 ◽  
Author(s):  
Ying Liu ◽  
Qi Wen ◽  
Jia Li Guan ◽  
Shi Jie Zhao ◽  
Qi Xing Hu ◽  
...  
Keyword(s):  
Molecular Weight ◽  
Ammonium Persulfate ◽  
Degree Of Crystallinity ◽  
Structure Property ◽  
X Ray Diffraction ◽  
Electrospinning Technique ◽  
Dodecylbenzenesulfonic Acid ◽  
Molar Ratios ◽  
Liquid Crystal Property ◽  
Relationship Of

Dodecylbenzenesulfonic acid (DBSA) doped polypanilines (PANIs) were chemically synthesized in different molar ratios of aniline (An) to ammonium persulfate (APS) and An to DBSA. The microstructures of these PANIs were investigated by means of scanning electron microscope (SEM), X-ray diffraction (XRD), and Fourier Transform Infrared (FTIR). UV-Vis spectrometer, semiconductor parameter analyzer, ubbelohde viscometer and electrospinning technique were used to characterize the optical, electrical properties, viscosity and solubility of these PANIs. The results show that the molar rations of An to APS and An to DBSA had strong effect on the microstructure, molecular weight, degree of crystallinity, optical property, solubility and conductivity of obtained DBSA doped PANI. With the increase of the molar ratios of An to APS and An to DBSA, the conductivities and molecular weight of DBSA doped PANIs decreased, while the degree of crystallinity and solubility of DBSA doped PANIs increased. The DBSA doped PANI could dissolve in dichloromethane or HFIP and could be fabricated short fibers by electrospinning. Moreover, the solution of DBSA doped PANIs in concentrated sulphuric acid showed liquid crystal property.

scholarly journals CoMnO2-Decorated Polyimide-Based Carbon Fiber Electrodes for Wire-Type Asymmetric Supercapacitor Applications

2020 ◽  
Author(s):  
Young-Hun Cho ◽  
Jae-Gyoung Seong ◽  
Jae-Hyun Noh ◽  
Da-Young Kim ◽  
Yong-Sik Chung ◽  
...  
Keyword(s):  
Carbon Fiber ◽  
Carbon Fibers ◽  
Rate Capability ◽  
Ammonium Persulfate ◽  
Chemical Oxidation ◽  
Sem Analysis ◽  
Metal Nanostructures ◽  
Carbon Fiber Electrode ◽  
Coated Carbon ◽  
Fiber Electrode

In this work, we report the carbon fiber-based wire-type asymmetric supercapacitors (ASCs). The highly conductive carbon fibers were prepared by the carbonized and graphitized process using the polyimide (PI) as a carbon fiber precursor. To assemble the ASC device, the CoMnO2-coated and Fe2O3-coated carbon fibers were used as the cathode and the anode materials, respectively. FE-SEM analysis confirmed that the CoMnO2-coated carbon fiber electrode exhibited the porous hierarchical interconnected nanosheet structures, depending on the added amounts of ammonium persulfate (APS) as an oxidizing agent, and Fe2O3-coated carbon fiber electrode showed a uniform distribution of porous Fe2O3 nanorods over the surface of carbon fibers. The nanostructured CoMnO2 were directly deposited onto carbon fibers by a chemical oxidation route without high temperature treatments. In particular, the electrochemical properties of the CoMnO2-coated carbon fiber with the concentration of 6 mmol APS presented the enhanced electrochemical activity, probably due to its porous morphologies and good conductivity. Further, to reduce the interfacial contact resistance as well as improve the adhesion between transition metal nanostructures and carbon fibers, the carbon fibers were pre-coated with the Ni layer as a seed layer using an electrochemical deposition method. The fabricated ASC device delivered a specific capacitance of 221 F g-1 at 0.7 A g-1 and good rate capability of 34.8% at 4.9 A g-1. Moreover, the wire-type device displayed the superior energy density of 60.16 Wh kg-1 at a power density of 490 W kg-1 and excellent capacitance retention of 95% up to 3,000 charge/discharge cycles.

scholarly journals The Influence of Morphology on the Charge Transport in Two-Phase Disordered Organic Systems

2015 ◽  
Vol 1737 ◽  
Author(s):  
Cristiano F. Woellner ◽  
Leonardo D. Machado ◽  
Pedro A. S. Autreto ◽  
José A. Freire ◽  
Douglas S. Galvão
Keyword(s):  
Charge Transport ◽  
Master Equation ◽  
Carrier Mobility ◽  
Three Dimensional ◽  
Domain Size ◽  
Threshold Field ◽  
Phase System ◽  
Two Phase ◽  
Donor Acceptor ◽  
Pauli Master Equation

ABSTRACTIn this work we use a three-dimensional Pauli master equation to investigate the charge carrier mobility of a two-phase system, which can mimic donor-acceptor and amorphous-crystalline bulk heterojunctions. Our approach can be separated into two parts: the morphology generation and the charge transport modeling in the generated blend. The morphology part is based on a Monte Carlo simulation of binary mixtures (donor/acceptor). The second part is carried out by numerically solving the steady-state Pauli master equation. By taking the energetic disorder of each phase, their energy offset and domain morphology into consideration, we show that the carrier mobility can have a significant different behavior when compared to a one-phase system. When the energy offset is non-zero, we show that the mobility electric field dependence switches from negative to positive at a threshold field proportional to the energy offset. Additionally, the influence of morphology, through the domain size and the interfacial roughness parameters, on the transport was also investigated.

Conductive Probe Microscopy Investigation of Electrical and Charge Transport in Advanced Carbon Nanotubes and Nanofibers-Polymer Nanocomposites

2014 ◽  
pp. 343-375
Author(s):  
Tewfik Souier
Keyword(s):  
Carbon Nanotubes ◽  
Charge Transport ◽  
Electrostatic Force ◽  
Three Dimensional ◽  
Current Sensing ◽  
Probe Microscopy ◽  
Force Microscopy ◽  
Three Dimensional Representation ◽  
Microscopy Investigation

In this chapter, the main scanning probe microscopy-based methods to measure the transport properties in advanced polymer-Carbon Nanotubes (CNT) nanocomposites are presented. The two major approaches to investigate the electrical and charge transport (i.e., Electrostatic Force Microscopy [EFM] and Current-Sensing Atomic Force Microscopy [CS-AFM]) are illustrated, starting from their basic principles. First, the authors show how the EFM-related techniques can be used to provide, at high spatial resolution, a three-dimensional representation CNT networks underneath the surface. This allows the studying of the role of nanoscopic features such as CNTs, CNT-CNT direct contact, and polymer-CNT junctions in determining the overall composite properties. Complementary, CS-AFM can bring insight into the transport mechanism by imaging the spatial distribution of currents percolation paths within the nanocomposite. Finally, the authors show how the CS-AFM can be used to quantify the surface/bulk percolation probability and the nanoscopic electrical conductivity, which allows one to predict the macroscopic percolation model.

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