Orientation relationships of carlsbergite in schreibersite and kamacite in the north Chile iron meteorite

2006 ◽  
Vol 70 (4) ◽  
pp. 373-382 ◽  
Author(s):  
G. Nolze ◽  
G. Wagner ◽  
R. Saliwan Neumann ◽  
R. Skála ◽  
V. Geist

AbstractThe crystallographic orientation of carlsbergite (CrN) in the north Chile meteorite (hexahedrite) was investigated using electron backscatter diffraction and transmission electron microscopy. These studies examined the CrN crystals in the rhabdites (idiomorphic schreibersite) and in kamacite. It was found that the CrN crystals embedded in rhabdite show a number of different orientation relationships with the host crystals. These orientations can be explained based on the lattice dimensions of both coexisting crystalline materials. It was also found that both carlsbergite and kamacite are characterized by a high dislocation density (≥ l09 cm-2) while rhabdite is free of dislocations. It is supposed that in spite of the deformed metallic matrix, a general connection between the orientation relation of all the phases involved exists.

2021 ◽  
Author(s):  
Olga Ageeva ◽  
Ge Bian ◽  
Gerlinde Habler ◽  
Rainer Abart

<p>Magnetite micro-inclusions in silicate minerals are important carriers of the remanent magnetization of rocks. Their shape orientation relationships (SOR) and crystallographic orientation relationships (COR) to the host crystal are of interest in the context of the bulk magnetic properties of the inclusion-host assemblage. We investigated the SOR and COR of magnetite (MT) micro-inclusions in plagioclase (PL) from oceanic gabbro using correlated optical microscopy, scanning electron microscopy, Electron backscatter diffraction analysis and Transmission electron microscopy.</p><p>In the mm-sized PL crystals of the investigated gabbros MT is present as equant, needle- and lath-shaped (sub)micrometer sized inclusions. More than 95% of the needle-shaped inclusions show SOR and specific COR to the plagioclase host. Most of the needles are elongated perpendicular to one of the MT{111} planes, which is aligned parallel to one of the (112), (1-12), (-312), (-3-12), (150), (1-50) or (100) planes of plagioclase. These inclusions are classified as “plane-normal type”. The needle elongation parallel to MT<111>, which is the easy direction of magnetization, ensures high magnetic susceptibility of these inclusions. The underlying formation mechanism is related to the parallel alignment of oxygen layers with similar lattice spacing across the MT-PL interfaces that are parallel to the elongation direction [1].</p><p>Apart from the SOR and the alignment of a MT{111} with one of the PL low index planes, the MT crystals rotate about the needle elongation direction. The rotation angles are statistically distributed with several maxima representing specific orientation relationships. In some cases one of the MT<001> axes is aligned with PL[14 10 7] or PL[-14 10 -7], which ensures that FeO<sub>6 </sub>octahedra of MT well fit into channels // [001] of PL, which are formed by six membered rings of SiO<sub>4</sub> and AlO<sub>4</sub> tetrahedra [2]. This COR is referred to as the “nucleation orientation” of magnetite with respect to PL. There are several other possibilities to fit FeO<sub>6</sub> octahedra into the [001] channels of PL, but the alignment stated above allows for the additional parallel alignment of one of the MT{111} with one of the above mentioned low index lattice planes of PL. MT crystals with one of these nucleation orientations can undergo directional growth to develop laths and needles. MT crystals with other nucleation orientations that do not allow for the parallel alignment of MT{111} with the above mentioned PL lattice planes, do not significantly grow and form the equant inclusions.</p><p>For some needles one or more of the MT{011} planes that are parallel to the needle elongation direction, are aligned with low-index planes of plagioclase such as PL (112), PL(150), PL(1-50) etc., and form MT facets. This situation corresponds to achievement of the best possible match between the two crystal lattices. This can either be generated during primary growth or during re-equilibration of the micro-inclusions and the plagioclase host.</p><p>Funding by RFBR project 18-55-14003 and Austrian Science fund (FWF): I 3998-N29 is acknowledged.</p><p>Reference</p><p>[1] Ageeva et al (2020) Contrib. Mineral. Petrol. 175(10), 1-16.</p><p>[2] Wenk et al (2011) Am. Min. 96, 1316-1324</p>


2014 ◽  
Vol 47 (2) ◽  
pp. 770-779 ◽  
Author(s):  
Feng Wang ◽  
Dong Qiu ◽  
Zhi-Lin Liu ◽  
John A. Taylor ◽  
Mark A. Easton ◽  
...  

The grain refinement of Al by the addition of a small amount of peritectic-forming solute, Nb, has been studied from the crystallographic point of view. Combining the observations of optical microscopy and scanning electron microscopy with the results of energy-dispersive X-ray spectroscopy and X-ray diffraction, it is confirmed that the particles observed at or near the grain centres of refined Al alloys are pro-peritectic Al3Nb particles. The crystallographic matching between the Al3Nb particles and Al grains has also been evaluated using an edge-to-edge matching model and further verified using electron backscatter diffraction and transmission electron microscopy. It is found that there are reproducible crystallographic orientation relationships between the Al3Nb particles and Al grains, and the experimental results are consistent with the predictions of the edge-to-edge matching model. This implies that the pro-peritectic Al3Nb particles are favourable nucleation sites for Al grains from the crystallographic point of view. Furthermore, the analysis of the size distribution of Al3Nb particles reveals that the Al3Nb particles at the grain centres have relatively large particle size, which also corroborates the high potency of Al3Nb according to the free growth model. It is therefore concluded that the significant grain refinement resulting from the addition of Nb is predominantly attributed to thein situformed Al3Nb particles which promote grain refinementviaenhanced heterogeneous nucleation.


2021 ◽  
Vol 176 (12) ◽  
Author(s):  
Ge Bian ◽  
Olga Ageeva ◽  
Aleksander Rečnik ◽  
Gerlinde Habler ◽  
Rainer Abart

AbstractPlagioclase hosted needle- and lath-shaped magnetite micro-inclusions from oceanic gabbro dredged at the mid-Atlantic ridge at 13° 01–02′ N, 44° 52′ W were investigated to constrain their formation pathway. Their genesis is discussed in the light of petrography, mineral chemistry, and new data from transmission electron microscopy (TEM). The magnetite micro-inclusions show systematic crystallographic and shape orientation relationships with the plagioclase host. Direct TEM observation and selected area electron diffraction (SAED) confirm that the systematic orientation relations are due to the alignment of important oxygen layers between the magnetite micro-inclusions and the plagioclase host, a hypothesis made earlier based on electron backscatter diffraction data. Precipitation from Fe-bearing plagioclase, which became supersaturated with respect to magnetite due to interaction with a reducing fluid, is inferred to be the most likely formation pathway. This process probably occurred without the supply of Fe from an external source but required the out-diffusion of oxygen from the plagioclase to facilitate partial reduction of the ferric iron originally contained in the plagioclase. The magnetite micro-inclusions contain oriented lamellae of ilmenite, the abundance, shape and size of which indicate high-temperature exsolution from Ti-rich magnetite constraining the precipitation of the magnetite micro-inclusions to temperatures in excess of ~ 600 °C. This is above the Curie temperature of magnetite, and the magnetic signature of the magnetite-bearing plagioclase grains must, therefore, be considered as the thermoremanent magnetization.


2009 ◽  
Vol 24 (3) ◽  
pp. 647-651 ◽  
Author(s):  
M. Rester ◽  
C. Motz ◽  
R. Pippan

Electron backscatter diffraction (EBSD) and transmission electron microscopy (TEM) analyses of small indentations in copper single crystals exhibit only slight changes of the crystal orientation in the surroundings of the imprints. Far-reaching dislocations might be the reason for these small misorientation changes. Using EBSD and TEM technique, this work makes an attempt to visualize the far-propagating dislocations by introducing a twin boundary in the vicinity of small indentations. Because dislocations piled up at the twin boundary produce a misorientation gradient, the otherwise far-propagating dislocations can be detected.


MRS Advances ◽  
2016 ◽  
Vol 1 (43) ◽  
pp. 2947-2952
Author(s):  
L. Chen ◽  
Z.-H. Lu ◽  
T.-M. Lu ◽  
I. Bhat ◽  
S.B. Zhang ◽  
...  

ABSTRACTEpitaxial Ge films are useful as a substrate for high-efficiency solar cell applications. It is possible to grow epitaxial Ge films on low cost, cube textured Ni(001) sheets using CaF2(001) as a buffer layer. Transmission electron microscopy (TEM) analysis indicates that the CaF2(001) lattice has a 45o in-plane rotation relative to the Ni(001) lattice. The in-plane epitaxy relationships are CaF2[110]//Ni[100] and CaF2[$\bar 1$10]//Ni[010]. Energy dispersive spectroscopy (EDS) shows a sharp interface between Ge/CaF2 as well as between CaF2/Ni. Electron backscatter diffraction (EBSD) shows that the Ge(001) film has a large grain size (∼50 μm) with small angle grain boundaries (< 8o). The epitaxial Ge thin film has the potential to be used as a substrate to grow high quality III-V and II-VI semiconductors for optoelectronic applications.


2021 ◽  
Vol 1027 ◽  
pp. 155-162
Author(s):  
Qiang Wang

In order to study the mechanism of the fatigue strengthening using laser shot peening in GH4169 alloy, micro-structural and nanoscale mechanical twins (MT) at different depth below the top surface subjected to laser shot peening processing (LSP) were investigated by means of electron backscatter diffraction (EBSD) and transmission electron microscopy (TEM) observations. In terms of the experimental observations and analyses, the formation of refined grains and nanoscale MT mechanism at the near surface of GH4169 alloy as a function of LSP treament can be summarized as follows: (i) two direction low density of MTs divide the initial coarse grains into submicron rhombic blocks; (ii) high density of MTs aligned in two directions subdivide the submicron rhombic blocks into nanoscale rhombic MT blocks; (iii) the third direction MT further refine the nanoscale rhombic MT blocks into nanoscale triangular MT blocks; (iv) some of subdivided blocks evolve into refined grains. An ultra-high strain rate induced by ultra-short laser pulse plays a key role in the formation of refined grains and nanoscale MT during plastic deformation of GH4169 alloy subjected to LSP treatment.


2020 ◽  
Vol 53 (4) ◽  
pp. 896-903
Author(s):  
Flávia Braga de Oliveira ◽  
Gilberto Álvares da Silva ◽  
Leonardo Martins Graça

Magnetite and hematite iron oxides are minerals of great economic and scientific importance. The oxidation of magnetite to hematite is characterized as a topotaxial reaction in which the crystallographic orientations of the hematite crystals are determined by the orientation of the magnetite crystals. Thus, the transformation between these minerals is described by specific orientation relationships, called topotaxial relationships. This study presents electron-backscatter diffraction analyses conducted on natural octahedral crystals of magnetite partially transformed into hematite. Inverse pole figure maps and pole figures were used to establish the topotaxial relationships between these phases. Transformation matrices were also applied to Euler angles to assess the diffraction patterns obtained and confirm the identified relationships. A new orientation condition resulting from the magnetite–hematite transformation was characterized, defined by the parallelism between the octahedral planes {111} of magnetite and rhombohedral planes \{10\bar {1}1\} of hematite. Moreover, there was a coincidence between one of the octahedral planes of magnetite and the basal {0001} plane of hematite, and between dodecahedral planes {110} of magnetite and prismatic planes \{11\bar {2}0\} of hematite. All these three orientation conditions are necessary and define a growth model for hematite crystals from a magnetite crystal. A new topotaxial relationship is also proposed: (111)Mag || (0001)Hem and (\bar {1}\bar {1}1)_{\rm Mag} || (10\bar {1}1)_{\rm Hem}.


Materials ◽  
2020 ◽  
Vol 13 (16) ◽  
pp. 3608 ◽  
Author(s):  
Jae-Hyung Cho ◽  
Sang-Ho Han ◽  
Geon Young Lee

Texture and microstructure evolution of ingot and twin-roll casted Mg–Al–Mn magnesium sheets were examined during deep drawing at elevated temperatures. The twin-roll casted sheets possessed smaller grain sizes and weaker basal intensity levels than the ingot-casted sheets. The strength and elongation at room temperature for the twin-roll casted sheets were greater than those of the ingot-casted sheets. At elevated temperatures, the ingot-casted sheets showed better elongation than the twin-roll casted sheets. Different size and density of precipitates were examined using transmission electron microscopy (TEM) for both ingot-casted and twin-roll-casted sheets. The deep drawing process was also carried out at various working temperatures and deformation rates, 225 °C to 350 °C and 30 mm/min to 50 mm/min, respectively. The middle wall part of cups were mainly tensile deformation, and the lower bent regions of drawn cups were most thinned region. Overall, the ingot-casted sheets revealed better deep drawability than the twin-roll casted sheets. Microstructure and texture evolution of the top, middle and lower parts of drawn cups were investigated using electron backscatter diffraction. Increased deformation rate is important to activate tensile twins both near the bent and flange areas. Ingot casted sheets revealed more tensile twins than twin-roll casted sheets. Increased working temperature is important to activate non-basal slips and produce the DRXed grain structure in the flange. Dynamic recrystallization were frequently found in the top flanges of the cups. Both tensile twins and non-basal slips contributed to occurrence of the dynamic recrystallization in the flange.


2007 ◽  
Vol 537-538 ◽  
pp. 297-302
Author(s):  
Tibor Berecz ◽  
Péter János Szabó

Duplex stainless steels are a famous group of the stainless steels. Duplex stainless steels consist of mainly austenitic and ferritic phases, which is resulted by high content of different alloying elements and low content of carbon. These alloying elements can effect a number of precipitations at high temperatures. The most important phase of these precipitation is the σ-phase, what cause rigidity and reduced resistance aganist the corrosion. Several orientation relationships have been determined between the austenitic, ferritic and σ-phase in duplex stainless steels. In this paper we tried to verify them by EBSD (electron backscatter diffraction).


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