Clay mineralogy of sediments of the western Nile Delta

Clay Minerals ◽  
1975 ◽  
Vol 10 (5) ◽  
pp. 369-386 ◽  
Author(s):  
A. H. Weir ◽  
E. C. Ormerod ◽  
I. M. I. El Mansey

AbstractInvestigation of the clay mineralogy of forty-seven samples of sediments from boreholes in the western Nile Delta, an area little studied hitherto, and from surface sites on the mouth of the Nile and adjacent coast shows that the clay fractions consist of dominant iron-rich, dioctahedral, randomly interstratified smectite-illitcs together with kaolinite, illite and chlorite.Amounts of the constituent minerals of the clay fractions are estimated from their X-ray diffraction intensities, supported by selective dissolution chemical data, and a new method is used to estimate the proportion of expanding layers in randomly interstratified smectite-illite. The results, which confirm and extend the work of previous investigators, also show that there is little correlation between the clay mineral composition and texture of the sediments, only kaolinite being weakly linearly correlated with clay content. Transformation of 2:1 layer silicate minerals occurs within the buried sediments ; chlorite is transformed and smectite and illite interlayers redistributed within randomly interstratified smectite-illites.

2021 ◽  
Vol 09 (07) ◽  
pp. 192-208
Author(s):  
Basuki Rahmad ◽  
Gerhana Prasetya ◽  
Sugeng   ◽  
Ediyanto   ◽  
Muchamad Ocky Bayu Nugroho ◽  
...  

Minerals ◽  
2021 ◽  
Vol 11 (1) ◽  
pp. 71
Author(s):  
Andrew Hurst ◽  
Michael Wilson ◽  
Antonio Grippa ◽  
Lyudmyla Wilson ◽  
Giuseppe Palladino ◽  
...  

Mudstone samples from the Moreno (Upper Cretaceous-Paleocene) and Kreyenhagen (Eocene) formations are analysed using X-ray diffraction (XRD) and X-ray fluorescence (XRF) to determine their mineralogy. Smectite (Reichweite R0) is the predominant phyllosilicate present, 48% to 71.7% bulk rock mineralogy (excluding carbonate cemented and highly bio siliceous samples) and 70% to 98% of the <2 μm clay fraction. Opal CT and less so cristobalite concentrations cause the main deviations from smectite dominance. Opal A is common only in the Upper Kreyenhagen. In the <2 μm fraction, the Moreno Fm is significantly more smectite-rich than the Kreyenhagen Fm. Smectite in the Moreno Fm was derived from the alteration of volcaniclastic debris from contemporaneous rhyolitic-dacitic magmatic arc volcanism. No tuff is preserved. Smectite in the Kreyenhagen Fm was derived from intense sub-tropical weathering of granitoid-dioritic terrane during the hypothermal period in the early to mid-Eocene; the derivation from local volcanism is unlikely. All samples had chemical indices of alteration (CIA) indicative of intense weathering of source terrane. Ferriferous enrichment and the occurrence of locally common kaolinite are contributory evidence for the intensity of weathering. Low concentration (max. 7.5%) of clinoptilolite in the Lower Kreyenhagen is possibly indicative of more open marine conditions than in the Upper Kreyenhagen. There is no evidence of volumetrically significant silicate diagenesis. The main diagenetic mineralisation is restricted to low-temperature silica phase transitions.


1962 ◽  
Vol 42 (2) ◽  
pp. 296-301 ◽  
Author(s):  
J. S. Clark ◽  
J. E. Brydon ◽  
H. J. Hortie

X-ray diffraction analysis was used to identify the clay minerals present in fourteen subsoil samples that were selected to represent some more important clay-bearing deposits in British Columbia. The clay mineralogy of the subsoils varied considerably but montmorillonitic clay minerals tended to predominate in the water-laid deposits of the south and illite in the soil parent materials of the Interior Plains region of the northeastern part of the Province.


Clay Minerals ◽  
2009 ◽  
Vol 44 (1) ◽  
pp. 35-50 ◽  
Author(s):  
Yun Huang ◽  
Xiaoyan Ma ◽  
Guozheng Liang ◽  
Hongxia Yan

AbstractMelt blending using a twin-screw extruder was used to prepare composites of polypropylene (PP)/organic rectorite (PR). The organic rectorite (OREC) was modified with dodecyl benzyl dimethyl ammonium bromide (1227). Wide-angle X-ray diffraction (WAXD) and transmission electron microscopy were used to investigate the dispersion of OREC in the composites. The d spacings of OREC in PR composites was greater than in OREC itself. The dispersion of OREC particles in the PP polymer matrix was fine and uniform when the clay content was small (2 wt.%). The rheology was characterized using a capillary rheometer. The processing behaviour of the PR system improved as the amount of OREC added increased. Non-isothermal crystallization kinetics were analysed using differential scanning calorimetry. It was shown that the addition of OREC had a heterogeneous nucleation effect on PP, and can accelerate the crystallization. However, only when fine dispersion was achieved, and at lower rates of temperature decrease, was the crystallinity greater. Wide-angle X-ray diffraction and polarized light microscopy were used to observe the crystalline form and crystallite size. The PP in the PR composites exhibited an a-monoclinic crystal form, as in pure PP, and in both cases a spherulite structure was observed. However, the smaller spherulite size in the PR systems indicated that addition of OREC can reduce the crystal size significantly, which might improve the ‘toughness’ of the PP. The mechanical properties (tensile and impact strength) improved when the amount of OREC added was appropriate. Dynamic mechanical analysis showed that the storage modulus (E′) and loss modulus (E″) of the nanocomposites were somewhat greater than those of pure PP when an appropriate amount of OREC was added. Finally, thermogravimetric analysis showed that the PR systems exhibited a greater thermal stability than was seen with pure PP.


Nature ◽  
1964 ◽  
Vol 201 (4914) ◽  
pp. 63-64 ◽  
Author(s):  
R. STEADMAN

Soil Research ◽  
1999 ◽  
Vol 37 (4) ◽  
pp. 695 ◽  
Author(s):  
Y. Pal ◽  
R. J. Gilkes ◽  
M. T. F. Wong

This investigation was undertaken to determine the potassium (K) status and adsorption behaviour of 227 samples from horizons of 41 representative virgin soil profiles, extending from Geraldton in the north to the Great Southern district of Western Australia. X-ray diffraction analysis of random powder of whole soil indicated that quartz is the dominant mineral and some soils contain significant amounts of feldspars. Clay mineralogy is dominated by kaolinite but minor quantities of illite are present in some soils. Most south-west Australian agricultural soils contain little available K: NaHCO3-extractable K (NaHCO3-K, median value 0·09 cmol K/kg, equivalent to 35 mg K/kg soil), HNO3-extractable K (HNO3-K, median value 0·30 cmol K/kg, equivalent to 117 mg K/kg soil), and total K (XRF determined K, median value, 17 cmol K/kg, equivalent to 6630 mg K/kg soil). The proportion of water-soluble K (H2O-K) ranges from 0 to 3·5% of total K, 0 to 76% of HNO3-K, and 0 to nearly 100% of exchangeable K. Exchangeable K ranges from 0 to 100% (median value 37%) of HNO3-K. These are relatively high proportions of H2O-K and exchangeable K compared with soils from many other parts of the world. The amounts of all forms of K variously increase or decrease downwards in the soil profile depending on both clay content and mineralogy. The commonly assumed increase in K with clay content alone is invalid. The soils mostly have low-to-moderate values of K sorption capacity, ranging from 5% to 67% (median value 14%) of added K (initially 4·1 mM K/L, equivalent to 4·1 cmol K/kg). otassium sorption isotherms conform well to the Freundlich equation. The inability of the Langmuir equation to describe the data may indicate that there are several types of K sorption sites in these soils. The Gapon coefficient KG varied widely from 0·04 to 29·8 (L/mol) ½ [median value 5·4 (L/mol) ½ ].


Clay Minerals ◽  
2002 ◽  
Vol 37 (4) ◽  
pp. 663-670 ◽  
Author(s):  
D. C. Bain ◽  
D. T. Griffen

AbstractThree soil profiles classed as brown forest soils on schistose parent material, in close proximity but under different land uses, have been studied. The profile under 50 year-old Sitka spruce trees is the most acidic, the second profile under rough grassland is less acidic, and the third profile in an arable field which has been fertilized is the least acidic. The clay fractions (ς μm) of all three profiles are very similar. However, computer simulations of the X-ray diffraction patterns of clay phases using a modified version of NEWMOD revealed two possible weathering trends: (1) an increasing proportion of vermiculite in interstratified mica-vermiculite in the upper horizons of the arable and forested soils; (2) formation of high-charge corrensite by weathering of chlorite in all three profiles but least pronounced in the arable soil. The differences in clay mineralogy amongst the profiles are minor, but these two different weathering trends may be due to the effects of different land use.


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