In situ Determination of the Stability of Iron Monosulphides and Kinetics of Pyrite Formation

1998 ◽  
Vol 62A (1) ◽  
pp. 151-152 ◽  
Author(s):  
L. G. Benning
Keyword(s):  
Pyrite Formation ◽  
The Stability ◽  
Kinetics Of

scholarly journals Phytochemical Molecules from the Decarboxylation of Gomphrenins in Violet Gomphrena globosa L.—Floral Infusions from Functional Food

2020 ◽  
Vol 21 (22) ◽  
pp. 8834
Author(s):  
Natalia Drobnicka ◽  
Katarzyna Sutor ◽  
Agnieszka Kumorkiewicz-Jamro ◽  
Aneta Spórna-Kucab ◽  
Michał Antonik ◽  
...  
Keyword(s):  
Citric Acid ◽  
High Resolution Mass Spectrometry ◽  
Potential Health ◽  
Gomphrena Globosa ◽  
Brewing Process ◽  
Health Promoting ◽  
The Stability ◽  
Kinetics Of ◽  
Derivatives Of

Herein, the generation of decarboxylated derivatives of gomphrenin pigments exhibiting potential health-promoting properties and the kinetics of their extraction during tea brewing from the purple flowers of Gomphrena globosa L. in aqueous and aqueous citric acid solutions were investigated. Time-dependent concentration monitoring of natural gomphrenins and their tentative identification was carried out by LC-DAD-ESI-MS/MS. The high content of acylated gomphrenins and their principal decarboxylation products, 2-, 15-, 17-decarboxy-gomphrenins, along with minor levels of their bidecarboxylated derivatives, were reported in the infusions. The identification was supported by the determination of molecular formulas of the extracted pigments by liquid chromatography coupled with high-resolution mass spectrometry (LCMS-IT-TOF). The influence of plant matrix on gomphrenins’ stability and generation of their derivatives, including the extraction kinetics, was determined by studying the concentration profiles in the primary and diluted infusions. Isolated and purified acylated gomphrenins from the same plant material were used for the preliminary determination of their decarboxylated derivatives. The acylated gomphrenins were found to be more stable than nonacylated ones. Citric acid addition had a degradative influence on natural gomphrenins mainly during the longer tea brewing process (above 15 min); however, the presence of plant matrix significantly increased the stability for betacyanins’ identification.

Thermal Stability of Retained Austenite in Low Alloyed TRIP-Steel Determined by High Energy Synchrotron Radiation

2013 ◽  
Vol 772 ◽  
pp. 129-133
Author(s):  
Stefan Brauser ◽  
Arne Kromm ◽  
Eitan Dabah ◽  
Thomas Kannengiesser ◽  
Michael Rethmeier
Keyword(s):  
Synchrotron Radiation ◽  
High Energy ◽  
Heating Process ◽  
Austenitic Phase ◽  
Trip Steels ◽  
The Stability ◽  
In Situ Diffraction ◽  
Kinetics Of ◽  
Thermal Stability Of

TRIP-steels offer a good combination between strength and ductility. Therefore TRIP-steels are widely used in the automobile industries. The aim of this work is to study the stability of involved phases during heating and to identify the kinetics of the occuring phase transformations. For that purpose, in-situ diffraction measurements, using high energy synchrotron radiation were conducted. The analysis revealed the decomposition of the metastable austenitic phase into carbide and ferrite along the heating process and the regeneration of the austenite by further heating of the sample.

scholarly journals Non-Invasive Approaches for the Evaluation of the Functionalization of Melamine Foams with In-Situ Synthesized Silver Nanoparticles

Polymers ◽  
2020 ◽  
Vol 12 (5) ◽  
pp. 996 ◽  
Author(s):  
Suset Barroso-Solares ◽  
Paula Cimavilla-Roman ◽  
Miguel Angel Rodriguez-Perez ◽  
Javier Pinto
Keyword(s):  
Polymeric Nanocomposites ◽  
Free Standing ◽  
X Ray ◽  
Color Changes ◽  
Non Invasive ◽  
Silver Nps ◽  
Promising Solution ◽  
The Stability

The use of polymeric nanocomposites has arisen as a promising solution to take advantage of the properties of nanoparticles (NPs) in diverse applications (e.g., water treatment, catalysis), while overcoming the drawbacks of free-standing nanoparticles (e.g., aggregation or accidental release). In most of the cases, the amount and size of the NPs will affect the stability of the composite as well as their performance. Therefore, a detailed characterization of the NPs present on the nanocomposites, including their quantification, is of vital importance for the optimization of these systems. However, the determination of the NPs load is often carried out by destructive techniques such as TGA or ICP-OES, the development of non-invasive approaches to that aim being necessary. In this work, the amount of silver NPs synthesized directly on the surface of melamine (ME) foams is studied using two non-invasive approaches: colorimetry and X-ray radiography. The obtained results show that the amount of silver NPs can be successfully determined from the luminosity and global color changes of the surface of the foams, as well as from the X-ray attenuance.

Stability analysis of mobile cranes and determination of outriggers loading

2018 ◽  
Vol 16 (6) ◽  
pp. 938-958 ◽  
Author(s):  
Giuseppe Romanello
Keyword(s):  
Stability Margin ◽  
Content Type ◽  
Stability Behavior ◽  
Mobile Crane ◽  
Computer Codes ◽  
The Stability ◽  
Practical Implications

Purpose The purpose of this paper is to develop mathematical tools that are reliable and easily implementable in computer codes, which address the determination of the outriggers reaction of mobile cranes and the monitoring of the actual stability margin available during lift operations. Design/methodology/approach An algorithm that determines the load transmitted to the ground by a mobile crane with four outriggers has been developed. Static theory of rigid body is adopted for the development of the algorithm and the static indeterminancy, due to the presence of more than three outriggers, is eluded through the adoption of specific hypotheses. An analysis of crane stability is also performed, and a method to monitor the actual stability behavior during lift operations is suggested. Findings A case study is proposed to test the algorithm and outcomes show a good matching with the actual outriggers reaction measured during a test conduct in situ. Two indices are introduced as a measure of the stability margin. Research limitations/implications The method developed accounts only for gravitational forces statically applied. Future works should be addressed to extend the model to the effect of wind and inertial forces. Practical implications This paper supplies a reliable tool to assess, in the design phase of a lifting operation, the compliance between bearing capacity of the ground and loads transmitted by outriggers. The method proposed for the analysis of the stability behavior is suitable for the development of an anti-upset device. Originality/value This study contributes to efforts to increase safety during lifting operations with mobile cranes. The method proposed is applicable to cranes with any geometry of the outriggers pattern and is extensible to a number of outriggers greater than four. Furthermore, the evaluation of the measure in real time of the stability margin, is not affected by the data entered by the crane’s operator with the consequence that human factor does not affect this measure.

In situ determination of adsorption kinetics of proteins in a finite bath

2005 ◽  
Vol 1069 (1) ◽  
pp. 23-30 ◽  
Author(s):  
Anne Tscheliessnig ◽  
Rainer Hahn ◽  
Alois Jungbauer
Keyword(s):  
Adsorption Kinetics ◽  
Kinetics Of

In-Situ resistance Measurements During Rapid Thermal Annealing for Process Characterization

1995 ◽  
Vol 387 ◽  
Author(s):  
E. G. Colgan ◽  
C. Cabral ◽  
L. A. Clevenger ◽  
J. M. E. Harper
Keyword(s):  
Thermal Annealing ◽  
Rapid Thermal Annealing ◽  
Silicide Phase ◽  
Heating Rates ◽  
Process Characterization ◽  
Process Learning ◽  
Silicon Structures ◽  
The Stability ◽  
Kinetics Of

AbstractMeasurement of resistance in-situ during rapid thermal annealing is a powerful technique for process characterization and optimization. A major advantage of in-situ resistance measurements is the very rapid process learning. With silicides, in-situ resistance measurements can quickly determine an appropriate thermal process in which a low resistance silicide phase is formed without the agglomeration or inversion of silicide/polycrystalline silicon structures. One example is an optimized two step anneal for CoSi2 formation which was developed in less than one day. Examples of process characterization include determining the phase formation kinetics of TiSi2 (C49 and C54), Co2Si, and CoSi2 using in-situ ramped resistance measurements. The stability of TiSi2 or CoSi2/poly-Si structures has also been characterized by isothermal measurements. Resistance measurements have been made at heating rates from 1 to 100°C/s and temperatures up to 1000°C. The sample temperature was calibrated by melting Ag, Al, or Au/Si eutectics.

scholarly journals Crystallization kinetics of amorphous calcium carbonate in confinement

2019 ◽  
Vol 10 (19) ◽  
pp. 5039-5043 ◽  
Author(s):  
Jack Cavanaugh ◽  
Michael L. Whittaker ◽  
Derk Joester
Keyword(s):  
Steady State ◽  
Calcium Carbonate ◽  
Crystal Nucleation ◽  
Amorphous Calcium Carbonate ◽  
Emulsion Droplets ◽  
Individual Crystal ◽  
Upper Limit ◽  
Kinetics Of

In situ observation of amorphous calcium carbonate (ACC) confined in ∼500 pL emulsion droplets allows determination of the timing of individual crystal nucleation events. Statistical analysis of events in hundreds of droplets establishes an upper limit for the steady-state nucleation rate of 1.2 cm−3 s−1 for the crystallization from ACC.

In-Situ Resistance Measurements During Rapid Thermal Annealing for Process Characterization

1995 ◽  
Vol 389 ◽  
Author(s):  
E.G. Colgan ◽  
C. Cabral ◽  
L.A. Clevenger ◽  
J.M.E. Harper
Keyword(s):  
Thermal Annealing ◽  
Rapid Thermal Annealing ◽  
Silicide Phase ◽  
Heating Rates ◽  
Process Characterization ◽  
Process Learning ◽  
Silicon Structures ◽  
The Stability ◽  
Kinetics Of

ABSTRACTMeasurement of resistance in-situ during rapid thermal annealing is a powerful technique for process characterization and optimization. A major advantage of in-situ resistance measurements is the very rapid process learning. With silicides, in-situ resistance measurements can quickly determine an appropriate thermal process in which a low resistance silicide phase is formed without the agglomeration or inversion of silicide/polycrystalline silicon structures. One example is an optimized two step anneal for CoSi2 formation which was developed in less than one clay. Examples of process characterization include determining the phase formation kinetics of TiSi2 (C49 and C54), Co2Si, and CoSi2 using in-situ ramped resistance measurements. The stability of TiSi2 or CoSi2/poly-Si structures has also been characterized by isothermal measurements. Resistance measurements have been made at heating rates from 1 to 100°C/s and temperatures up to 1000°C. The sample temperature was calibrated by melting Ag, Al, or Au/Si eutectics.

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