electromagnetic field at the particl e has to be computed numerically. An example of such a computation using a program based on [49] is given in Fig. 4. But not only doe s the Mie theory describe an enhancement of the laser intensity in the particles' near field, it also predicts that for certain values of the size parameter nd/X (d denoting the particle diameter, À the laser wavelength) the enhancement should be particularly efficient, resulting in a resonant intensity enhancement, the so-called "Mie-resonances". 3.2.2. Near-field induced substrate damage When inspecting contaminated samples by scanning electron microscopy (SEM) or atomic force microscopy (AFM ) after DLC using ns laser pulses, the consequences of the field enhancement process became obvious: all over the cleaned areas w e found substrate damages localized exactly at the former particle positions [35, 37-39]. These damages manifested as melting pools or even holes in the surface, typical examples can be seen in Fig. 5. The consequences for the laser cleaning process are obvious. The intensity enhancement reduces the maximum laser fluence that can be applied in the process. Usually in laser cleaning studies [19, 31 ] the laser fluence corresponding to the melting threshold of a bare surface is taken as the damage threshold fluence. Our experiments show clearly that this is an inadequate definition. Instead one must take into account the enhanced laser fluence underneath the particles, as it will be discussed in Section 4. Fro m the obtained AFM images we were able to analyse in detail the surface profile at the damaged sites. Here we found that for high field enhancement factors the silicon substrate was not only molten , but that some material was even ablated (see Sec. 4). The momentum transfer to the particles during the ablation process significantly contributes to the cleanin g process and hence local substrate ablation

2003 ◽  
pp. 327-330
Plasmonics ◽  
2019 ◽  
Vol 15 (2) ◽  
pp. 335-340 ◽  
Author(s):  
Benedek J. Nagy ◽  
Zsuzsanna Pápa ◽  
László Péter ◽  
Christine Prietl ◽  
Joachim R. Krenn ◽  
...  

Abstract We studied the evolution of femtosecond breakdown in lithographically produced plasmonic nanoparticles with increasing laser intensity. Localized plasmons were generated with 40-fs laser pulses with up to 1.4 × 1012 W/cm2 peak intensity. The damage morphology shows substantial variation with intensity, starting with the detachment of hot spots and stochastic nanoparticle removal. For higher intensities, we observe precise nanolithographic mapping of near-field distributions via ablation. The common feature of these phenomena is the central role played by the single plasmonic hot spot of the triangular nanoparticles used. We also derive a damage threshold value from stochastic damage trends on the arrays fostering the optimization of novel nanoarchitectures for nonlinear plasmonics.


2013 ◽  
Vol 829 ◽  
pp. 263-267
Author(s):  
Samaneh Malek ◽  
Reza Poursalehi

In this study, localized heating of homogenous spherical copper nanoparticles surrounded by water on exposure to short laser pulses is investigated. We are intended to estimate the maximum temperatures of nanoparticles by calculating the absorption efficiency and absorbed energy with some radii in the range 1-50 nm at the laser wavelengths of 248 and 633 nm using Mie theory. The dependency of the melting temperature of nanoparticles upon the particle size is also considered. Our calculations show the appropriate laser wavelength and nanoparticle size which are preferred for large area heating, localized heating without thermal damage or completely localized destroying of small amount of species and polymeric materials modification. The significant temperature rising and the heat transfer to the immediate vicinity is of exceptional interest in selective cell targeting, diagnosis and therapeutic applications, surface modification, and particle removing below damage threshold energy of surrounding media.


Author(s):  
Alex J. Heltzel ◽  
Senthil Theppakuttai ◽  
John R. Howell ◽  
Shaochen Chen

An investigation on the features created on a silicon substrate by the irradiation of nanospheres on the substrate surface with a pulsed laser is presented. Silica nanospheres of diameter on the order of laser wavelength are deposited on silicon substrate and irradiated with a pulsed Nd: YAG laser. As a result, nanofeatures are created on the surface by the melting and resolidification of silicon. The experiment is repeated for different laser wavelengths (532 nm, and 355 nm), sphere diameters (640 nm, and 1.76 μm) and laser energies, and the effect of each of these parameters on the features created are studied. An analytical model based on Mie Theory complements the results. The model includes all evanescent terms and does not rely on either far field or size-parameter approximations. The predicted intensity distributions on the substrate indicate a strong near field enhancement confined to a very small area (nanometer scale). The results correlate well with the feature geometries obtained in the experiment.


Author(s):  
A. Chimmalgi ◽  
D. J. Hwang ◽  
C. P. Griogoropoulos

Nanostructuring of thin films is gaining widespread importance owing to ever-increasing applications in a variety of fields. The current study details nanosecond laser-based rapid melting and crystallization of thin amorphous silicon (a-Si) films at the nanoscale. Two different near-field processing schemes were employed. In the first scheme, local field enhancement in the near-field of a SPM probe tip irradiated with nanosecond laser pulses was utilized. As a second approach, the laser beam was spatially confined by a cantilevered near field scanning microscope tip (NSOM) fiber tip. Details of various modification regimes produced as a result of the rapid a-Si melting and crystallization transformations that critically depend on the input laser fluence are presented. At one extreme corresponding to relatively high applied fluence, ablation area surrounded by a narrow melt region was observed. At the other extreme, where the incident laser energy density is much lower, single nanostructures with a lateral dimension of ~90 nm were defined. The ability to induce nucleation and produce single semiconductor nanostructures in a controlled fashion may be crucial in the field of nano-opto-electronics.


2013 ◽  
Vol 4 ◽  
pp. 588-602 ◽  
Author(s):  
Simon Dickreuter ◽  
Julia Gleixner ◽  
Andreas Kolloch ◽  
Johannes Boneberg ◽  
Elke Scheer ◽  
...  

Plasmonic resonances in metallic nano-triangles have been investigated by irradiating these structures with short laser pulses and imaging the resulting ablation and melting patterns. The triangular gold structures were prepared on Si substrates and had a thickness of 40 nm and a side length of ca. 500 nm. Irradiation was carried out with single femtosecond and picosecond laser pulses at a wavelength of 800 nm, which excited higher order plasmon modes in these triangles. The ablation distribution as well as the local melting of small parts of the nanostructures reflect the regions of large near-field enhancement. The observed patterns are reproduced in great detail by FDTD simulations with a 3-dimensional model, provided that the calculations are not based on idealized, but on realistic structures. In this realistic model, details like the exact shape of the triangle edges and the dielectric environment of the structures are taken into account. The experimental numbers found for the field enhancement are typically somewhat smaller than the calculated ones. The results demonstrate the caveats for FDTD simulations and the potential and the limitations of “near field photography” by local ablation and melting for the mapping of complex plasmon fields and their applications.


Nanomaterials ◽  
2019 ◽  
Vol 9 (10) ◽  
pp. 1421
Author(s):  
Wang ◽  
Chu ◽  
Yu ◽  
Gao ◽  
Peng

In this paper, we focus on transmission behavior based on the single aperture with a scatter. Both the near-field enhancement and polarization selection can be achieved numerically with a proposed nano-system under He-Ne laser wavelength. The nano-system consists of an Ag antenna, a wafer layer, an Ag film with an aperture and a dielectric substrate. Numerical results show that the near-field enhancement is related to the FP-like resonance base on surface plasmon polaritons (SPPs) in the metal–isolator–metal (MIM) waveguide for transverse magnetic (TM) polarization. The near-field optical spot is confined at the aperture export with a maximal electric intensity 20 times the value of the incident field for an antenna length of 430 nm. The transmission cutoff phenomenon for transverse electric (TE) polarization is because the transmission is forbidden for smaller aperture width. High extinction ratios of 9.6×10-8 (or 70.2 dB) and 4.4×10-8 (or 73.6 dB) with antenna lengths of 130 nm and 430 nm are achieved numerically with the nano-system. The polarization selective property has a good angular tolerance for oblique angles smaller than 15°. The spectral response is also investigated. We further demonstrate that the nano-system is applicable for another incident wavelength of 500 nm. Our investigation may be beneficial for the detection of polar molecules or local nano polarized nanosource.


2001 ◽  
Vol 704 ◽  
Author(s):  
Y.F. Lu ◽  
W.Y. Zheng ◽  
L. Zhang ◽  
B. Luk'yanchuk ◽  
W.D. Song ◽  
...  

AbstractThe experimental analysis of dry laser cleaning efficiency is done for certified spherical particle (SiO2, 5.0, 2.5, 1.0 and 0.5 μm) from different substrates (Si, Ge and NiP). The influence of different options (laser wavelength, incident angle, substrate properties, i.e. type of material, surface roughness, etc.) on the cleaning efficiency is presented in addition to commonly analyzed options (cleaning efficiency versus laser fluence and particle size). Found laser cleaning efficiency demonstrates a great sensitivity to some of these options (e.g. laser wavelength, angle of incidence, etc.). Partially these effects can be explained within the frame of the Mie theory of scattering. Other effects (e.g. influence of roughness) can be explained along the more complex line, related to examination of the problem “particle on the surface” beyond the Mie theory. 0.5 μm spherical silica particles were placed on Silicon (100) substrate. After laser irradiation with a 248 nm KrF excimer laser, hillocks with size of about 100 nm were obtained at the original position of the particles. Mechanism of the formation of the sub-wavelength structures were investigated and found to be the near-field optical resonance effect induced by particles on surface. Theoretical prediction of the near-field light intensity distribution was presented, which was in agreement with the experimental result.


Nanomaterials ◽  
2021 ◽  
Vol 11 (9) ◽  
pp. 2389
Author(s):  
Zhen Zhao ◽  
Chaoqun Xia ◽  
Jianjun Yang

We report the formation of a sole long nanowire structure and the regular nanowire arrays inside a groove on the surface of Fe-based metallic glass upon irradiation of two temporally delayed femtosecond lasers with the identical linear polarization parallel and perpendicular to the groove, respectively. The regular structure formation can be well observed within the delay time of 20 ps for a given total laser fluence of F = 30 mJ/cm2 and within a total laser fluence range of F = 30–42 mJ/cm2 for a given delay time of 5 ps. The structural features, including the unit width and distribution period, are measured on a one-hundred nanometer scale, much less than the incident laser wavelength of 800 nm. The degree of structure regularity sharply contrasts with traditional observations. To comprehensively understand such phenomena, we propose a new physical model by considering the spin angular momentum of surface plasmon and its enhanced inhomogeneous magnetization for the ferromagnetic metal. Therefore, an intensive TE polarized magnetic surface wave is excited to result in the nanometer-scaled energy fringes and the ablative troughs. The theory is further verified by the observation of nanowire structure disappearance at the larger time delays of two laser pulses.


Nanophotonics ◽  
2021 ◽  
Vol 0 (0) ◽  
Author(s):  
Elmina Kabouraki ◽  
Vasileia Melissinaki ◽  
Amit Yadav ◽  
Andrius Melninkaitis ◽  
Konstantina Tourlouki ◽  
...  

Abstract Optics manufacturing technology is predicted to play a major role in the future production of integrated photonic circuits. One of the major drawbacks in the realization of photonic circuits is the damage of optical materials by intense laser pulses. Here, we report on the preparation of a series of organic–inorganic hybrid photoresists that exhibit enhanced laser-induced damage threshold. These photoresists showed to be candidates for the fabrication of micro-optical elements (MOEs) using three-dimensional multiphoton lithography. Moreover, they demonstrate pattern ability by nanoimprint lithography, making them suitable for future mass production of MOEs.


Nanomaterials ◽  
2021 ◽  
Vol 11 (1) ◽  
pp. 123
Author(s):  
Zhong Lijing ◽  
Roman A. Zakoldaev ◽  
Maksim M. Sergeev ◽  
Andrey B. Petrov ◽  
Vadim P. Veiko ◽  
...  

Laser direct writing technique in glass is a powerful tool for various waveguides’ fabrication that highly develop the element base for designing photonic devices. We apply this technique to fabricate waveguides in porous glass (PG). Nanoporous optical materials for the inscription can elevate the sensing ability of such waveguides to higher standards. The waveguides were fabricated by a single-scan approach with femtosecond laser pulses in the densification mode, which resulted in the formation of a core and cladding. Experimental studies revealed three types of waveguides and quantified the refractive index contrast (up to Δn = 1.2·10−2) accompanied with ~1.2 dB/cm insertion losses. The waveguides demonstrated the sensitivity to small objects captured by the nanoporous framework. We noticed that the deposited ethanol molecules (3 µL) on the PG surface influence the waveguide optical properties indicating the penetration of the molecule to its cladding. Continuous monitoring of the output near field intensity distribution allowed us to determine the response time (6 s) of the waveguide buried at 400 µm below the glass surface. We found that the minimum distinguishable change of the refractive index contrast is 2 × 10−4. The results obtained pave the way to consider the waveguides inscribed into PG as primary transducers for sensor applications.


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