Synthesis of Ni-loaded carbon aerogels by in-situ and incipient wetness methods and their adsorption performance for dibenzothiophene in model fuel oil

Author(s):  
N Jiang ◽  
S Jin ◽  
X Shao ◽  
H Zhang ◽  
Z Li ◽  
...  
2017 ◽  
Vol 9 (4) ◽  
pp. 421-429
Author(s):  
S. S. Bristy ◽  
H. Ahmad

The nanocomposite particles named as ?-Al2O3/Fe3O4/SiO2/poly(glycidyl methacrylate) or ?-Al2O3/Fe3O4/SiO2/PGMA were prepared by multi-step process. At first, ?- Al2O3 nanoparticles were prepared by sol-gel method. Magnetite, Fe3O4, nanoparticles were then precipitated by in situ co-precipitation in presence of ?-Al2O3 particles, followed by incorporation of mesoporous silica layer using Stöber process. Finally, the surface of the ?-Al2O3/Fe3O4/SiO2 nanocomposite particles was modified by seeded polymerization of GMA using free radical polymerization. The surface modification, morphology and size distribution of the prepared nanocomposite particles were confirmed by FTIR, scanning electron microscopy (SEM) and thermogravimetric analysis (TGA). The adsorption capacity of ?-Al2O3/Fe3O4/SiO2/PGMA nanocomposite particles was evaluated using remazol navy RGB (RN-RGB) as a model dye.


2008 ◽  
Vol 2008 (1) ◽  
pp. 331-338 ◽  
Author(s):  
Bernard Fichaut ◽  
Bahr Loubnan

ABSTRACT Following the bombardment of the Jyeh power station in Lebanon on July 16 2006, about 10 to 15000 tons of heavy fuel oil drifted 150 km northward all the way to the Syrian border. Because of the continuing war, the cleanup operations could not start until early September. The response consisted of conceptually dividing the coast line into several sectors managed by various operators; from Jyeh to Beyrouth, a 34.5 km stretch of shoreline, the treatment of beaches was assigned to the lebanese N.G.O “Bahr Loubnan’. In this area, 5.3 km of sandy and gravel beaches appeared to be heavily oiled on a width that seldomly exceeded 10 m. Oil was found buried down to a depth of 1.8 m at several locations. Additionnally oil was also found sunken in shallow waters in the breaker zones of numerous beaches. In order to minimize sediment removal and production of oily waste to be treated, it was decided to operate massive treatmenN in situ. After manual recovery of stranded oil, about 12,000 m of sediment including 1,000 m of cobbles have been relocated in the surf zone. Despite the lack of tides and of the generally calm weather conditions, surfwashing was very efficient due mainly to the fact that, in non tidal conditions, sediments are continuously reworked by wave açtion which operates at the same level on the beaches. Only 540 m of heavily oiled sand, was removed from beaches and submitted for further treatment. The lack of appropriate sorbents material in Lebanon to capture the floating oil released by surfwahing was also a challenge. This was addressed by using locally Nmanufactured sorbents, which proved to be very efficient and 60 m of sorbent soaked with oil were produced during the cleanup.


1975 ◽  
Vol 21 (3) ◽  
pp. 305-313 ◽  
Author(s):  
J. D. Walker ◽  
R. R. Colwell

Degradation of mixed hydrocarbon substrate in a system comprising water from an environment relatively free of oil and a sediment inoculum from an oil-contaminated site was significantly greater than when sediment from the non-oil-contaminated environment served as inoculum. Mixed hydrocarbon substrate, however, was observed to have a limiting effect on the growth of autochthonous bacteria from the non-oil-contaminated estuarine source. Growth and cell yield were similarly reduced when marine sediment bacteria were cultured in seawater supplemented with mixed hydrocarbon substrate. The addition of a South Louisiana crude oil or a No. 2 fuel oil to water and sediment collected from a marsh area of Chesapeake Bay showed no limiting effects on growth of the total heterotrophic microbial flora when examined over a 28-day period. However, results of these studies indicate that the effects of petroleum on microorganisms should be examined carefully under conditions closely approximating those in situ.


2014 ◽  
Vol 16 (27) ◽  
pp. 13748-13754 ◽  
Author(s):  
Hiromitsu Uehara ◽  
Yohei Uemura ◽  
Takafumi Ogawa ◽  
Kentaro Kono ◽  
Ryoichi Ueno ◽  
...  

We measured the in situ polarization-dependent X-ray absorption fine structure of PtNPs deposited on a flat HOPG substrate.


Author(s):  
Xiao-hua Tang ◽  
Rui-qiang Liu ◽  
Hai-feng Tian ◽  
Hui Li ◽  
fei zha ◽  
...  

Phosphorus promoted HZSM-5 zeolites (P-HZSM-5) were prepared by synthetic methods of incipient wetness impregnation and in-situ synthesis, respectively. It was characterized by the means of XRD, SEM, BET, TG and NH3-TPD. The P-HZSM-5 zeolite prepared by incipient wetness impregnation has a large specific surface area and pore size, and the weak acidity is remarkably increased. The catalytic activity of P-HZSM-5 for the coupling transformation of methanol with 1-butene to propylene was investigated. Under the reaction conditions of temperature at 550 ℃, pressure at 0.4 MPa, space velocity at 1800 mL/(gcath) and mole ratio of CH3OH/C4H8 to 1:1, the conversion of C4H8 can reach to 75.8%, and the selectivity and yield of propylene are 42.2% and 31.9%, respectively.


Catalysts ◽  
2020 ◽  
Vol 10 (10) ◽  
pp. 1152
Author(s):  
Tatiana Kuchinskaya ◽  
Mariia Kniazeva ◽  
Vadim Samoilov ◽  
Anton Maximov

The hydrocracking reaction of a pyrolysis fuel oil fraction using in situ generated nano-sized NiWS-sulfide catalysts is studied. The obtained catalysts were defined using X-ray photoelectron spectroscopy (XPS) and transmission electron microscopy (TEM). The features of catalytically active phase generation, as well as its structure and morphology were considered. The catalytic reactivity of in situ generated catalysts was evaluated using the hydrocracking reaction of pyrolysis fuel oil to obtain a light fraction to be used as a feedstock for benzene, toluene, and xylene (BTX) production. It was demonstrated that the temperature of 380 °C, pressure of 5 MPa, and catalyst-to-feedstock ratio of 4% provide for a target fraction (IPB −180 °C) yield of 44 wt %, and the BTX yield of reaching 15 wt %.


2015 ◽  
Vol 44 (13) ◽  
pp. 6224-6228 ◽  
Author(s):  
Bingyu Xu ◽  
Ying Li ◽  
Guofeng Wang ◽  
Dongdong Zhao ◽  
Kai Pan ◽  
...  

MoO2/Mo4O11 and MoO2/MoS2 composite nanorods with high adsorption performance were successfully synthesized by reducing MoO3 nanorods.


2012 ◽  
Vol 134 (23) ◽  
pp. 9664-9671 ◽  
Author(s):  
Daniel Friebel ◽  
Venkatasubramanian Viswanathan ◽  
Daniel J. Miller ◽  
Toyli Anniyev ◽  
Hirohito Ogasawara ◽  
...  

RSC Advances ◽  
2015 ◽  
Vol 5 (118) ◽  
pp. 97467-97476 ◽  
Author(s):  
Ning Yan ◽  
Yabin Zhou ◽  
Yudong Zheng ◽  
Shuang Qiao ◽  
Qun Yu ◽  
...  

p-BC/AgNP carbon aerogels with excellent reabsorption capacities and mechanical properties were prepared by in situ reduction and carbonization. The aerogels had better antibacterial behavior and biocompatibility due to their slow controlled release of silver.


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